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氧化还原

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Forbidden-band-width of mono-clinic phase of bismuth vanadate (mBiVO4) is high enough to 2.3-2.4 eV, it could be valence band to carry out entirely that hole band degrade organic pollutants,and the conduction band possesses high oxidizability to make for reduction of photoinduced electron,and oxidation potential of its valence band with 2.4 eV nearby could achieve decomposition of water and degradation of organic pollutants under visible light.

单斜晶相钒酸铋(mBiVO4)的禁带宽度为2.3 - 2.4 eV,它足够高的价带完全可以实现空穴对有机污染物的降解,并且导带位置也有利于光生电子的还原,具有较高的氧化能力,且其价带氧化电位位于2.4 eV附近,可实现在可见光下分解水和降解有机污染物。本文综述了mBiVO4应用于降解污染物、光解水产氧以及光电化学分解水的研究概况,及其在光催化降解有机物等领域的应用前景。

The highest total flavonoid rate was 1.127%. An all-round evaluation for the antioxidant activity of the flavonoids extract from zizania-bract was carried out with that of ascorbic acid as the control. The evaluation indexes included the cleanup rate of the polyphenolic extract towards superoxidized anionic radicals, hydroxyl radicals, DPPH free radicals, the deoxidizing ability, and the antioxidant activity towards the peroxidize of lipids and edible oils.

采用抗坏血酸作为对照,全面测定了茭白苞叶总黄酮对超氧阴离子自由基、羟基自由基、DPPH自由基的清除率,以及还原能力、抗脂质过氧化活性和对食用油脂的抗氧化性的影响,结果表明,白苞叶中的总黄酮是一种有开发价值的天然抗氧化剂。

Aldol condensation 2, 5-dimethoxymethoxyacetophone with 2, 4, 6 -tri methoxymethoxybenzendehyde, then hydrogenation, reductive, the key intermediate 83 (84) of natural product 3, 5, 7, 2′, 5′- pentahydroxyflavan, was obtained; Mini reviewed EGCg activity, Then gallic acid and phloroglucin were used to synthsis EGCg, The key intermediate Chalcone 109 of EGCg was abtained through 7 steps from gallic acid.

重点介绍了以没食子酸为原料,经酯化,保护,还原,氧化,格氏反应,氧化六步反应得到3,4,5-三苄氧基苯乙酮,以间苯三酚为原料,经维斯迈尔反应,苄基保护,甲氧甲氧基保护三步反应得到2,4-二苄氧基-6甲氧甲氧基苯甲醛,酮106与醛108经羟醛缩合得到EGCg重要反应中间体查尔酮109。

The time of the pedogenic process was in the last ice age, therefore this area was colder and drier in climate and lower in sea level than today. The main chemical process in the soil was oxidation, a period of the formation of oxide minerals such as limonite. With the deposition and covering of the marine facies layer in the postglacial period, the soil turned into diagenetic process. Consequently the chemical process in the soil was dominated by reduction and this process was the main development period for nodules of iron-manganese carbonate to form.

成土期处于末次冰期低海面、气候寒冷干燥期,土壤的化学过程是以氧化作用为主,是褐铁矿等氧化性矿物形成时期;冰后期海相层的沉积覆盖使土壤层进入成者阶段,土壤层的化学过程以还原作用为主,成岩过程是铁锰碳酸盆结核的主要生成期。

This dissertation consists of two main parts: The first is a systematic study of the selective catalytic reduction of nitrogen monoxide with propene over tin containing oxide catalysts.

本论文分为两部分,第一部分是一氧化氮在氧化锡基催化剂上的选择还原消除;第二部分是耐高温大比表面氧化物的制备。

Finally, the article discussed the possible mechanism of multi-phase electrochemical degradation of wastewater through the XPS spectrum of the used catalysts surface: In the acid solutions, the electro-generated O_2 may get electrons on the porous graphite cathode and then form H_2O_2, H_2O_2 may diffused to the surface of catalyst and reacted with its active part to produce OH, which in turn can destruct organics. The catalyst functioned as both the catalyst to decompose H_2O_2 and the flocculants to sedimentate the degraded waste.

最后全文结合研究反应后催化剂表面的XPS光电子能谱推断了该体系降解污废水可能的反应机理:在酸性条件下,石墨双阳极产生的O_2被多孔扩散性石墨阴极还原成H_2O_2,并通过扩散传质作用在催化剂的表面活性中心分解为强氧化性中间产物·OH,强氧化性攻击有机物,使其降解为小分子有机物或CO_2和H_2O,催化剂在体系中即起催化作用也起吸附、絮凝作用。

METHODS: We measured levels of blood hydroperoxides as an indexof oxidative injury of cellular components, as well as plasmaferric-reducing ability as an index of total antioxidant potential,during sigmoidectomy under four conditions: open sigmoidectomywith sevoflurane anesthesia, laparoscopic sigmoidectomy withsevoflurane anesthesia, open sigmoidectomy with propofol anesthesia,and laparoscopic sigmoidectomy with propofol anesthesia.

在四种不同麻醉方法下乙状结肠切除术中,测定血液中的过氧化氢水平作为细胞氧化损伤的指标,以及血浆铁还原能力作为总抗氧化潜力的指标:七氟醚麻醉开腹乙状结肠切除术,七氟醚麻醉腹腔镜下乙状结肠切除术,异丙酚麻醉开腹乙状结肠切除术,异丙酚麻醉腹腔镜下乙状结肠切除术。

Background:Matrine is an active ingredient extracted from the traditional Chinese medicine called foxtail-like sophora herb and seed or sophorae radix which contains 98%of oxymatrine.Matrine is a kind of alkaloid which belongs to tetranuclear quinolizidine,and the active component is oxymatrine for it could be deoxidized easily into matrine to produce its effect at the condition of the human intestinal tract where there are bacterium,water,hot and so on.

苦参碱是从中药苦豆子或苦参根中提取的有效成分,含氧化苦参碱约98%,属四环的喹诺里西啶类生物碱,其中苦参碱为活性成分,主要是氧化苦参碱在人体肠道内菌、水、热等成分的共同影响下易被还原为苦参碱而发挥作用。

In this experiment, we use different kind of solvent to extract Vitaceae plants to test of antioxidae, includes clean DPPH free radical, ferrous ions chelating effects, restrain producing superoxide anion, ferric reducing ability of plasma and anti-liver lipid peroxidation assay.

在利用不同溶媒萃取葡萄科植物评估抗乳癌细胞株MCF-7毒杀试验和抗氧化试验中,其包含清除DPPH自由基、螯合亚铁离子、抑制超氧阴离子之生成、还原三价铁离子能力测定及抗肝脂质过氧化等几项。

The result indicated that the σ-AgFeO2 phases are the main att ribution to the surface oxygen property and CO oxidation activity of catalysts.M eanwhile,the Ag/Fe(1∶1)catalyst exhibited the highest reducibility and CO oxid ation activity among the other ratio of catalysts which resulted with the cr ystal of the σ-AgFeO2 in catalysts.

研究结果表明,催化剂上生成的σ-AgFeO2晶相结构对催化剂的表面氧性能及CO氧化反应贡献较大,同时发现,Ag/Fe(1∶1)催化剂的还原能力、氧脱附能力明显优于其他比例的催化剂,并与 CO氧化活性相对应。

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