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In this paper, a new kind of bonded organic/inorganic hybrid NLO materials containing P-Nitro aniline was synthesized through sol-gel process by using alkoxysilane dye containing P-Nitro aniline and tetraethylorthosilicate as reactants.

以含对硝基苯胺生色团的烷氧基硅烷染料和正硅酸乙酯为原料,通过溶胶-凝胶法合成了含对硝基苯胺生色团的键合型有机/无机复合非线性光学材料。

Optimization of polyester condensation process and reactor design;2. The Structure Characters of the Sulfonated Condensation Polymer Series High Performance;3. The pH value of the solution was adjusted,and the co- condensation reaction was taken place between the hydroxy groups forming transparent organic-inorganic hybrid films on polycarbonate.

以甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)水解聚合产物作为主要成膜物质,引入正硅酸乙酯水解产物硅溶胶作为无机增强物,调节两种混合溶液pH值,利用两者羟基之间的共缩聚反应在聚碳酸酯板表面制备有机/无机复合透明耐磨薄膜;采用TG/DTA、FT-IR、SEM及UV-V IS对成膜过程、薄膜性能与结构进行表征。

It was discussed that the main factors having effect on the vulcanization time of RTV block methyl silicone rubber, such as the mol ratio of ethoxyl and silicone hydroxyl, the pH value of methyltriethoxysilane, and the content of iron ions impurity in methyltriethoxysilane, temperature, moisture, and the quantity of catalyst.

讨论了影响甲基嵌段室温硫化硅橡胶硫化时间的主要因素,如:乙氧基与硅羟基的量之比,甲基三乙氧基硅烷低聚物的pH值、铁离子的含量,以及温度、湿度和催化剂的用量等;并介绍了预防和控制这些影响因素的方法。

Advancing the temperature can increase its molecular weight, the best reaction temperature is 60℃, following by IR, the mechanism of HC1 is the hydrolyzation of alkoxy in 1 hour, and then condensation reaction.

升高温度有利于生成大相对分子量的聚合物,其水解缩合的最佳温度为60℃,通过IR对反应物的跟踪,在水解缩合过程中盐酸作为催化剂先是烷氧机硅烷的水解作用,1小时内就可以完成,之后再发生缩合反应。

Then the molecular structure information connectivity indices of 22 alkoxyl silicon chlorides , 61 sulfides and 74 alkanes were calculated.

利用线性回归技术分别建立了 22个烷氧氯硅烷、61个单硫醚化合物的mY与这些物质的气相色谱保留指数RI的定量结构/保留相关关系模型。

The effects of increasing the stereospecilicity is due to deactivation of different selectivity for both atactic and isotatic active centers and the deactivation of atacitic active centers is much greater than that of isotactic active centers.

EB、DIBP和TMP用作Din的效果则各不相同。烷氧基硅烷等Dex提高等规度的作用是由于它们选择性地使无规活性中心失活大大高于等规活性中心。

Further more, to make the hybrid microspheres with good dispersibility in aqueous media, 3-propyl triethoxysilane was added to copolymerize with St and DVB, and after hydrolization the microspheres with silanol groups on the surface were obtained, which can be well dispersed in water and used for cell imaging.

进而将3-甲基丙烯酰氧基丙基三甲氧基硅烷作为共聚单体,得到了表面硅羟基功能化的聚苯乙烯荧光微球,改善了微球在水相中的分散性,并将此类荧光功能微球成功用于细胞成像。

Silicone ; hard coating ; silicone resin ; methyltriethoxy silicone ; tetraethoxy silicane ; transparent plastic

有机硅;硬质涂料;硅树脂;甲基三乙氧基硅烷;正硅酸乙酯;透明塑料

Dicyclopentyldimethoxysilane was synthesized by the addition of silicon hydride method and the reaction conditions were studied.

介绍了以二环戊基二氯硅烷为中间产物合成二环戊基二甲氧基硅烷的方法。

The primary content of this paper is the synthesis of POSS with r-glycidyl-propyl-trimethoxysilane throught hydrolysis and condensation reaction and the modification of shape memory polyurethane with synthesized POSS.

本文主要研究了以γ-(2,3环氧丙氧)丙基三甲氧基硅烷为原料通过水解缩合反应合成含有羟基的POSS以及利用该产物改性形状记忆聚氨酯。

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