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2When excess ascorbic acid is added to the reaction mixture to reduce o-quinone back to catechol...

四乙醇的存在,并不影响多酚氧化酶氧化儿茶酚作用时氧气被完全还原为水的作用。

We had determined the reducing power of the three Boletes,in addition,the antioxidant effect on peroxidation of unsaturated fatty acid in lipoprotein,Fenton system and the self oxidation method of pyrogallol were measured in vitro,we also detected the compounds of antioxidant.

实验测定了三种牛肝菌甲醇提取物的还原力,以及在卵黄脂蛋白不饱和脂肪酸过氧化体系、Fenton体系和邻苯三酚自氧化体系中的体外抗氧化活性及其起抗氧化作用的物质。

The results indicated that the water or 50% ethanol extracts from peonies petals could reduce light absorption of DPPH and OH initiated hydroxylation of salicylate, and inhibit O2(superscript -) mediated light chemical reduction of nitroblue tetrazolium effectively, and lipid peroxidation of polyunsaturated fatty from yolk lipoprotein, in which DPPH scavenging activities of 6 peonies water extracts were hinger than that of 200 μg/mL BHT, but lower than 80 μg/mL Vc. In 4 kinds of detecting systems of antioxidation, the peroxidation activity of deep colored flowers of peonies was higher than that of light colored flowers of peonies.

牡丹花瓣提取液能明显抑制卵黄组织匀浆的脂质过氧化作用,降低DPPH的吸光值、抑制O2介导的NBT光化学还原及OH作用下的水杨酸羟基化作用,其中牡丹花瓣提取液清除DPPH自由基的活性高于200μg/mL BHT,但低于80μg/mL Vc.6个品种的牡丹花瓣提取液,在4种测定系统中均具有一定程度的抗氧化能力,且水提取液的抗氧化活性略高于体积分数50%乙醇提取液,深色花瓣提取液对不同自由基的清除能力较强。

Finally, the article discussed the possible mechanism of multi-phase electrochemical degradation of wastewater through the XPS spectrum of the used catalysts surface: In the acid solutions, the electro-generated O_2 may get electrons on the porous graphite cathode and then form H_2O_2, H_2O_2 may diffused to the surface of catalyst and reacted with its active part to produce OH, which in turn can destruct organics. The catalyst functioned as both the catalyst to decompose H_2O_2 and the flocculants to sedimentate the degraded waste.

最后全文结合研究反应后催化剂表面的XPS光电子能谱推断了该体系降解污废水可能的反应机理:在酸性条件下,石墨双阳极产生的O_2被多孔扩散性石墨阴极还原成H_2O_2,并通过扩散传质作用在催化剂的表面活性中心分解为强氧化性中间产物·OH,强氧化性攻击有机物,使其降解为小分子有机物或CO_2和H_2O,催化剂在体系中即起催化作用也起吸附、絮凝作用。

MgO-C brick has a good erosion resistance but Al〓O〓-C brick is better. Corrosion mechanism for refractory without carbon is that FeO and oxides of molten slag take place chemical reaction with constituents of refractory and forming low fusing point compounds to be dissolved in molten slag. For those refractory containing graphite carbon is to be decarburized in advance and to form decarburizing layer and metamorphosis layer. The subsequent corrosion is decarburizing and taking chemical reaction to form low fusing point compounds and dissolved in molten slag at the same time.

铁浴中硅和钛的扩散是影响铁浴及熔渣与耐火材料作用的重要因素,耐火材料中添加的TiO〓和SiC受熔渣氧化和侵蚀,将被部分还原形成Si,Ti向铁浴中扩散,Si、Ti在铁浴中的扩散研究结果是: D〓=1.84×10〓exp(-5988.7/T) cm〓/S E〓=49766 J/mol D〓=7.76×10〓exp(-53225.5/T) cm〓/S E〓=442304 J/mol 铁浴式熔融还原熔体对粘土砖,高铝砖,镁砖的侵蚀速度很高,镁碳砖抗侵蚀能力比前几种耐火材料强,但不如铝碳砖;对不含碳耐火材料在熔体中的侵蚀是熔渣中FeO及其它氧化物与耐火材料组分的化学反应形成低熔点物熔蚀进入渣相,产生损毁。

By injecting commercially pure argon to make pressure in furnace up to 66.66 kPa and controlling refining temperature between 1 450 ℃ to 1 500 ℃, adding Mg-Ca alloy 50 kg/t and fluxed additions CaF\-2 11 kg/t, after refining the phosphorus content in steel 00Cr18Ni10 further decreased to (50~60)×10 -6, and oxygen and sulphur content in steel decreased to (4~6)×10 -6 and 15×10 -6 respectively.

采用CaC2 CaF2 法脱磷容易增碳,使后期冶炼工艺复杂,因此最好在吹氧前使用;CaC2 CaF2 也可用作喷吹SiCa粉脱磷时的覆盖渣,可起到保持还原气氛的作用。SiCa CaF2 法是唯一在工业规模上有少量应用的还原脱磷法,而且氧化脱除增加的硅比较容易。

The paper studied the scavenging active oxygen radicals of brown pigment from chestnut shell. The results showed that the brown pigment had scavenging effects on hydroxyl radical, superoxide anion radical and aliphatic radicals on lipid-peroxidation. In the range of test concentration, the maximum scavenging or inhibition rate of the brown pigment to hydroxyl radical generated by Fenton reaction, superoxide anion radical generated by illuminating riboflavin system and linoleic acid auto-oxidation was 83.0%, 82.1% and 88.5% respectively.

从清除羟基自由基和超氧阴离子自由基、抗脂质过氧化以及还原能力等方面对板栗壳棕色素的抗活性氧自由基进行了试验研究和评价,结果表明:板栗壳棕色素对Fenton反应产生的羟基自由基和光照核黄素产生的超氧阴离子自由基均具有较强清除作用,对脂质过氧化过程中产生的脂自由基和脂过氧化自由基有明显的抑制作用,且在试验浓度范围内,其最大清除率或抑制率分别可达到83.0%、82.1%和88.5%。

The outer layer consists of iron oxide and the inner layer chromium and iron oxide. The central point at hindering effect of the surface on the permeatin of hydrogen isotopes is the reduction of this oxide layer.

不锈钢表面对氢同位素透过的阻碍作用实质是该氧化层所发生的还原反应;其还原反应的程度主要依赖于与氢同位素作用的温度条件,并能够从功函数的变化中明显地反映出来。

The S entering into pellet with concentrate is pyrite, with coal powder are iron sulfide, sulphate and organic sulphur, when reducing, S existing in pyrite, iron sulfide and organic sulfur come into gas phase, then been absorbed by fresh Fe and liberate out of pellet, combined with CaO existing in outside of the pellet to form CaS finally, sulphate will remain in DRI.

当还原温度高于在铁碳相图中的最低液相线温度1147~1153℃时,渗碳作用导致DRI外壳熔化,这层致密的熔融外壳起到热态直接还原铁的防氧化作用。低于这个温度将有助于还原和脱硫。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )>Fe〓TPPS (-0.14V)>Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应,电极电位从大到小排列为:Co〓-TPPS(-0.08V)>Fe〓-TPPS(-0.14V)>Mn〓-TPPS(-0.23V),电极反应可逆性也不相同,Mn〓-TPPS是可逆过程,Co〓-TPPS、Fe〓-TPPS是准可逆过程,实验测得Co〓-TPPS的标准电极反应速率常数ks=1.4×10〓cm/s,Fe〓-TPPS的ks=1.4×10〓cm/s,电极反应的速率从大到小为:Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS,即Mn〓-TPPS最容易被溶解氧所氧化,Fe〓-TPPS被氧化的速度最慢,Ni〓-TMPyP不能被氧化,因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

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