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In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2,3-d]嘧啶的方法,此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵,二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

The hydrophobic association in heating process is not the same as the disassociation in cooling. Thermal gelation behavior is strongly influenced by the degree of substitution.

HPMC的两个取代基团对热凝胶过程的影响效果是相反的,羟丙基和水分子之间的氢键作用对预凝胶阶段的开始起着阻碍作用,而甲氧基则对凝胶阶段的大分子的疏水结合起促进作用。

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物,通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征,研究结果表明,配合物的组成为M〓(n=0或2),配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

Nitro derivatives of phenols, the pyrolysis initial reaction is an isomerization reaction It meansthe O-H bond in hydroxide rupture, then the Hydrogen atom transfer to the Oxygen atom in nitryl to form isomer.

苯酚的硝基衍生物的热解引发反应为异构化反应——酚羟基中的氢氧键断裂,氢原子迁移到邻位硝基(-NO_2)中的氧原子上,形成新的异构体化合物。

Water, Sweet almond oil, Cetearyl wheat bran glycosides and cetearyl alcohol, Hydrogenated jojoba oil, Zinc oxide, Rosehip oil, Evening primrose oil, Macadamia nut oil, Calendula oil, Honey, Camellia oil, Rose geranium oil, Frankincense oil, Lavender oil, Grapefruit seed extract, Vitamin E,marshmallow root,ginkgo bilboa, Phenoxyethanol, Iodopropynyl butylcarbonate.

水,甜杏油,麦秸鲸蜡硬脂基葡糖苷和十六烷基醇,氢化霍霍巴油,氧化锌,野玫瑰果籽油,月见草油,澳洲坚果油,金盏菊油,蜂蜜,山茶油,老鹳草玫瑰油,乳香油,薰衣草油,药属葵根,百果树,苯氧乙醇,碘代丙炔基氨基甲酸丁

The polymerization reacts from the inverse emulsion . Selecting white oil as continuous medium , Span60 and TX-10 as the complex emulsifier , AM-01﹑(NH4)2S2O4 and NaHSO3 as new-type complex initiator , the copolymerization of dimethylamino ethyl acrylate methyl chloride/acrylamide was developed . The effects of the concentration of monomer﹑emulsifier and initiator﹑ temperature﹑reaction time and pH on the molecular weight﹑intrinsic viscostity﹑conversion ratio and cation degree of copolymer were studied .

以反相乳液为初始聚合体系,油酸失水山梨醇酯Span60和辛基酚聚氧乙烯醚TX-10构成复配乳化剂,白油为连续介质,AM-01、过硫酸铵和亚硫酸氢钠组成新型复合引发体系,进行丙烯酰胺/(2-甲基丙烯酰氧乙基)三甲基氯化铵的反相准微乳液共聚合,研究了单体浓度、乳化剂、反应温度、反应时间、pH等因素对聚合产品分子量、特性粘数、转化率及阳离子度的影响。

AIM: To investigate the cardiac actions of 2--1 , 2, 3, 4-tetrahydro-6,7-dimethoxyl-l-[1'-(6''-methoxy-2''-naph-thalenyl ) ethyl ]-isoquinoline ( CPU57 ) by comparison with nifedipine and focus on its mechanism of actions.

目的:研究2--1,2,3,4-四氢-6,7-二甲氧基-1-[1′-(6&-甲氧-2&-萘)乙基]-异喹啉(CPU57)对心脏的作用并与硝苯地平进行比较,着重于其作用机制的研究。

Cyclization: cyclization occurs at 100℃in polyphosphoric acid for 4h in the mass ratio of 3-(4-methoxyanilino) propionic acid to PPA with 1:8, and 6-methoxy-2,3-dihydro-4-quinolone is formed in 50.5% yield with a method of rapid chromatographic column, c.

成环反应:质量比[3-(4-甲氧苯氨基)丙酸∶多聚磷酸]=1∶8,反应温度为100℃,反应时间4h,柱层析纯化后6-甲氧基-2,3-二氢-4-喹啉酮的收率为50.5%;c。

But the yields decreased to 71~37% in n-propanol, i-propanol and i-butanol, with another trimeric byproduct 1-oxo-13c-(2-naphthyloxy)-1, 13c-dihydro-dibenzo xanthenes (29) increasing up to 30% yield.

而在正丙醇、异丙醇和异丁醇中二苯并咕吨4~6的产率下降至71~37%,另一个二聚体副产物1-氧代-13c-(2-萘氧基)-1,13c-二氢-二苯并-咕吨(29)的含量增加,产率可达30%。

By studying the alkali erosion mechanism and alkali resistance of glass fibers,the paper comes to conclusions that the corrosion of glass fibers by cement matrix includes the chemical action of hydroxide ions and silica tetrahedrons and the physical action in the static fitigue process,and that glass fibers behave quite differentl.

通过对玻璃纤维碱侵蚀机理和耐碱性的探讨,得出了水泥基对玻璃纤维的腐蚀作用包括氢氧离子和硅氧四面体的化学作用和静态疲劳过程的物理作用及玻璃纤维因成分和结构的不同有很大的差异等结论。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

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双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。