氨化合物

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中，本发明是引发自由基聚合的体系，包括：a在一个部分中，一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物，其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物，例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上，和b在第二部分中，在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

The technology of preparation of chiral phenylglycinol from chiral phenylglycine is turned out to be a technical platform which can prepare many kinds of aminoalcohol through repeated experiments of the small scale test.

并且经过实验室小试反复测试，证明由手性苯甘氨酸制备手性苯甘氨醇工艺有技术平台式作用，可用于各种氨基醇类化合物的合成。

NMR and ESI-MS techniques were used to study the interactions between diperoxovanadates and small organic molecules such as pyridine, imidazole, arginine, picoline ester, and picoline amide. Spectroscopic methods were established to explore this type of interactions.

在合成数种双过氧钒化合物的基础上，利用多种NMR技术结合ESI-MS等谱学方法系统研究了双过氧钒化合物和咪唑、吡啶、取代吡啶、精氨酸、皮考啉酯以及皮考啉酰胺等有机配体的相互作用，建立了一套适合研究过氧钒化合物与有机小分子相互作用的谱学方法。

Analysis of the material change, garlic cells bioactive aliphatic thio cysteine sulfoxide and thiosulfate propenyl cysteine sulfoxide sulfur compounds in garlic, such as the role of enzymes, the generation of thiobarbituric acid sub - ester, propylene-based thiosulfinates, allyl thiosulfinates as garlic pigment precursor substances, and further changes occurred in the green garlic.

从物质变化分析，大蒜细胞中的生物活性物质硫代脂肪族半胱氨酸亚砜和硫代丙烯基半胱氨酸亚砜等含硫化合物在蒜酶的作用下，生成硫代亚磺酸酯、丙烯基硫代亚磺酸酯、烯丙基硫代亚磺酸酯，作为大蒜色素物质的前体，进一步发生大蒜绿变。

In certain embodiments, the compounds and compositions are effective to inhibit the activity of at least one serine/threonine kinase or receptor tyrosine kinase.

在某些实施方案中，该化合物和组合物可有效抑制至少一种丝氨酸/苏氨酸激酶或受体酪氨酸激酶的活性。

We devote in the research, development, production and marketing of precious metal compound and related products with reliable quality, such as; potassium gold noncyanide, Rhodium sulphate, potassium tetrabroaurate, Chloroplatinic acid, gold chloride, Ammonium chloropalladate, Ammonium tetrachloropalladate, recycled and refined precious metals etc.

公司主要从事贵金属材料相关产品的研究、开发、生产和销售，主要产品有无氰金盐和其他贵金属化合物，包括：硫酸铑、溴金酸钾、氯铂酸、三氯化金、二氯化二氨络钯、二氯化四氨络钯等，并提供贵金属资源二次回收服务。

Three aspects were included here:The derivatives of dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid were synthesized via three different routes:(1) four new compounds were synthesized via the reaction bet ween dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid, thionyl chloride and corresponding alcohol ;(2) first ,dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate wer e synthesized, then ,another four new compounds were obtained t hrough the alcoholysis under the catalyst ;(3) three acylamines were got through the ammonolysis betw een dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate and amines.

本论文分别通过三条不同的路线合成了1，4-二氢-3，6-二甲酸-s-四嗪的衍生物：(1)通过1，4-二氢-3，6-二甲酸-s-四嗪与氯化亚砜和相应的醇反应，制备了四个新化合物；(2)合成1，4-二氢-3，6-二甲酸甲酯-s-四嗪，在催化剂的作用下，与高沸点的醇进行酯交换反应，合成了四个新化合物；(3)合成1，4-二氢-3，6-二甲酸甲酯-s-四嗪后，与胺进行氨解反应，合成三个新的1，4-二氢-3，6-二甲酰胺-s-四嗪化合物。

Mehods Commercially available glycine ethyl ester hydrochloride was used as starting material to give the target compound via addition, protection with BOC, Dieckmann cyclation, reduction with NaBH4 and LiAlH4, protection, oxidation, oximation and deprotection.

以甘氨酸乙酯盐酸盐为原料，依次经加成、BOC保护氨基、Dieckmann环化、NaBH4还原羰基、LiAlH4还原氰基、BOC保护氨甲基、氧化、肟化、脱BOC保护等9步反应制得目标化合物。

In order to check the corresponding compound at 31P NMR –45.4 ppm, stable pentacoordinate spirobicyclic 2-phenoxy-1,3-phenylene-dioxo-1,3,2-iminoacetoxyphosphoranes were synthesized through a new and efficient method whereby phosphorus pentachloride was displaced stepwise by catechol, N,O-bisamino acid and phenol, or catechol, phenol and N,O-bisamino acid, their 31P NMR chemical shifts are at about 31P NMR –45.0 ppm, the results showed that the compound 4 at 31P NMR –45.4 ppm was pentacoordinate phosphorane containing amino acid residue.

采用磷谱跟踪来研究上述成肽反应机理。例如在氮气保护下，0.1mmol O，O-亚苯基磷酰氯（1）和0.15mmol N，O-二苯丙氨酸（2）苯溶液加入0.6ml核磁管中，混合均匀，反应过程用磷谱检测。反应1分钟后，起始原料1(δp=19ppm)很快转变成N-磷酰苯丙氨酸的三甲基硅基酯（3）(δp=19.8ppm)，在8分钟内，3完全转变成苯丙氨酸磷烷4(δp =-45.4ppm)，同时出现环磷三酯（6）(δp=3.5ppm)。随着反应的进行，对应于化合物4的峰逐渐变小，而6逐渐变大。

AIM To investigate whether the human pro- lidase possesses the G-type organophosphate hydrolyzing enzyme activity besides its ability to catalyze the hydrolysis of the dipeptides bearing a proline residue at the C-terminus.

目的研究人氨酰基脯氨酸二肽酶除催化水解C端为脯氨酸残基的二肽外，是否还有G类有机磷化合物水解酶活性。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失