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氧化还原

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Mo isotopic signatures in sediments can be used as an indicator for redox conditions of paleo-environment and corresponding paleo-oceanography. Therefore, molybdenum isotopes can be used as a powerful tool for understanding the redox conditions of local or regional depositional environment, the biogeochemical cycle of sulfur or carbon, and the geochemical evolution of ancient oceans.

沉积物中的Mo同位素既能指示古沉积环境的氧化还原条件,也能够指示与之相关的古海洋地理环境,因此,Mo同位素是了解局域至区域沉积环境的氧化还原条件、硫和碳地球化学循环及古海洋化学演化等的强有力工具。

In this paper, firstly, a detail analysis、 study and discussion of the existing disposing-chlorine method were made, on this condition, a new method based on the way of oxidation and deoxidization was discussed, phosphoramidic acid chelate resin and DOOl cation exchange resin were chosen as framework materials, two kinds of new disposing-chlorine materials could be obtained by loading Fe~(2+) on the skeleton of the materials, the surplus residual chlorine was disposed by taking advantage of chlorine oxidizing Fe~(2+).

本文在对已有的余氯去除方法进行分析、研究、探讨的基础上,提出一种基于氧化还原方式的吸附除氯方法,实验以氨基磷酸螯合树脂和D001强酸性阳离子交换树脂为骨架材料,并对这两种材料载Fe~(2+)改性得到两种新型除氯剂,通过固载的Fe~(2+)与水中余氯(Cl_2、ClO~-、HClO)的氧化还原作用将水中的余氯除去。

Results All the NQs can activate the calcium release channel to some entent and induce Ca2+ transportation.The modulations of 1,4 NQ,1,2 NQ,1,4 NQ2S and 1,2 N are biphasic and depend on their concentrations.The mechanism of gating modulation depends on oxidation and reduction of NQ.The by-products of NQ during oxidation and reduction do not interact with RyR.

结果 所有NQ都不同程度地激活钙通道引起钙流释放;1,4NQ、1,2NQ、1,2NQ、1,4NQ 2S和1,2NQ4S对RyR的调节表现出强烈的浓度依赖性的双相作用性;NQ通过氧化还原作用调控RyR的门控机制;NQ在氧化还原循环中产生的超氧等伴生物没有参与RyR的相互作用。

In nature, some green algae can produce hydrogen after incubation under anaerobic conditions, during which hydrogenase is synthesized and activated.

自然界中存在于藻类和细菌中的氢酶是高效的催化氢气氧化和质子还原的氧化还原酶,在生物产氢和能量转换过程中发挥着重要的作用。

In nature,some green algae can produce hydrogen after incubation under anaerobic conditions,during which hydrogenase is synthesized and activated.

自然界中存在于藻类和细菌中的氢酶是高效催化氢气氧化和质子还原的氧化还原酶,在生物产氢和能量转换过程中发挥着重要作用。

The potential sources of NO in plants include nitric oxide synthase, nitrate reductase, xanthine oxidoreductase and the nonenzymatic pathway.

在植物中, NO的潜在来源包括一氧化氮合成酶、硝酸还原酶、黄嘌呤氧化还原酶和非酶促途径。

Diketoreductaseis a class of new enzyme, and compared with other oxidoreductase, whose uniqueness lies in its ability to restore at the same time reduced to two hydroxy carbonyl and a high degree of stereoselectivity.

双羰基还原酶(Diketoreductase,简称DKR)是一类全新的酶,与其他的氧化还原酶相比,其独特之处在于它能够同时还原两个羰基还原成羟基,并有高度的立体选择性。

The experiments show that TiO〓 nanowire arrays have higher photodecomposition efficiency than TiO〓 film. It is due to not only their higher surface area, but also their wider energy gap. 6. Ordered NiO nanowire arrays embedded in anodic alumina membranes have been prepared by using an electrochemical deposition method. Thermogravimetry curve shows that NiOH embedded in AAO decomposed slowly compared to thin film.

可能存在两个原因:氧化钛纳米丝具有比氧化钛纳米膜更大的比表面积;氧化钛纳米丝的光学带隙大于氧化钛纳米膜的,带宽的增加,使得价带电子电位变得更正,导带电位变得更负,这实际上增加了光生电子和空穴的氧化还原能力,提高了半导体光催化氧化有机物的活性。

The nanocrystalline film was composed of a three-diminsional network of interconnected particles.Reodx behavior and electrocatalytic activities of the Ti/nano-TiO2 electrode were investigated by cyclic voltammetry from oxalic acid and nitrobenzene to glyoxalic acid and p-aminionphenol. The Ti/Ti redox system,as a medium,shows highly electrocatalytic activities and stable characteristic to indirect electroreduction of organic compounds(e.g.:oxalic acid and nitrobenzene).

循环伏安法研究了纳米TiO2膜电极对草酸还原为乙醛酸、硝基苯还原为对氨基苯酚反应的电催化活性,结果发现纳米膜中的Ti/Ti氧化还原电对起一种中介作用,可使有机物如草酸和硝基苯间接电还原,且电极催化活性高,性能稳定。

In range of 300℃~900℃, all the transition metal oxide catalysts could get high ammonia conversion, during the initial stages of the reaction, the SO〓 conversion is relatively low since the catalysts have not been sulfureted, but it increases gradually and attain constant with rising temperature and time continuance,〓 is better than other catalysts in reactivity and elemental sulfur selectivity; XRD indicates that, in the SO〓-SCR process, stable transition metal sulfide is generated which is very important to SO〓 reduction and transition metal sulfide probably is the active phase of catalyst, further the reduction of SO〓 by H〓 to H〓S is the limiting step of all process, then the activity is somewhat related to its lattice oxygen yet not so notable; XPS indicates that little sulfur on surface exists as S〓 in sulfate, showing that TiO〓 could restrain the generation of sulfate.

对于过渡金属氧化物催化剂的研究发现,在300℃~900℃范围内,不同的催化剂均可获得很高的NH〓转化率,反应初期由于催化剂还未硫化,所以SO〓的转化率较低,随着温度升高和反应时间的延续,SO〓的转化率逐渐升高并达到了稳定值;七种过渡金属氧化物中,以〓对于NH〓还原SO〓反应的活性和选择性最好;XRD结果表明在NH〓-SO〓反应后生成了稳定的硫化物相,硫化物对SO〓的还原过程具有重要作用,催化剂的活性相可能是过渡金属硫化物,而且在硫化物催化剂上进行的H〓还原SO〓生成H〓S的反应是整个过程的速率控制步骤,所以催化剂的活性与其自身的晶格氧的氧化还原能力有一定的联系,但关系不明显;XPS结果表明催化剂表面的硫大部分以过渡金属硫化物的形式存在,只生成少量的S〓,说明TiO〓催化剂能够较好的抑制硫酸盐的生成。

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