氧化锆

The product properties had been improved by using fused magnesium partial-stabilized zirconia, fused calcium partial-stabilized zirconia and baddeleyite as raw materials, adding a certain of additives and agents, rationally choosing grain composition, optimizing craft parameter and adjusting zirconia's stabilization rate of specimen in the research.

为此，本试验采用以电熔氧化镁部分稳定氧化锆、电熔氧化钙部分稳定氧化锆和斜锆石为原料，加入一定的添加剂和结合剂，合理调整原料的颗粒级配，优化成型工艺，调整制品中氧化锆的稳定化率，改变制品的性能。

Our survey suggested that :(1)the way in which zirconia is added has significant impact to the property of ceramic powders. The flexural strength of the ceramic powders produced by the mix of ZrO2 and leucite crystal is much lower than that of ceramic powders produced by solid phase reaction.

氧化锆-白榴石基烤瓷粉的研究表明：(1)氧化锆的添加方式对瓷粉的性能影响很大，氧化锆与合成的白榴石晶体混合所得的瓷粉的弯曲强度大大低于一次固相反应合成的氧化锆-白榴石烤瓷粉，其弯曲强度甚至还不如没有添加氧化锆的瓷粉。

The composites were tested by X-Ray Diffraction, Scanning Electron Microscopy, Thermal Expansion Coefficient and flexural strength. In these ways, the synthesization of leucite crystal and the preparation of Zro2-KAlSi2O6 Ceramic powder are systemically investigated.

本研究以钾长石、纳米氧化锆和碳酸钾为原料，采用固相反应合成氧化锆-白榴石基烤瓷粉，借助XRD、SEM、TEC和弯曲强度等分析测试方法，对白榴石晶体的合成及氧化锆-白榴石基烤瓷粉的制备进行了较为系统的研究。

The results indicate that the effect of anhydrous and un-hydroxyl resin is better than liquid paraffin and each of electrocast zirconia and monocline zirconia can promote sintering of magnesia-calcia brick,and the effect of monocline zirconia is better than that of electracast zirconia.

结果表明：作结合剂用时无水无羟基树脂效果好于液体石蜡；作为添加剂时电熔氧化锆和单斜氧化锆均能显著促进镁钙砖的烧结，其中单斜氧化锆的效果好于电熔氧化锆。

The influence of different assembled condition such as assembly method, concentration of zirconium source and pH value on the effectiveness of assembly were evaluated via DSC-TG, FT-IR, Uv-vis and SAXRD et al. It showed that the assembly effectivness of uncalcined 3 Si/Zr_10# sample was best.c The optical characteristic, which including light-conduction in infrared band and polarity in visible band, of dip-coating film and membrane assembled zirconia after processing parameters of assembly optimized were observed via FT-IR and Uv-vis. The polarity was characterized by polarizing angle through calculation from light-transmittance, light-reflectance and fresnel coefficient. qualitative analysis showed that the polarity of Si/Zr_10 # dip-coating film assembled was best.d Adopting zirconium oxychloride as zirconium source, CTAB as template, employing different CTAB adding sequence, two mesoporous zirconia samples were prepared. The template effect of two samples was discussed. It showed that the effect of the sample which CTAB adding sequence was same as mesoporous silica film was better. The light-conduction in infrared band of these samples was also studied, which offered comparison to the polarity of zirconium dioxide assembled within mesopore.

结果显示：组装条件优化后的uncalcined 3 Si/Zr_10#厚膜样组装效果最好，其组装液对应的pH值最利于该锆源离子模板交换组装； c选用FT-IR、Uv-vis对组装条件优化后纳米氧化锆/介孔氧化硅厚膜、纳米氧化锆/介孔氧化硅薄膜包括红外导光性、可见光区内的偏光性在内的光学特性进行了分析，其中偏光性以膜层透光性、反光性及菲涅耳系数计算出的偏振角即布儒斯特角表征，定性分析显示，Si/Zr_10#ZrO_2/介孔氧化硅厚膜偏光性最好； d以氧氯化锆ZrOCl_2·8H_2O为锆源，CTAB为模板剂，采用不同的模板剂加入顺序，探索性地制备两介孔氧化锆样，分析了两介孔氧化锆样的模板效果，得出模板剂加入顺序同介孔氧化硅薄膜时介孔氧化锆样的模板效果较好，并分析了所得样品的导光性，为锆氧粒子引起的附加光学特性分析提供了参考和对比。

Low vacuum measurement ; yttria stabilized zirconia ; zirconia oxygen sensor ; zirconia oxygen concentration cell

低真空测量；氧化钇稳定氧化锆；氧化锆氧传感器；氧化锆氧浓差电池

Four large-scale high-frequency melting Cubic Zirconia production line produced zirconia quality, color stability of diverse, low price, become the largest supplier of zirconium oxide materials.

四条大型高频熔炼立方氧化锆生产线，所产氧化锆质量上乘，颜色稳定多样，价格低廉，成为目前国内最大的氧化锆材料供应商。

Main specifications of the zirconium oxide ceramic casing, zirconia ceramic casing is optical fiber communications link with the core components, its products of high accuracy (1 micron), the stability of zirconia finished the demanding, complex processing technology.

主营各种规格的氧化锆陶瓷套管，氧化锆陶瓷套管是光纤通信的连接器的核心部件，其产品精度高（1微米），氧化锆成品稳定性要求严格，加工工艺复杂。

The mian works are as follows:(1)By coprecipitation technique and coprecipitation- gel technique the nano zirconia powder was produced, factors affecting the properties of nano zirconia powder such as pH and the content of stabilizator are analyzed;(2)By the new pressless sintering process, the nano zirconia ceramic was produced, factors which can affecting the properties of nano zirconia sinter body such as moulding press and the sinter temperature are analyzed;(3)By the microtherm pressless sintering process, the nano copper added functional zirconia ceramic composite was produced, microscopic dimensionality and electric properties of such sinter body and the factors affecting such sinter body are analyzed;(4)By the self-invented "external albumen coating" technique the zirconia powder was successfully coated by carbon in the corresponding sinter body, which can help solve the traditional aggregation problem to some degree;(5)Based on analyze the characteristics in the nano powder sinter process, the "three-ball sinter model" was proposed, for the relationship between the relative density and porosity of sinter body, by mathematical fitting, such model was successfully verified.

本研究比较系统地研究了纳米氧化锆陶瓷的合成与成型机理，特别是讨论了纳米氧化锆陶瓷的稳定性，为防止纳米颗粒在外场作用下的团聚和长大提供了理论基础和实验数据，具体工作有以下几方面：(1)采用共沉淀法和共沉淀-凝胶法制备了纳米氧化锆粉体，并分析了pH值和稳定剂含量对粉体性能的影响；(2)采用新型无压烧结工艺制备了纳米氧化锆陶瓷，并分析了成型压力和烧结温度对烧结体性能的影响；(3)采用低温无压烧结工艺制备出添加纳米铜的功能性纳米氧化锆复合陶瓷，并分析了烧结体的微观尺度和电学性能的变化以及影响因素；(4)通过自创的&鸡蛋清外敷法&在真空镀膜台上对纳米氧化锆粉体进行包敷碳颗粒的表面处理，并采用真空烧结工艺制得相应烧结体，初步开始解决陶瓷烧结过程中团聚长大这一传统难题；(5)通过分析纳米颗粒在制备烧结体过程中的实际特点，提出了&三球烧结数学模型&，通过引入坯体相对密度和孔隙率的相对关系分析并通过自行编写的数学拟合软件，验证了这一数学模型。

Zirconia/graphite compound mold core was prepared by the coating, in which the silicon sol was used as binder and zirconia was used as refractory materials. The application feasibility of metal particles as a coolant in the solidification process was studied, and the application of metal particles as subsidiary coolant in the liquid metal cooling of directional solidification were analyzed and studied in this investigation. The conclusions can be drawn as follows: 1 The zireonia/graphite compound cores fabricated by brushing coating which was prepared by making silicon sol agglutinated zirconia as a refractory material were casteded at 800℃and 1000℃respectively, and the results show that the strength of the mold core is strong enough to meet the requirement of practical casting.

本文研究了以硅溶胶为粘结剂，氧化锆为耐火材料来制备氧化锆／石墨复合型芯的制备工艺；并分析了金属颗粒作为冷却剂在金属凝固过程中应用的可行性、金属颗粒的冷却能力以及金属颗粒作为辅助冷却剂在定向凝固的液态金属冷却法中的应用，得出以下结论：(1)以硅溶胶为粘结剂，氧化锆为耐火材料来配制涂料，采用刷涂石墨型芯的方法来制备的氧化锆／石墨复合型芯经800℃和1000℃实际浇铸实验，结果证明型芯的强度足够满足实际浇铸要求。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。