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The changes of silicate tetrahedron of fly ash in the process of mechanical grinding were analyzed by trimetheylsilicane.

采用三甲基硅烷化分析技术,研究了粉煤灰机械研磨过程中硅氧四面体结构的变化趋势。

The crosslinked PEG-20M glass capillary column was prepared by dynamic coating method with boron trifluoride as catalyst,3-glvcidyl-oxypropyl-trimethoxysilane as crosslinking agent.

以PEG-20M为固定相,三氟化硼为催化剂,3-缩甘油氧丙基三甲氧基硅烷(简称KH-560)为交联剂,二氯甲烷为溶剂,对预先用氯化钠沉积法粗糙化的玻璃毛细管柱进行动态涂渍。

Hyperbranched polymer; siloxysilane; metallic haloid catalyst; UV curing; kinetics

超支化聚合物;硅氧基硅烷;金属卤化物催化;紫外光固化;动力学

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 1 to 99 percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 99 to 1 percent of one or more alkoxysilane compounds.

一种用于丙烯聚合的催化剂组合物,包括:一种或多种齐格勒-纳塔主催化剂组合物,该齐格勒-纳塔主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体;一种或多种包含铝的辅催化剂;和两种或更多种不同的选择性控制剂的混合物,所述SCA混合物包括1到99%的一种或多种芳族单羧酸的一种或多种酯或其取代衍生物、和99到1%的一种或多种烷氧基硅烷化合物。

Three part of research works had been carried out in the dissertation. The first part: a kind of multidentate amine modified silica gel was synthesized through the following steps:(1) introduce the amino groups onto the surface of silica-gel by the treatment of surface silanol groups withγ-aminopropyl trimethoxy silane;(2) michael addition of excess trihydroxymethyl propyl triacrylate to amino groups on the silica gel surface;(3) amidation of the unreacted double bonds of TMPTA on the surface of TMPTA modified silica gel with diethylenetriamine;(4) the multidentate amine modified silica gel was finally obtained by the reaction of amino groups on the surface of DETA modified silica gel with double bond of butyl acrylate.

本论文进行了三部分研究工作,第一部分:通过多步反应对硅胶进行改性合成了一种多齿胺改性硅胶配体,合成过程如下:1通过γ-氨丙基三甲氧基硅烷与硅胶表面的硅羟基反应,使硅胶表面带有氨基;2利用硅胶表面氨基与过量的三羟甲基丙烷三丙烯酸酯发生Michael加成反应;3利用二乙烯三胺与TMPTA改性硅胶表面未反应的双键发生反应使硅胶表面氨基化;4最后用丙烯酸正丁酯与DETA改性硅胶表面氨基充分反应成功合多齿胺改性硅胶配体。

A series of tri-block copolymers of styrene/tetradecyl methyl acrylate/3-methacryloxyl-propyl thimethoxyl silane was synthesized by atom transfer radical polymerization. The structures of those copolymers were characterized by means of gel permeation chromatography, infrared spectrum, and nuclear magnetic resonance (1H-NMR). Effect of tri-block copolymers on the mechanical properties of glass fiber/polypropylene composites was also investigated.

采用原子转移自由基聚合法合成了一系列新的三嵌段共聚物大分子偶联剂聚苯乙烯-b-聚甲基丙烯酸十四酯-b-聚3-甲基丙烯酰氧基丙基三甲氧基硅烷,通过凝胶渗透色谱、红外光谱和核磁共振(1H-NMR)证实了其结构,并研究了其对玻璃纤维/聚丙烯复合材料力学性能的影响。

Finally, we discuss the preparation, characterization and application of alkylsilane and mercaptoacetoxy monolayers on ordered mesoporous titanosilicate molecular sieve.

最后,我们讨论了介孔钛硅分子筛表面烷基硅烷单层和巯基乙酰氧基单层的制备、表征及应用。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术,以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶,再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合,经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

A novel hydroxyl terminated aminosilicone oil was synthesized using octamethylcyclo tetrasiloxane (D4) and the hydrolysis product of γ-piperazinepropylmethyldimethoxysilane (HD-110) as raw material and potassium hydrate as catalyst.

以八甲基环四硅氧烷(D4)、γ-哌嗪基丙基甲基二甲氧基硅烷(HD-110)水解物为原料,在氢氧化钾催化下,制备了羟基封端的新型氨基硅油。

The novel molecular topological index was recommendedrelating to such atomic properties as electronegativity,electron number of valence shell,number of bonding electrons,the main quantum number of valence shell and bond length.

采用该拓扑指数对饱和烷烃、烷基苯、烷氧氯硅烷、卤代苯、含氮杂环化合物、碱金属卤化物及卤化锡的性质/活性进行了相关关系的研究。

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