氧锆基

Recently, Lacorre and his coworker discovered that La_2Mo_2O_9 as a new type of oxide-ion conductor has higher oxide-ionic conductivity than that of conventional yttria stabilized zirconia. However, up to now, most of the literatures on La_2Mo_2O_9 and doped La_2Mo_2O_9 reported mainly concerned with the characterization of structure and phase transformation, there has been no detailed work with respect to the conduction property on them.

最近，Lacorre等人发现新型氧离子导体钼酸镧(La_2Mo_2O_9)复合氧化物具有比传统的氧化钇稳定的二氧化锆更高的氧离子电导率，但至今有关La_2Mo_2O_9基氧化物的文献侧重于其结构、相变的报道，对其导电性能及其变化规律的研究报道较少。

Zirconium 3-nitrophthalate Zr(3-NO2-PHT2·2H20 was synthesized using 3-nitrophthalic acid, sodium hydroxide, and zirconyl nitrate as raw materials.

用3一硝基邻苯二甲酸、氢氧化钠和硝酸氧锆为原料，制备了3。

The chemical structure and applications of the alkoxy zirconates are completely analogous to those of the alkoxy titanates.

烷氧基锆酸酯的化学结构和应用完全与烷氧基钛酸酯类似。

O methoxy phenyl lithium reacts with 6,6 dimethyl fulvene to give ligand lithium (Cp ′Li,Cp ′ represents cyclopentadienyl with substituents).

邻甲氧基苯基锂和 6，6-二甲基富烯(或 6，6-二乙基富烯)反应得配体锂盐，Cp′ Li直接和 Cp Zr Cl3· DME反应生成 2个新的锆络合物 Cp′ Cp Zr Cl2 。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

The factors of temperature and humidity influenced on film thickness and order of layer were studied, in which pulling speed and pulling times were also included. It showed that the thickness of single dip-coating film reached 0.23 μm ~ 0.625 μm, and the degree of order of surface layer were still holding much higher.b Adopting calcined or uncalcined mesoporous silica membrane as matrix, nano zirconia particles were assembled through ion exchange method and ion-template exchange method.

结果表明，单次提拉膜膜厚0.23μm～0.625μm、8次提拉后表层膜仍有一定的有序性； b以自制的介孔氧化硅煅烧/未煅烧厚膜样为基体，采用离子交换法/离子模板交换法组装锆氧纳米粒子，选用DSC-TG、FT-IR、Uv-vis、SAXRD等对不同组装方法、锆源浓度、pH值等组装条件下ZrO_2/介孔氧化硅厚膜组装效果进行评价。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。