氧化钛

The results show that the TiO2 porous films can be obtained by anode oxidation using 10% H2SO4, voltage of 120V on the surface of Ti-6Al-4V alloy, and the aperture size is about 100-200nm. The acerate CaHPO4 with size of 200-400nm can be gained by the electrochemical deposition. Ultimately, the acerate CaHPO4 changed to the sheet Ca10(PO4)62 after being treated with 0.1mol/L NaOH in autoclave at 200℃ for 10 hours .

结果表明：钛合金（Ti-6Al-4V）板经以10％的硫酸为电解液和电压为120V时阳极氧化，产生孔径大约为100-200nm的多孔氧化膜，再经电化学沉积，得到尺寸大小约200-400nm针状的CaHP04，最后经盛有浓度为0.1mol/LNaOH 水溶液、温度为200℃的高压釜中水热合成10h，针状的CaHP04 转变为片状的Ca10(PO4)62。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The pure titanium, MAO layer and MAO-HS have slightly influence on the tissue of animals, and their tissue compatibility enhanced subsequently from inbed impanation under skin test.

皮下埋植实验表明纯钛、微弧氧化和微弧氧化-水热合成试样引起的组织反应为轻度，且组织相容性依次递增。

The composition, interface and cross section of the sintered EPCD coating were observedand analyzed by SEM, X-ray diffraction , Infra-red spectrum, EPMA, Energydispersion X-ray fluorescence analysis and X-ray-electron spectroscopy,the results show that the coating made from〓BG is composed of HA, titanite and bioglass.

钛合金基体表面的喷砂处理不仅可改善与涂层的机械结合，还可加速其表面氧化和降低预氧化温度，对于实现涂层的低温快速烧结和提高涂层结合强度有重要意义。

On the basis of investigating the developments of inorganic mesoporous material's syntheses and applications, mesostructured tin oxide, bismuth oxychloride, lead sulfide, bismuth sulfide, titanium phosphate and zinc phosphate were synthesized by Sol-Gel and hydrothermal techniques, employing the neutral surfactant organic amine and anion surfactant alkyl sulfonate as templates.

在对无机介孔材料的合成、应用等方面的发展现状进行了充分调研的基础上，本文运用溶胶一凝胶法、水热法等合成手段，选用中性表面活性剂有机伯胺和阴离子表面活性剂烷基磺酸盐为模板，制备了二氧化锡、氯氧化铋、硫化铅、硫化铋、磷酸钛、磷酸锌等无机介孔材料。

On the basis of investigating the developments of inorganic mesoporous material's syntheses and applications, mesostructured tin oxide, bismuth oxychloride, lead sulfide, bismuth sulfide, titanium phosphate and zinc phosphate were synthesized by Sol-Gel and hydrothermal techniques, employing the neutral surfactant organic amine and anion surfactant alkyl sulfonate as templates.

中文题名非硅基介孔材料的合成与表征副题名外文题名论文作者周书喜导师李健民学科专业物理化学研究领域\研究方向学位级别博士学位授予单位中国科学技术大学学位授予日期2003 论文页码总数92页关键词介孔材料介孔分子筛馆藏号BSLW /2003 /O643.3 /50 在对无机介孔材料的合成、应用等方面的发展现状进行了充分调研的基础上，本文运用溶胶一凝胶法、水热法等合成手段，选用中性表面活性剂有机伯胺和阴离子表面活性剂烷基磺酸盐为模板，制备了二氧化锡、氯氧化铋、硫化铅、硫化铋、磷酸钛、磷酸锌等无机介孔材料。

A porcelain like film with protective and ornamental function can be obtained by anodizing aluminum alloy in potassium titantyl oxalate acidic solution.

草酸钛钾法瓷质阳极氧化可在铝及其合金材料表面形成一层外观类似瓷釉和搪瓷的氧化膜，具有较好的保护、装饰性。

Aiming at solving the problem in the electrochemical oxidation of ammonia wastewater,the tin and antimony electrodes based on titanium were manufactured,the effect of different manufacturing condition to the impact of electrochemical oxidating ammonia wastewater was researched. After researching the influential factor and optimizing the manufacturing condition,the appearance analysis and the electrochemical analysis was hold on, the electroactivated character of the electrodes was studied to provide warrant to its application in the ammonia wastewater.

本论文从电化学氧化法处理含氨氮废水的问题出发，对钛基锡锑电极材料进行研制，考察了不同的制备条件对含氨氮废水的电化学氧化去除的影响，研究了各影响因素并优化了制备条件，并对其进行了表面形貌分析、电化学分析的研究，微观地研究了电极的电催化性能，为其应用于实际氨氮废水处理中提供了依据。

Taking titanium as the base metal, a kind of tin dioxide catalytic electrode with an inter-layer containing Mn(Ti/Mn/SnO2) was prepared by pyrolysis.

采用高温热氧化方法制备了含Mn中间层的钛基二氧化锡电催化电极Ti/Mn/SnO2。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐