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氧化还原

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The niobium suboxide powder was prepared by NbH reduction Nb2O5procedure, pressing to the mould, sintering and oxidation of the niobium suboxide anode, and niobium suboxide for capacitor anode with good electrical property was obtained.

摘 要:采用NbH还原Nb2O5工艺制备低价铌氧化物粉末,经压制成型、阳极烧结、阳极氧化工艺,获得电性能优良的低价铌氧化物电解电容器阳极。

This paper discusses the cause of sulphurous acid's difference between oxidation and reduction in the medium of acid and alkali, by applying the principle of normal electrode trend and thermodynamic coincidence reaction .

应用标准电极电势和热力学偶合反应原理对亚硫酸在酸碱介质中氧化、还原性不同的原因进行探讨。

In this paper we performed calculation on electrical structure of SnO2(110) surface of (1×1) and (2×1) symmetry with first principle DFT theory. We emphasized on the effect of O vacancies on surface electronic structure and future adsorption.

本文应用第一性原理密度泛函理论研究了具有(1×1)和(2×1)对称性的SnO2(110)氧化表面和还原表面的几何结构和电子结构,重点分析了表面氧空穴对表面电子结构的影响以及对气体分子吸附的影响。

In the process of laboratory study, oxycodone was prepared by oxidating thebaine at 6,14-position under oxydol, hydrodeoxidizing 7,8-position double bond and 14-position ether under palladium catalyst. Furthermore, N-methyl of oxycodone was isolated byα-chloro-ethyl chloroformate under anhydrous condition and protection of 14-position hydroxyl to obtain noroxycodone, which was further converted into methylnaltrexone by N-alkylation in presence of cyclopropyl bromomethane, then by isolating 3-position methyl of methylnaltrexone under boron tribromide, becoming hydrochloride to prepare target compound, natrexone hydrochloride.

实验室工艺方面,本文首先用双氧水氧化蒂巴因的6-位和14-位、在钯炭催化下加氢还原7-8位双键和14-位醚合成羟考酮,然后提出并优化了在无水和14-位保护的情况下,用氯甲酸-α-氯乙酯脱去羟考酮的N-位甲基合成去甲羟考酮,再用环丙甲基溴将去甲羟考酮的N-位烷基化合成甲基纳曲酮,最后采用三溴化硼脱去甲基纳曲酮的3-位甲基和成盐酸盐合成盐酸纳曲酮。

The synthesis of nalbuphine hydrochloride from thebaine as starting material was through following processes:oxidation,high-pressure hydrogenation,acetylation,removing methyl of 3-methoxy,hydrolysis,condensation,reduction and finial salification.

以蒂巴因为起始原料,经氧化、高压氢化、乙酰化、氰化、脱3-位甲氧基的甲基、水解、缩合、还原、成盐,合成了盐酸纳布啡,总收率达18。

In situ AFM follows the transformation process of redox state of polypyrrole films and the change of the surface microstructure.

利用现场AFM技术跟踪测定了聚吡咯膜由氧化态到还原态的转变过程和表面微观形貌的变化。

This article studied dispersion polymerization of the vinyl acetate in alcohol/water medium, choose potassium persulphate-sodium bisulfite as oxidized-reduction initiator.

研究了醋酸乙烯酯在醇/水介质中以过硫酸钾-亚硫酸氢钠为氧化-还原引发剂的分散聚合。

The effects of pH value, temperature, light, metal ions and additives on the stability of red pigments from waxberry were studied.

研究了pH值、温度、光照、金属离子和添加剂等对杨梅鲜汁中红色素稳定性的影响,结果表明:杨梅果汁中的红色素对酸碱度极其敏感,热稳定性差,耐氧化和还原性极差,防腐剂的消色作用较大。

Glucose is the only carbon and energy source,which is used to form biomass,and produces acetoin and by-product via redox balance.

葡萄糖作为唯一的碳源和能源物质,将沿着氧化和还原两个平行路径代谢,产生目的产物和副产物,伴生的其他终产物有2,3-丁二醇、丁二酮、乙酸、乳酸等有机酸。

Preparation of the lateral chain-4-benzyloxy-3-hydroxy butyronitrile is introduced as the substrate, the REFORMATSKY reaction is performed, then obtains the dicarbonyl ester, in the structure of which containing a chiral hydroxyl group, then performs the chiral reduction, take off the benzyl group after the protection reaction with acetonylidene,then obtains the lateral chain by oxidation.

手性侧链醛的合成:采用-4-苄氧基-3-羟基丁腈作为底物,通过REFORMATSKY反应缩合得到含有手性羟基的二羰物酯,再手性还原,丙酮叉保护后氢解脱苄,最后氧化得到侧链醛。

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