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The drying process of chrome liquor was studied. The structure and property of chrome complex reducing by alcohol were analysed and tokened by many present well-rounded separation and analysis methods such as IR, UV-Vis Spectrum, IEC and pH potentiometry. Application tests of chrome tanning agents were conducted and tanning methods of tanning at high pH were studied. A systematic study was conducted on high alkalinity chrome tanning agents application in leather making process and possibility of clean chrome tanning was discussed.

本文系统地研究了多种小分子醇与重铬酸盐之间的氧化-还原反应,对反应过程进行了认真的剖析;对铬鞣液的干燥过程进行了研究;用红外光谱法、紫外及可见分光光度法、离子色谱法以及pH电位滴定法等多种比较成熟的现代分离分析方法相结合,对醇还原铬配合物的结构与性能进行了分析与表征;对铬鞣剂的鞣革性能进行了应用实验,研究了醇铬鞣剂在高pH值下的鞣制方法,并就高碱度铬鞣剂在制革过程中的应用进行了系统研究,探讨了用其实施清洁化铬鞣的可能性。

The drying process of chrome liquor was studied. The structure andproperty of chrome complex reducing by alcohol were analysed and tokened by manypresent well-rounded separation and analysis methods such as IR, UV-Vis Spectrum,IEC and pH potentiometry. Application tests of chrome tanning agents wereconducted and tanning methods of tanning at high pH were studied. A systematic studywas conducted on high alkalinity chrome tanning agents application in leather makingprocess and possibility of clean chrome tanning was discussed.

本文系统地研究了多种小分子醇与重铬酸盐之间的氧化-还原反应,对反应过程进行了认真的剖析;对铬鞣液的干燥过程进行了研究;用红外光谱法、紫外及可见分光光度法、离子色谱法以及pH电位滴定法等多种比较成熟的现代分离分析方法相结合,对醇还原铬配合物的结构与性能进行了分析与表征;对铬鞣剂的鞣革性能进行了应用实验,研究了醇铬鞣剂在高pH值下的鞣制方法,并就高碱度铬鞣剂在制革过程中的应用进行了系统研究,探讨了用其实施清洁化铬鞣的可能性。

The electropolymerization of Cobalt tetraaminophthalocyanine on gold electrode has been studied by cyclic voltammetry and electrochemical quartz crystal microbalance.

采用循环伏安法和石英晶体微天平技术对四氨基钴酞菁在金电极上的聚合成膜过程进行了研究,考察了扫描速度、溶剂、支持电解质及单体浓度对其成膜过程的影响,同时初步探讨了聚合膜分别在非水溶液和水溶液中的氧化还原行为及稳定性,其中借助EQCM重点讨论了在这些过程中溶液中离子在膜中传输的机理。

In this process, the discharge process of single point to point contact is transformed to the process of both point to point contact and the overall surrounding contact of sphere Ni through the self redox reaction, thus making a highly efficient electron transfer process. In this dissertation, the catalytic electrolysis mechanism is discussed. The influence of various parameters (e.g. kind and concentration of catalyst, reaction temperature and electrolysis duration) on electrolysis were investigated.

本文首次提出了以KMnO_4为代表的高锰酸盐作为电解过程电子传递的媒介,通过锰盐自身氧化还原反应的参与,在阳极和溶液中的球形Ni_2之间建立起高效的电子转移过程,使球形Ni_2和阳极之间单一的固体之间的点点接触放电,转变为点点接触放电和球镍与溶液全方位包围接触放电过程,大大提高了电解过程的效率。

In this study,the changes of phenolic compounds ,phenylalanine ammonia-lyase,peroxidase and polyphenol oxidase activities during malting(including steeping,germination and kilning) with three domestic barley varieties were investigated,and the relationships between changes of phenolic content and enzyme activities and malting technics were analysed.

研究了3种典型国产啤酒大麦在麦芽制造过程中酚类物质及其相关酶类(苯丙氨酸解氨酶:phenylalanine ammonia-lyase,PAL、过氧化物酶:peroxidase,POD和多酚氧化酶:polyphenol oxidase,PPO)的变化,分析了制麦过程中酚类物质含量的变化与酶活力和制麦工艺之间的关系,讨论了大麦发芽过程中苯丙氨酸解氨酶在合成酚类物质方面的作用及过氧化物酶对根芽生长和制麦损失的影响。

Phenolic compounds and related enzymes in barley influence its growth and brewing processes.In this study,the changes of phenolic compounds,phenylalanine ammonia-lyase,peroxidase and polyphenol oxidase activities during malting(including steeping,germination and kilning) with three domestic barley varieties were investigated,and the relationships between changes of phenolic content and enzyme activities and malting technics were analysed.The functions of PAL on biosynthesis of phenolic compou...

研究了3种典型国产啤酒大麦在麦芽制造过程中酚类物质及其相关酶类(苯丙氨酸解氨酶:phenylalanine ammonia-lyase,PAL、过氧化物酶:peroxidase,POD和多酚氧化酶:polyphenol oxidase,PPO)的变化,分析了制麦过程中酚类物质含量的变化与酶活力和制麦工艺之间的关系,讨论了大麦发芽过程中苯丙氨酸解氨酶在合成酚类物质方面的作用及过氧化物酶对根芽生长和制麦损失的影响。

The lipid oxidation of the muscles of breast and leg in dry-cured duck during processing was studied by determination of the peroxide value,TBARS value,carbonyl compounds and conjugated dienes.

通过对过氧化值、硫代巴比妥酸值、羰基值和双烯值等氧化指标的测定,研究南京板鸭加工过程中各工艺点板鸭肌肉脂肪的氧化变化。

In the selective oxidations, Manganese porphyrin mimic enzyme systems supported on different inorganic supports are designed and developed, which are applied in studies of green processes, such as, the selective olefin epoxidation with oxygen in either ionic liquid or water, the oxidation of alcohols.

在选择性氧化反应中,设计制备了不同无机载体的锰卟啉模拟酶体系,分别在离子液选择性和水相中开展了以氧气为氧源的烯烃环氧化、醇的氧化等绿色反应过程的研究。

Laccase (benzenediol: oxygen oxidoreductase: EC 1.10.3.2) is a type of multi copper-containing polyphenol oxidases capable of oxidizing a wide range of polyphenols and other lignin-derived aromatic compounds, and the enzyme is involved in lignin degradation and in the development of soil humus.

漆酶(EC 1.10.3.2,对苯二酚:氧氧化还原酶)是一种含多个铜原子的多酚氧化酶,催化氧化多种芳香族化合物,在木质素矿化降解、腐殖质形成等过程中发挥重要作用。

For ozonolysis, the SOA yield has not been changed by inorganic seed aerosol, because the products are mainly carboxylic acids, which has much lower saturation vapor pressure and thus easily undergo homogeneous nucleation or gas-particle partitioning to be in the aerosol phase.

而对于α-蒎烯臭氧氧化的过程,实验结果表明,干态硫酸铵颗粒物种子的存在对SOA产率无影响,对臭氧氧化生成的SOA分子鉴别的结果表明,可鉴别组分中有很高比例的有机羧酸类物质,这一比例远高于光氧化产物,这些有机酸具有较低的挥发性而极易形成颗粒相,并且不参与异相酸催化反应。

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