氧化锌

Said lead tungstate crystal comprises tungsten oxide, lead monoxide, ytterbium oxide and zinc oxide; the molar ratio between tungsten oxide and lead monoxide is 1: 1, the doping amount of ytterbium oxide is 50 -300 ppm of the total weight of tungsten oxide and lead monoxide, the doping amount of zinc oxide is 50 -1050 ppm of the total weight of tungsten oxide and lead monoxide.

Yb和Zn双掺杂钨酸铅晶体由氧化钨、氧化铅、氧化镱和氧化锌制成；氧化钨与氧化铅的摩尔比为1∶1，氧化镱的掺杂量为氧化钨和氧化铅总质量的50～300ppm，氧化锌的掺杂量为氧化钨和氧化铅总质量的50～1050ppm。

Further oxidation treatment or reduction treatment of molybdenum dioxide nanowire arrays resulted in molybdenum trioxide nanowire arrays and molybdenum nanowire arrays. We fabricated WO3 nanowire arrays successfully by further oxidizing W18O49 nanowire arrays. Based on the vertical aligned zinc oxide nanowire arrays, we prepared the aligned zinc oxide/silicon core-shell nanowire arrays, zinc oxide nanowire-zinc silicate nanotube heterojunction arrays and zinc silicate nanotube arrays by adjusting the size of the templates as well as the annealing temperature.

我们通过氧化和还原处理二氧化钼纳米线阵列，分别合成了三氧化钼纳米线阵列和单质钼纳米线阵列；通过氧化W18O49纳米线阵列合成了三氧化钨纳米线阵列；利用氧化锌纳米线阵列作为模板，通过调节氧化锌纳米线模板的尺寸和退火温度，合成了氧化锌－硅同轴纳米线阵列、氧化锌纳米线－硅酸锌纳米管异质结阵列和硅酸锌纳米管阵列。

The influence of battery formula and technology parameter on the safety performance of mercury-free alkaline Zn/MnO2 button cell was explored. Short circuit test and overdischarge test were used to study the safety performance of battery produced with varied formula and technology parameter. The factors affecting the safety performance of battery were studied. The optimal technology parameters are confirmed as follows: capacity ratio of anode to cathode is 0.91, KOH electrolyte content is 43%, content of Zn22- dissolved in KOH electrolyte is 7%, content of ZnO added in zinc gel is 0.8%1.0%, content of electrolyte added in zinc gel is 40%42%, content of binder added in zinc gel is 1% and the mass ratio of polyacrylate sodium to polyacrylic acid is 64, content of inhibitor added in zinc gel is 0.01%.

摘 要：探讨电池配方和工艺参数对无汞扣式碱锰电池安全性能的影响，采用短路测试和过放电测试的方法研究各种工艺配方下电池的安全性能，通过实验研究了影响电池安全性能的各种因素，并确定最佳的工艺参数分别如下：负极与正极容量配比为0.91，KOH电解液浓度为43%，电解液中氧化锌的含量为7%，锌膏中的氧化锌用量为0.8%~1.0%，锌膏中电解液用量为锌粉量的40%~42%，锌膏中增稠剂用量为锌粉量的1%且其中聚丙烯酸钠与聚丙烯酸的质量比为64，锌膏中缓蚀剂用量为锌粉量的0.01%。

In this thesis, three major achievements were made in theoretical study: conditions and rules for preparing nano-powders by chemical precipitation are analyzed from the point of view of thermodynamics and kinetics, the principle, standards and experimental method for the aqueous dispersion of nano-scaled metal oxide powders were proposed and verified, mathematical model of nano-filming addition of dopants by chemical coprecipitation was established. In experimental research, nm-ZnO, nm-Bi〓O〓, nm-Co〓O〓 and nm-MnO powder with spherical shape, narrow particle size distribution and small particle size were prepared successfully, highly stable and dispersive aqueous suspensoid of nm-ZnO, nm-TiO〓, nm-Co〓O〓 and nm-MnO powder were prepared successfully and surface modification on these nano-powders was also achieved, 0-3 nanocomposite ZnO varistors with nm-ZnO, nm-TiO〓and nm-MnO respectively were prepared successfully by conventional mechanical attrition, and exhibited much better electrical properties than those of conventional varistors.

综上所述，本文在理论研究方面取得了三项成果：（1）从热力学和动力学角度推导并分析了液相化学沉淀法制备纳米粉体的反应条件和规律，（2）提出了纳米氧化物的水分散体系的设计原理、规范和通用实验步骤，（3）提出了共沉淀的数学模型和计算方法；在实验方面所取得的成果有：（1）成功制备了粒度小、分布窄、形貌对称的纳米氧化锌、纳米氧化铋、纳米氧化钴和纳米氧化亚锰，（2）成功地制备了纳米氧化锌、纳米二氧化钛、纳米氧化钴和纳米氧化锰的高稳定分散悬浮液并实现了干粉体的表面改性，（3）成功地进行了纳米氧化锌、纳米二氧化钛和纳米氧化锰对压敏电阻的0—3复合掺杂实验，试样性能远优于常规压敏电阻，为实现压敏电阻的高能高压化提供了新的方法和思路。

Acetate groups charge ZnO nanocrystals negatively and passivate the surfaces,reducing the surface defects and visible emission centers. Resultantly, the increase of acetategroups lead to the quench of visible emission and improvement of photoluminescenceproperties. At appropriate concentrations, the hydroxide groups mainly passivate the surfaceand improve the photoluminescence properties.

研究发现，氢氧化锂/醋酸锌的比值对胶体氧化锌量子点的发光性质有重要影响；醋酸根基团通过使氧化锌粒子带负电荷并钝化其表面，使得氧化锌纳米点的表面缺陷和可见发射中心大大减少，因此醋酸根浓度的增大导致了可见发光的淬灭和发光性质的增强；氢氧根基团在中等浓度时主要起钝化氧化锌表面的作用，使产物的发光性质得到改善。

When the concentration of zinc nitrite is lower than 0.1 M,(002) is the prior face for zinc oxide. As the concentration raise, the other kinds of crystal face would appear. Among those data,(002) grows the best when the concentration of zinc nitrite is 0.06 M. We add lactic acid and citric acid respectively; there is an carboxyl group on the lactic acid and three carboxyl groups on the citric acid. The monodentate of lactic acid helps the growth of zinc oxide, compared to the tridentate of citric acid which can only produce zinc oxide film under very low concentration, but the growth of (002) face is not that stable as adding the lactic acid and zinc will electrodeposit to substrate.

实验中，当硝酸锌浓度低於0.1 M 时，氧化锌以(002)面为优选位相，当浓度提高，其他晶面将会出现，当硝酸锌为0.06 M，(002)晶面成长最佳，分别加入乳酸和柠檬酸，乳酸结构上有一羧基团而柠檬酸有三个羧基团，单芽基的乳酸有助於氧化锌成长，对照於三芽基的柠檬酸，则必须在极低的浓度下才能制备氧化锌薄膜，但(002)面成长却没有添加乳酸来的稳定而金属锌也会电沉积到基板上。

Further study showed that quanta size effect is the reason of ultraviolet absorption and blue shift ofabsorption peak.The prepared nano-ZnO was used in NR-SBR-BR composites, the investigation showed that the vulcanization would be proponed when very small amount of nano-ZnO was added. However, as more nano-ZnO was added and the smaller the particle size was, the shorter the vulcanization time was.

用几种不同粒径的纳米氧化锌取代普通氧化锌，应用于以NR-BR-SBR为基体的橡胶复合材料中，研究了不同粒径的纳米氧化锌对橡胶复合材料硫化时间、常规力学性能、耐老化性能及摩擦磨损性能的影响并与加入普通氧化锌的传统橡胶体系进行了 l厂b文通人学顾＊咐穴生学位沦义摘罗比较。

The main products are: the indirect method zinc oxide Zno99.7, Zno99.5, special rubber zinc oxide, light magnesium oxide, activated magnesium oxide, magnesium oxide wire and cable, adhesives dedicated magnesia, light magnesium carbonate, basic zinc carbonate, rubber accelerator TMTD, rubber Antioxidant: RD, DFC-34, SP-C, 4010,4010 NA of the Company to " With faith in order to survive, rely on technology and development, quality-oriented "approach, the vast numbers of users at home and abroad to win the trust and support, established a good cooperative relationship.

主要产品有：间接法氧化锌Zno99.7、Zno99.5、橡胶专用氧化锌、轻质氧化镁、活性氧化镁、电线电缆专用氧化镁、胶粘剂专用氧化镁、轻质碳酸镁、碱式碳酸锌、橡胶促进剂TMTD、橡胶防老剂：RD、DFC-34、SP-C、4010、4010NA 本公司以&凭诚信求生存，靠技术求发展，质量为本&的方针，赢得国内外广大用户的信赖与支持，建立了良好的合作关系。

Main production direct method zinc oxide, indirect method zinc oxide, zinc carbonate, zinc oxide in a total production of 4000 tons.

主要生产直接法氧化锌，间接法氧化锌，碳酸锌，年生产各种氧化锌共计4000吨。

A method for the analysis of zinc oxide phase content in sulfide ore was studied. On the basis of the characteristics of each phase component, the sulfide ore sample was leached twice with NaOH and acetic acid-ascorbic acid, respectively, so that the oxide mineral and zinc oxide were dissolved completely. The leaching rate of zinc oxide phase was up to 98 Vo. Moreover, the dissolution of zinc sulfide phase was effectively inhibited, solving the problems of selective leaching and determination for zinc oxide.

研究了硫化矿中氧化锌相含量的分析方法，根据硫化矿中各物相组分特点，提出了用氢氧化钠溶液和乙酸－抗坏血酸溶液二次浸取硫化矿，使锌氧化矿、氧化锌充分溶解，氧化锌相的浸取率达到98%以上，同时有效地抑制了硫化锌相的溶解，较好地解决了氧化锌相选择溶解测定的问题。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。