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The effects of various reaction conditions were studied by GC analysis. Reaction time has slight effect on the conversion of acenaphthene. The selectivity of N-phenyl aminoacenaphthene increases with reaction time. Biacenaphthenyls or N-phenyl aminoacenaphthene is in the majority, 77.6% or 90.2% when the molar ratio of AlCl3 to acenaphthene is 1.2 and 2.4 respectively.

GC考察了不同反应条件对苊转化率和产物选择性的影响,时间对苊转化率影响不大,N-苯基氨基苊的选择性随着时间增加而增大;随着AlCl3用量的增加,苊转化率和N-苯基氨基苊的选择性随之增加;AlCl3与苊的摩尔比为1.2和2.4时,产物中联苊和N-苯基氨基苊的选择性分别达到77.6%和90.2%。

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上,利用传统植化分离手段和现代分离技术,包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱,制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物,其中,2个新化合物和2个己知化合物,并进一步通过现代分析技术IR,ESI-MS,~1H-NMR,~(13C-NMR,HMBC,HMQC,~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是:3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2,6-二甲基-6-O-β-D-吡喃鸡纳糖基-2,7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷,金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷;2个已知化合物结构分别是:金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷,金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

The methylated amidogen still held protonation at low pH. Therefore, the adsorption ability of biomass was almost unchangeable through methylation of amidogen in biomass. The acetylated amidogen lost protonation at low pH, and the capacity of dye adsorption of biomass decreased by 51.6% after acetylation of amidogen in biomass.

甲基化氨基在酸性条件下仍然可以质子化,故氨基甲基化修饰后染料吸附性能不变;乙酰化氨基在酸性体系中失去质子化能力,乙酰化修饰菌体染料吸附性能下降51.6%。

Benzene-acetone (4:1,V/V)was used as developing agent to soparate amidopyrine and barbitone from the compound amidopyrine injection solution on the silica G plate,and Dual wave thin-layer chromatographic densitometry was used to determine amidopyrine (λ_s = 270nm,λ_R=340nm)and barbitone (λ_x=205nm,λ_R=320nm).

以苯-丙酮(4:1,V/V)为展开剂,在薄层硅胶板上将复方氨基比林注射液中的氨基比林和巴比妥分离后,通过双波长扫描测出氨基比林(λ_s=270nm,λ_R=300nm)和巴比妥(λ_s=205nm,λ_R=320nm)的含量

At the same time coupling reaction combined with urea and methanol is used in the synthesis of methyl carbamate.

重点研究了氨基甲酸甲酯的合成路线,本文将耦合反应应用于氨基甲酸甲酯的合成反应中,结合尿素醇解法制备氨基甲酸甲酯。

If, relative to isoflurane, cyclopropane minimally increases GABA-induced chloride currents at any GABAA receptor subtype, the present data for MAC are consistent with the notion that GABAA receptors do not mediate the immobility produced by inhaled anesthetics.

如果,相对於异氟烷而言,环丙烷在任何γ-氨基丁酸 A 受体的亚体上都是极微弱地增加γ-氨基丁酸介导氯电子流的作用,那麼现在关於 MAC 的资料就和γ-氨基丁酸 A 受体不是吸入性麻醉药产生的抑制作用的介导者这一概念一致。

A method for determination of the four metabolites of nitrofuran antibiotics such as 3-amino-2-oxazolidinone, 3-amino-5-morpholinomethyl-2- oxazolidinone, semicarbazide and 1-aminohydantoin in Poultry Tis- sues by LC-MS-MS was developed.

本文建立了用高效液相色谱-串联质谱测定禽肉组织中3-氨基-2-唑烷基酮、5-甲基吗啉-3-氨基-2-唑烷基酮、氨基脲和1-氨基-2-内酰脲4种硝基呋喃类抗生素代谢物的方法。

The polymeric resin NDA-8 was employed to treat the industrial wastewater from hydrogenated deoxidization process in tolylene diisocyanate production and good performance of adsorption and desorption was shown.

经树脂吸附处理,废水中主要污染物2,4-二氨基甲苯和2,6-二氨基甲苯均得到完全去除,COD由6 300mg/L降为150mg/L以下,达到国家二级排放标准,采用稀盐酸可实现树脂的完全再生,高浓度脱附液经调碱和结晶,可回收2,4-二氨基甲苯和2,6-二氨基甲苯

The source and formation mechanism of methyl carbamate in liquor covered the followings:①methyl carbamate formed by spontaneous chemical reaction of carbamide and methanol in fermented and undistilled alcoholic beverage;②in alcohol produced by grains as raw materials, cyanide precursor of grains formed into cyanate during fermentation and distillation, which further developed into methyl carbamate in alcohol.

白酒中氨基甲酸甲酯的来源和形成机理主要有:①在已发酵的和未蒸馏的酒精饮料中尿素和甲醇自发的化学反应生成氨基甲酸甲酯;②以谷物为原料生产的酒精中,氨基甲酸甲酯形成的途径来源于谷物的氰化物前体在发酵和蒸馏时反应形成的氰酸盐,氰酸盐在酒精中转化为氨基甲酸甲酯。

The kinetics of reconstitution of apoacylase with either 〓 or 〓 and the inactivation of the 〓 reconstituted enzyme by 1, 10-phenanthroline has been studied by following the substrate reaction continuously in presence of the metal ion or OP respectively. Although the native 〓-containing and the 〓-reconstituted enzymes have closely similar Michaelis constants and maximal velocities, the kinetics for both the inactivation by OP and the reconstitution of the apoenzyme with the metal ions differs considerably.

虽然钴重组的氨基酰化酶与天然含锌的氨基酰化酶在催化活性上比较相近,但两种酶在去金属失活动力学机制以及去金属失活的氨基酰化酶与两种金属离子重组复活的动力学过程均存在较大的差异,说明锌在氨基酰化酶中的作用比较复杂,并不能完全由钴替代。

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