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3A biomimetic catalytic system M_n/CH_3CHO has been used in the selective oxidation of p-chlorotoluene.The effects of the center metal ions,the amount of catalyst and ethanal,the oxygen pressure,the reaction time,and the reaction solvents on the selective oxidation were investigated.

3将M_n/CH_3CHO仿生催化体系用于对氯甲苯的选择性氧化,研究了不同中心金属离子、催化剂用量、乙醛用量、氧气压力、反应时间及反应介质对反应的影响。

To improve the selectivity, the Co/Mn/Br catalyst system with ethanal as an additive was studied and the reaction conditions were also optimized, which were as follows:the amount of ethanal 10%(mole ration base on the substrate), reaction temperature 100℃,reaction time 30min,the oxygen pressure 0.2MPa, the amount of the composite catalyst Co/Mn/Br 7%,the mass ration of different ingredients 2:2:1. Under these conditions, the yield comes to 24.10% and the selectivity reaches 75.03%.

为了提高反应的选择性,论文初步研究了以乙醛作为添加剂条件下各工艺参数的影响,并进行正交优化,得出最佳条件为:乙醛加入量1:10,反应温度100℃,反应时间30min,氧气压力0.2MPa, Co/Mn/Br混合催化剂加入量7%,质量比2:2:1,在此条件下,反应产率为24.10%,选择性可达75.03%。

The results show that among the acetoacetonate complexes,Co_3 has the best catalytic activity.The optimum reaction conditions were as follows:0.764 mmol of Co_3,mole fraction of ethanal 10%based on the substrate,room temperature,oxygen pressure 2 MPa,reaction time 11h and solvent acetonitrile.Under these conditions,13.3%p-chlorobenzaldehyde was obtained with 15.3%conversion and 87.2%selectivity.The oxidation can also be carried out without solvent with 8.1%conversion,89.1%selectivity and 7.2%yield respectively.

在金属配合物中Co_3的催化性能最好,在其用量为0.764 mmol、乙醛用量为反应物物质的量的10%、氧气压力为2MPa时,以乙腈为反应介质,室温下反应11h,反应的转化率和选择性可达15.3%,87.2%,对氯苯甲醛收率可达13.3%;反应也可在无溶剂时进行,此时反应的转化率、选择性及醛的收率分别为:8.1%,89.1%,7.2%。

This meter is suit oxygen, ethine, hydrogen and other high pressure decompress installment, has decompress and stead pressure function.

该仪表适用于氧气、乙炔、氢气等高压所瓶的减压装置,有降压和稳压两种作用。

The results show that under the follow conditions: pyrolysis temperature 270癈,active carbon and: ethyne black=9:l, carbon pretreated with HNOs, 7.18% Mn(NO3)2(vs. carbon support) catalyst can exhibit the best performance. In order to improve the electrocatalystic performance of MnO2, Pb(CH3COO)2 , La(NO3)3-6H2O and Ce(NO3)3-6H2O are chosen as additives of MnCVC air electrode . Electrochemical performance of the electrodes is studied by current-potential polarization curves.

为了提高催化剂的性能,选择了醋酸铅、稀土作为添加剂,采用稳态极化和交流阻抗测试方法,结果表明:铅的氧化物、稀土La和Ce可作为MnO_2催化剂的助剂来促进氧气还原反应的进行,醋酸铅添加7.5%时极化最小,在一般金属-空气电池的工作电流密度20~50mA/cm~(-2)下,电位比单独MnO_2催化剂可提升30~50mV。

A moving van locomotes, processes fuel and oxygen and excretes waste gasses.

开动的火车在移动,燃烧氧气排除废气。

On the epoxidation of styrene with molecular oxygen using cobalt-containing faujasite Co(superscript 2+-NaX as the catalyst have been studied.

100℃对含钴八面沸石Co(上标 2+-NaX催化的以氧气为氧化剂的苯乙烯环氧化反应的影响。

The finless sharks will either bleed to death, or drown because they cannot swim and need to go foward to get oxygen.

失去了鳍的鲨鱼只能留血至死,或者由于无法游泳和获得氧气而最终沉溺。

And while legions of Borat converts will be well-prepared for Baron Cohen's fearless, funny-bone-fracturing style, Allen Funt fans may want to bring along some oxygen and a defibrillator just to be safe.

而大批《波拉特》影迷将作好准备迎接拜伦。科恩的无畏的,滑稽露骨的风格,为了安全起见,艾伦凡特的影迷可能要带上一些氧气和除颤器。

During their four-hour journey, Mr Grylls his co-pilot, Gilo Cardozo, entered the death zone where the amount of oxygen present cannot sustain human life .

在历时4个小时的飞越过程中,拜尔与助手吉洛·卡多佐成功飞越了所谓的&死亡区&。&死亡区&的氧气量稀少到不能维持人的生命。

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这一模式非常关注商人的网络信用基础。

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