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氧化还原滴定

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This paper put forward three ways: Oxidation-reduction titration, ferruginous spectrophotometry, and direct spectrophotometry. Every way is applied in PH fit for itself. Every way should pay attention to some ways.

本论文确定高铁酸钾的三种定量分析方法:亚砷酸钠氧化还原滴定法、邻二氮杂菲分光光度法、直接分光光度法,并明确了每种方法的适用PH值范围和应遵守的相应注意事项。

Chromic trioxide and chromium hemitrioxide are determined with iodometry, the coefficient of variation of chromic trioxide is 0.056%, and the recovery of marked compound is 99.82-99.83%; the coefficient of variation of chromium hemitrioxide is 1.45%,and the recovery of marked compound is 98.55-99.26%; iron is determined by complexometric titration, the coefficient of variation of iron is 1.73%, and the recovery of marked compound is 99.12-99.23%;sulfate is determined by complexometric titration, the coefficient of variation of sulphate is 0.16%, and the recovery of marked compound is

Analysis Of The Chromium Electroplating Wastewater By Oxidation-reduction And Complexometric Titration-化学工程与工艺-本文采用氧化还原滴定法与络合滴定法对镀六价铬的废水中铬酸酐,三氧化二铬,铁和硫酸根的含量进行了测定:铬酸酐和三氧化二铬用碘量法测定,铬酸酐的变异系数为0.056%,加标回收率为99.82-99.83%,三氧化二铬的变异系数为1.45%,加标回收率为98.55-99.26%;铁用络合滴定法测定,其变异系数为1.73%,加标回收率为99.12-99.23%;硫酸根用络合返滴定法测定,其变异系数为0.16%,加标回收率为

Complex formation titration, oxidimetry and precipitation titration were compared.

对配位滴定法,氧化还原滴定法和沉淀滴定法进行了比较。

A rapid and practical redox titration method for determination of vanadium in steel was proposed.

提出了一种快速的氧化还原滴定法测定钢铁中钒的实用方法。

Thus this method could be applied to monitor the process of producing dinitrogen pentoxide by electrochemical oxidation of dinitrogen tetroxide in nitric acid. The results from the two-step titration method of redox titration combined with acidity titration were well consistent with that from the method of redox titration combined with NMR.

氧化还原和酸度两步滴定与氧化还原滴定结合核磁共振光谱法的分析结果表明,两种方法的分析结果吻合良好,精确度良好,两种方法都可用于N_2O_4-N_2O_5-HNO_3体系各组分的全浓度分析。

The kinetics of iridium catalyzed oxidation of isobutyl alcohol by cerium in aqueous sulphuric acid medium has been investigated by titrimetric technique in the temperature range of 25~40℃.

在酸性介质中用氧化还原滴定法研究了鈰离子在痕量铱离子催化作用下,於25~40℃区间氧化异丁醇的反应动力学。

The comples formed with phen,dipy and variant valence metal such as Fe,Co,Ru and so on was statable and had higher electric potential at low valence.There was difference between the colours of low and high valence methal complex,so it played very important rule in oxidate-reduction titration and spectrophotometry.

邻二氮菲、联吡啶与铁、钴、钌等变价元素形成配合物,低价态呈稳定态,电对电位升高,且高低价态配合物颜色有明显差异,使之在光度分析,氧化还原滴定中获得重要应用。

The determination of industrial zinc sulphide content by redox titration method was introduced.

利用氧化还原滴定法测定工业硫化锌的含量,分析了影响硫化锌含量测定的因素,样品测定实验结果表明,该法样本合并标准偏差s_q=0。

In the paper,according to the specific law of redox titration,using stoichiometric relation and Nernst formula in the chemical reactions.

根据氧化还原滴定的特殊规律,运用化学反应的计量关系和能斯特公式,给出了氧化还原滴定终点误差的简单计算公式。

In the paper following the change law of concentration and electric potential of different stage oxidation-reduction titration and appling the Nernst formula, it was discussed that the application of Ringbom error formula in symmetry donblet oxidation-reduction titration.

本文遵循氧化还原滴定各个阶段的浓度与电位变化规律,运用能斯特公式,探讨了能适用于氧化还原滴定中对称电对的林邦误差公式,具有便于记忆与应用等特点。

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