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氧化过程

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The vascular adventitia is involved in the pathological process of intimal hyperplasia, and oxidative stress caused by increased NADPH oxidase activity may be one of the mechanisms.

血管外膜参与了内膜病变形成的病理过程;NADPH氧化酶活性升高导致的氧化应激可能是外膜损伤致内膜病变的机制之一。

In the course of oxidation, reaction temperature should rise step by step, and in the late stage, reduced pressure distillation should follow so that the concertration of gly oxalic acid can rise and production rate of allantoin can rise up to 40%.

在氧化反应的过程中逐步地提高反应温度,反应后期进行减压浓缩,提高了乙醛酸的浓度,缩短了氧化时间,并使尿囊素産率达到40%。

Secondly, the influence of products and impurities in the propylene epoxidation process on the anthraquinone route was also investigated.

其次,实验研究了环氧化产物和杂质对蒽醌工作液氢化、氧化反应的影响,并对过程集成中萃取后工作液的干燥脱水进行了实验研究。

There are three effects that may be important in producing this trend. First, lowtemperature oxidation preferentially affects the finer single-domain magnetites responsible for the Hopkinson peak, which is therefore suppressed in the more oxidized loams. Second, the possible production of uniaxial magnetite with shape anisotropy can also lead to a relatively muted Hopkinson peak. There is, additionally, a third alternative, and the one preferred here, that the natural alteration processes involved in pedogenic susceptibility enhancement have probably depleted the supply of ironbearing precursor phases, so that less new magnetite is formed on heating.

产生这种特殊热磁性质的可能原因如下:第一,成土过程中的低温氧化作用减弱了磁铁矿的Hopkinson效应;第二,可能是成土过程中生成的一向延长的针状磁铁矿颗粒表现出较弱的Hopkinson效应;第三,随着成土作用增强,现代黄土、黑垆土中的硅酸盐、粘土矿物因受土壤化作用分解而越来越少,加热过程中分解产生的磁铁矿造成的磁化率增强相对于其初始磁化率也就越来越小,从而产生越来越弱的Hopkinson/alteration峰,本文认为这是最主要的原因。

The results show that the thermal degradation process of polystyrene initiates from chain end scission, and styrene dimer is the residual of degradation of polystyrene; Different catalysts have different catalytic activity on the degradation process of polystyrene, among which barium oxide is the best.

作者利用热重质谱法对聚苯乙烯热降解和催化降解过程进行了研究,得出以下结论,聚苯乙烯的热降解过程主要由链端断链反应引发,苯乙烯二聚体可能是聚苯乙烯降解结束阶段的剩余物;不同催化剂在聚苯乙烯降解过程中具有不同的催化活性,其中氧化钡的催化活性最高。

The expression of one-dimensional mathematical model of vertical migration of ammonia in the CRI system is:The parameters in the CRI model are determined as following: the retardarce coefficient is determined by static isothermal absorption experiment, the velocity of sewage travel through the soil column is determined by permeability test, the vertical dispersion coefficient is determined by test the electric conductivity of tracer in the dispersion experiment, the rate of nitrification and denitrification is determined by test of Baps technology.

依据单一氨氮、硝氮配水条件下的试验结果,引入多孔介质的溶质运移理论及对流-弥散方程,考虑NH4+-N在CRI系统中的运移受到对流和水动力弥散作用的影响,并吸附-解吸、硝化与反硝化3个过程,首次将配水流经CRI土柱的孔隙水流速方程与CRI土柱内发生的、以氧为约束条件的硝化、反硝化过程联系起来,建立了CRI系统一维垂向氨氮运移转化数学模型,表达式为:研究分别通过静态等温吸附实验率定了模型方程中的阻滞系数、通过渗滤试验测定了土柱中的孔隙水流速、通过测定弥散试验中示踪剂的电导率确定了纵向弥散系数、通过气压过程分离技术测定了土柱中的总硝化与反硝化反应速率常数,最后通过测定土柱沿程氧化-还原电位的方法分析氨氮在CRI系统中的运移转化机理。

The results show that the surface layer of the air-exposed ZrVFe getter is covered with H20, CO2 and hydrocarbons, both Zr and V exist in the oxidized state, and vanadium oxide starts to reduce at 200℃. The activation results in the enrichment of Zr on the getter surface and the formation of the metallic carbides. H2O, CO2 and hydrocarbons sequentially desorb from the surface with the increase of temperature. H2 is the main gas which desorbs above 200℃ and O2 is not discovered. ZrO2 is reduced to near-metallic or metallic state because O in ZrO2 leaves the getter surface through diffusing into getter bulk.

结果表明:暴露于过大气的吸气剂表面覆盖着H2O、CO2及碳氢化合物等,Zr和V主要以氧化态存在;在吸气剂加热激活过程中,V的氧化物在200℃开始还原;激活过程导致表面近金属态Zr的富集以及部分金属碳化物的生成;随着温度的升高,H2O、CO2及碳氢化合物逐渐从吸气剂表面脱附,在200℃以上,主要脱附气体为H2,整个激活过程未发现O2;ZrO2还原为近金属态或金属态,主要是由于ZrO2中的O通过向吸气剂内部扩散而离开吸气剂表面所致。

I.S.P is the typical complex and continuous production process. Based on the peculiarity of I.S.P: physical chemistry reaction is quite complex, operation condition is comparatively rigid, the charging ration needs to be exactitude. Temperature variety of zones in furnace including: warm-up charging zone, re-oxidation zone, revivification zone, slag smelting zone, The soft point and soft zone are the key factors, which have an effect on the smelting of ISP and it is a comprehensive parameter appraising the quality of sintered aggregate.

基于密闭鼓风炉铅锌冶炼生产过程特点:物理化学反应十分复杂,操作条件比较严格,入炉物料的配比要求也非常精确,是典型的复杂连续生产过程;论文分析了炉内各带的温度变化:料预热带、再氧化带、还原带、炉渣熔化带;分析、总结了影响鼓风炉生产的因素:鼓风制度(富氧熔炼、预热鼓风熔炼)、炉料的性质对熔炼过程的影响(烧结块、焦炭的性质及消耗)、鼓风炉操作的影响因素(鼓风炉系统、鼓风量与风温调节、炉前操作、冷凝分离系统、煤气洗涤系统、电热前床)。

During wear process, not only chemical and mechanical change such as oxidating and breaking etc. take place in debris, but also metallurgical course such as adhesing especially hot press sintering at small areas in debris because of hot extruding.

磨损过程中磨屑不仅存在氧化、碎化等化学、机械过程,还存在因相互挤压、粘结甚至微区热压烧结等冶金过程,两方面的共同作用,使氧化物磨屑成分均匀化。

The following main results are obtained: The TiO_2 photocatalyst with small crystallite size, high surface area, narrow and uniform pore size distribution, and microporous frameworks could be prepared out by applying MW radiation in the preparation process. The microwave-induced fluorescence technique verified for the first time that microwave enhanced the formation rate of hydroxyl radical, leading to the increase in the photocatalytic efficiency. Compared with the conventional catalyst, TiO_2 prepared by MW dielectric heating owns a higher UV absorption ability, and its optical absorption edge and photovoltaic response are shifted toward the short wavelength region, resulting in increase of photooxidation efficiency. The photocatalytic conversion and the mineralization ratio of acetaldehyde are increased respectively by 30% and 40% over the TiO2 prepared by MW radiation when compared to the TiO2 prepared by the conventional heating. For the MW-assisted photocatalytic reaction over the MW-prepared TiO2, production of hydroxyl radicals is enhanced by 22.5%, and the photocatalytic conversion is accordingly increased by 20%. Similarlly, applying MW also increased the photocatalytic conversion and the mineralization ratio of acetaldehyde over TiO2/Al2O3 sample.

论文得到如下主要结果和结论:(1)微波介电加热TiO_2 溶胶可得到晶粒度小、光催化活性高、比表面积大和孔径分布窄而均一,且微孔发达的TiO_2光催化剂;在溶胶干燥处理过程中微波可使催化剂表面缺陷增加,进而导致光催化反应过程有更多的活性羟基自由基产生;(2)微波制备能显著增强TiO_2 样品的紫外光吸收率,并使其光吸收和光伏响应阈值发生蓝移,从而提高TiO_2的氧化还原能力;(3)与常规加热法所制TiO_2比较,微波法制备的TiO_2对乙醛的光催化降解转化率提高30%,CO_2生成率提高40%以上;(4)与未加微波辐射时相比,发现在光催化反应过程中施加微波,TiO_2 的羟基自由基生成速率提高了22.5%,相应CH_3CHO 光催化降解转化率提高了20%;对Al_2O_3/TiO_2催化剂,CH_3CHO 光催化降解转化率甚至提高了33%,同时CO_2 的生成率也都大幅度提高;(5)微波辐射可改变光催化降解乙醛的产物分布,推断施加微波时乙醛光催化降解按照羟基自由基引发的链式反应机理进行,微波&非热效应&起主要作用。

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