氧氢基

Though the result was not so good, a general understanding of the problems lying in the manufacture process of the device was gotten.We found the symmetry was destroyed or decreased in the crystal structure of symmetrical star-shaped molecules, such as tetra(4-cyanophenoxymethyl-methane, tetra(N-pyrrolemethyl)methane, and a center of charility was self-formed.

本文发现，原本高度对称的星状分子，在晶体结构中，分子对称性破坏或降低，表现为手性分子；以四(4-氰基苯氧基甲基)甲烷为例，从分子间氢键作用的角度，解释了该现象形成的原因。

We found the symmetry was destroyed or decreased in the crystal structure of symmetrical star-shaped molecules, such as tetra (4-cyanophenoxy methyl -methane, tetra (N-pyrrolemethyl) methane, and a center of charility was self-formed. The phenomena was discussed by analyzing the intermolecular hydrogen-bonding interactions of tetra (4-cyanophenoxy methyl -methane.

本文发现，原本高度对称的星状分子，在晶体结构中，分子对称性破坏或降低，表现为手性分子；以四（4-氰基苯氧基甲基）甲烷为例，从分子间氢键作用的角度，解释了该现象形成的原因。

PP–Ag NPs were obtained in water by reacting silver nitrate with sodium borohydride in the presence of 4-(prop-2-ynyloxy)pyridine solution at room temperature for 2 h.

PP－Ag NPs是在存在4（丙炔-2-基氧基苯基）吡啶溶液的情况下，通过硝酸银与硼氢化钠在室温下反应2h而在水中得到的。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下，以异丙醇作溶剂，苯硒酚与化合物2不反应。在氢氧化钾存在下，以异丙醇／水作溶剂（体积比20：1，在室温下，硒酚可以有效地进攻中化合物2中1，3，2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件，顺利实现了硒酚对N^1-（2-呋喃基）-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环，生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

Receptor agonist ; SA4503{1?[2?（3; 4?dimethoxyphenyl）ethyl]?4?（3?phenylpropyl）piperazine}; DTG[3?di（2?tolyl）guanidine]; DHEAS ; PREGS ; learning ; memory

σ受体激动剂； 1-[2-（3； 4-二甲氧基苯基）乙基]-4-（3-苯丙基）哌嗪（SA4503）； 1； 3-二（2-甲苯基胍）；脱氢雄表酮硫酸酯；孕烯醇酮硫酸酯；学习记忆

2-Substituted-3,4-dihydro-1(2H)-isoquinolinones were synthesized from methyl 3-hydroxy-ben- zoates via allyl etherification, Claisen rearrangement, oxidation, reductive amination and aminolysis for the first time.

以3-羟基-4-甲氧基苯甲酸甲酯等为原料，通过烯丙基醚化、Claisen重排、氧化、与伯胺反应、还原、分子内酯的胺解六步反应合成了一系列2-取代-3，4-二氢-1-异喹啉酮类化合物。

When the 3-keto glycosides was reduced by sodium borohydride, the D-allo configuration was considered the most probable since it has an equatorial arylamino group at C-2 position and reduction of the keto group was considerably less hindered to equatorial attack by borohydride ion to give an axial hydroxyl, than axial attack by borohydride to give an equatorial hydroxyl.

并对反应的立体化学问题进行了讨论，认为该反应的立体专一性是由于向下直立键上的1-位α-甲氧基和2-位向下平伏键上芳胺基大基团的共同影响，造成内侧进攻受阻，而使得氢负离子只能从外侧进攻的结果。

These data were used to infer the molecular formula and the elemental compositions of all the fragmental ions through software interpretation and, by further applying fragmentation regularities of mass spectrometry, the majority of ions were fully assigned. A base peak at m/z 402 in the mass spectrum was found as the molecular ion. The fragments were created mainly from the fragmentations of the tetrahydrofuran rings and the hydroxyl group. The most fragment products contain the dimethoxy phenyl group.

利用这些数据通过软件导出了分子式和所有碎片离子的元素组成，由此进一步根据质谱裂解规律对石梓醇分子的电子轰击质谱的主要裂解碎片给出了完全的归属，质谱中发现基峰为分子离子峰(m/z402)，裂解碎片主要来自双骈四氢呋喃环的裂解和羟基引起的裂解，绝大部分裂解产物包含二甲氧基苯基基团。

The cis-decalin 79 was obtained from 2-methoxy-4-methylphenol (77) via a sequence of reactions involving intermolecular Diels-Alder reaction of masked o-benzoquinone derived from 77 and ethyl vinyl ketone, silyl enol ether formation and Cope rearrangement.

第一部份：以2-甲氧基-4-甲基酚(77)为起始物，经由二乙醯基亚碘苯氧化、分子间Diels-Alder反应、烯醇矽醚的形成及Cope重排反应得到具有十氢萘骨架化合物79。

A series of 3,3,6,6 tetramethyl 1,8 dioxo 9 aryl 1,2,3,4,5,6,7,8,9,10 decahydro acridines have been synthesized by the condensation of aromatic aldehydes, 5,5 dimethyl 1,3 cyclohexanedione and ammonium acetate in the presence of triethylbenzylammonium chloride as catalyst in water.

芳醛、5 ，5 二甲基 1，3 环己二酮与醋酸铵在三乙基苄基氯化铵催化下以水作为溶剂反应，生成一系列 3 ，3 ，6，6 四甲基 1，8 二氧代 9 芳基 1，2 ，3 ，4，5 ，6，7，8，9，10 十氢吖啶，与其它溶剂相比，水作为该反应的溶剂具有价格便宜，不易燃和无毒等优点，而且产率较高，产物的结构通过单晶X射线确

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。