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氧化还原

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1 A mediator modified carbon glassy electrode (NMP-GC electrode) is made by immobilizing N-methyl phenazine sulfate as the mediator on the surfase of carbon glassy electrode, which successfully catalyzes the oxidation of NADH and reduce the over-potential of NADH almost 700mv.

采用N-甲基吩嗪硫酸酯作为氧化还原介体,制作了NMP修饰的玻碳电极,将该电极用于NADH的电催化,实现了NADH在NMP-GC上的可逆氧化还原,并且将NADH在电极上的过电位降低了700mv左右。

Their electrochemical behaviors for single solute and mixed systems of hydroquinone(H2Q) and pyrocatechol are investigated.A pair of redox peak of H2Q and two pairs of redox peaks of PC on the composite film electrodes can be obviously distinguished in their mixed systems,which show the composite film electrodes have excellent electrocatalytic activity for two ...

结果表明聚苯胺复合膜电极具有很好的电催化作用,在混合体系中对苯二酚的一对氧化还原峰和邻苯二酚的两对氧化还原峰能够清楚地区分;并且在一定的浓度范围内单组分的浓度与峰电流呈良好的线性关系,说明该电极对苯二酚的测定在定性、定量中具有潜在的应用价值。

Because oxidations always go hand in hand with reduction, we refer to these reactions as redox reactions.

由于氧化反应总是与还原反应同时发生,所以我们称这些反应为氧化还原反应。

Through investigation on the Eh values of cinnamon soil,sierozem,brown desert soil in situ with new electrochemical methods and summarization of the same results of laterite,red soil and yellow brown soil,a horizontal zonal variation of oxidation-reduction characteristics in semi-humid,semiarid and arid areas from south China to north China is revealed.

用新的电化学方法原位考察了褐土、灰钙土、棕漠土、黑土、风沙土、灌淤土、盐土、碱土、亚高山草甸土、灰褐土、水稻土和旱地土壤的氧化还原状况。综合已有原位测定结果,地带性土壤的电位由南向北的空间分异与其水平地带谱相应;亚高山草甸土和灰褐土的氧化还原状况随山体高度和植物群落而呈垂直分异趋势。

Reinders' redox buffers were used to study the redox properties of sensitivity centers and latent image centers on microcrystals of cubic silver bromide emulsion in this paper.

本文采用Reinders的氧化还原缓冲液的方法研究硫敏化的立方体卤化银微晶的敏化中心和潜影中心的氧化还原性能。

Thus this method could be applied to monitor the process of producing dinitrogen pentoxide by electrochemical oxidation of dinitrogen tetroxide in nitric acid. The results from the two-step titration method of redox titration combined with acidity titration were well consistent with that from the method of redox titration combined with NMR.

氧化还原和酸度两步滴定与氧化还原滴定结合核磁共振光谱法的分析结果表明,两种方法的分析结果吻合良好,精确度良好,两种方法都可用于N_2O_4-N_2O_5-HNO_3体系各组分的全浓度分析。

While in the media of pH=3.96 Mcllvaine buffer solution and pH=7.48 KRPB buffer solution, the adrenalinequinone which is the primary electrode product of the adrenaline can take part in a series of the following chemical reactions and the final electrochemical oxidation product is adrenochrome.

肾上腺素红在电势为O伏左右时,又可进行氧化还原反应,从而在循环伏安图上又相应有一对氧化还原峰。

The Myb/MWNTs modified GC electrode can catalyse the electroreduction of O2, H2O2 and NO, with a significant lowering of overpotential.

SCE处观察到一对可逆的氧化还原峰,这是Myb的血红素辅基Fe / Fe氧化还原电对的特征峰。

This Thesis consists of the following five pacts: Following a brief Introduction on the mechanism of reactions of coenzyme NADH models with activated ethylenic compounds is discussed. Pross-Shaik treatment is employed to analyze the results.

本论文研究了:(1)辅酶NADH模型物和活化烯烃氧化还原反应的机理,并运用Pross-Shaik构型混合模型分析了这些反应的机理;(2)用辅酶NAD~+/NADH模型物催化氧化一级和二级苄醇,还原α,β-环氧酮。

The values of equilibnum constants of the complex 〓 and 〓( M = Cu, Ni)are much smaller than those of 〓 and 〓 due to steric effect of fluorenyl.

循环伏安法研究了〓和〓铜、镍配合物的电化学性质,结果表明,〓和〓铜、镍配合物中〓的氧化还原过程都是单电子准可逆氧化还原电极过程。

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