氧化钛

Result of photocatalytic degradation of methyl orange showed that the TiO2 photocatalytic activity decreased with the decreasing of anatase ratio in the mixed crystallite of anatase,rutile,and brookite;and photocatalytic activity of pure rutile TiO2 was relatively bad.

光催化降解甲基橙的研究表明，所得锐钛矿、金红石和板钛矿3种混晶中，二氧化钛的光催化活性随着锐钛矿含量的降低而降低；纯金红石型二氧化钛的光催化活性较差。

When the is 0.1mol/l, ratio / is 0 or 4, aged at 95250℃ for 24 hours, anatase and rutile TiO〓 particles are formed respectively; when the ratio / is between 0 and 4, mixture of anatase and rutile TiO〓 particles is formed, the high the temperature the more the rutile phase. When the / is 5, aged at below 200℃ for 24 hours, amorphous product is gained, aged at 250℃ for 24 hours, olive-like TiO〓 particles with brookite structure are formed.

Ti〓=0.1mol·L〓时，95～250℃陈化，/比为0时，得到金红石型TiO〓颗粒，/比为4时，得到锐钛型TiO〓颗粒；/比介于0～4，可得到金红石型与锐钛型混合二氧化钛颗粒，温度越高含金红石型成分越多；/比为5，200℃以下陈化，得无定型产物，250℃陈化得橄榄形单分散板钛矿型二氧化钛。

The space oriented blocks of modifiers favor the formation of small-sized rutile TiO2 nano-rods, at the same time, the coordination between carboxyl or hydroxyl group of modifiers and TiO2 nanoparticles also inhibit the TiO2 crystal growth, resulting in small-sized rutile nanoparticles.

结果表明：含羧基或羟基的有机化合物在修饰剂条件下都制得了纳米金红石型二氧化钛，且修饰剂的加入抑制了棒状纳米二氧化钛的颗粒大小，其中修饰剂的空间位阻效应在控制合成小尺寸二氧化钛纳米棒中起主要作用，且修饰剂的羟基和羧基的络合作用对颗粒的生长也起到抑制作用。

In the protein adsorption and osteoblast culture in vitro, more surface hydroxyl groups and higher polar component of surface energy led to more protein and cell adsorbed, and higher cellular activity.

在本论文中，通过金红石二氧化钛膜、锐钛矿二氧化钛膜、含钙的钛表面、含磷的钛表面和Ti-羟基磷灰石涂层的表征，结合羟基磷灰石沉积、蛋白质吸附和细胞体外培养，研究了钛的表面表征与生物活性的关系。

The dispersion mechanism of the dispersants was analyzed by testing the Zeta potential of the dispersion phase in the dispersion medium. It was shown that Ⅰ and Ⅱ raised obviously the absolute values of surface Zeta potential of titania particles, and NK-1 formed good solvate layers of the particles so that the nano-titania particles were stably dispersed in the water solns.

通过测定分散相在分散递质中的Zeta电位，分析了分散剂的分散机理，说明六偏磷酸钠和硅酸钠可显著提高整理液中二氧化钛颗粒表面Zeta电位的绝对值，NK-1在纳米二氧化钛颗粒表面形成良好的溶剂化层，使纳米二氧化钛颗粒在水溶液中获得优良的分散稳定性。

At the same time we produce high purity magnesium oxide powder, activate magnesium oxide powder, high purity fused magneisum oxide powder, Strontium Titanate powder, and supply Yttrium Oxide powder, magnesium oxide hydroxide powder.

同时又生产国内领先的高纯度氧化镁粉、高纯度活性氧化镁粉、高纯度电熔陶瓷氧化镁粉、钛酸锶粉等粉体材料，并还能提供高纯度二氧化钛粉和氧化钇粉以及高纯度氢氧化镁等原料。

In this paper,we compared the photodegradation efficiency of nano-titania films by using dichloroacetic acid,rhodamine B and methyl orange as the photocatalytic referents and the ultraviolet lamp as the source light to generate the photocatalytic reaction.

针对纳米氧化钛光催化性能研究中缺乏统一有效表征标准的现状，比较了二氯乙酸、罗丹明B和甲基橙三种光催化活性评价物的热稳定性和对紫外光的稳定性，并以氧化钛纳米薄膜为光催化剂，研究了三种评价物的光催化降解效率表征，以及酸碱度、通氧条件等因素对评价物在光催化活性表征中的影响及其机理，归纳了三种评价物对于纳米氧化钛光催化活性表征的优缺点。

The results showed that new type structure of organic phase containing inorganic phase between polyimide and titania particle by bond conjunct was formed.The discomposing temperature was decreased with the increasing of TiO2 contents,and the thermal stability was better than polyimide materials under the temperature of 450℃.The pore size increased with the increasing of TiO2 contents,and pore size distribution tended to disperse.The permeability of N2,H2 and CO2 across the membrane were controlled by Knudsen diffusion,and the memebrane exhibited outstanding hydrophilicity since their permeation coefficients of H2O／N,are higher than the Knudsen diffusion values.

结果表明，杂化膜材料形成了有机相包裹无机相的交联结构；聚酰亚胺与二氧化钛粒子形成了新型键联结构；其热分解温度随二氧化钛含量的增加而降低，在 450℃以下热稳定性优于聚酰亚胺膜材料；平均孔径随二氧化钛含量增大而增大，孔径分布趋于弥散；N2、H2和CO2在膜内渗透由Knudsen扩散控制，H2ON2分离因子均大于Knudsen扩散值，表现出良好的亲水性。

The aim of this thesis is to prepare rutile TiO2 nanorods under the hydrothermal condition and to investigate the correlation between the preparation parameters and the photocatalytic activity of as-prepared TiO2 samples. The initial sols for TiO2 were prepared by the hydrolysis and condensation of Ti precursor, titanium n-butoxide 〔Ti4, TNB〕 in DI-water with hydrogen chloride as a peptizer.

中文摘要本研究的主要目的是制备以水热法制备金红石相二氧化钛奈米棒并探讨其制备条件与光催化活性的相关性，以四丁基氧化钛为前驱物，在盐酸的催化下，经由水热处理来合成金红石相的二氧化钛奈米粒，并藉由XRD鉴定其结晶相，TEM来观察其外观形貌及其颗粒大小，氮气吸附法来分析其比表面积。

When using urea-hydroperoxide as oxygent, just the trimethylphosphine adsorbed on the Lewis acid sites in TS-1 zeolite was oxidized. It further confirmed that the hydroperoxo-titanium species formed by the interaction between the titanium in Lewis acid sites and urea-hydroperoxide are the active oxidation center, and the titanium in the framework as Lewis acid sites enhances the oxidation ability of hydroperoxide. 3. Phenylacetaldehyde and benzaldehyde are found to be the major products in the catalytic oxidation of styrene over TS-1 zeolite, and styrene epoxide is not as speculated detected.

当以过氧化氢尿素为氧化剂时，室温条件下吸附在TS-1分子筛Lewis酸性位的三甲基膦即能被氧化，由此进一步证明，TS-1分子筛中由Lewis酸性位的骨架钛与过氧化氢相互作用形成的过氧化钛物种是三甲基膦氧化反应的活性中心，骨架钛作为Lewis酸中心提高了过氧化氢的氧化能力。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。