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The results show that the periodic average yield of acrylonitrile under any forced periodic oscillation of oxygen concentration among this experimental conditions,thus obtained could higher than that under the steady-state condition.

而为完成整个氧化还原循环过程,气相氧分子就必须在不同丙烯吸附中心的再氧化中心上吸附,获得电子,解离后扩散进入催化剂中的阴离子孔穴,如图1所示。从该机理可知,反应气氛中的氧烯比大小对催化剂表面的氧化还原反应过程的循环有重大影响。

Because of the chief equipment and technic are mostly imported from the abroad presently. It is necessary to lucubrate oxidation mechanism of calcium sulfite and the main influencing factors in the oxidation of calcium sulfite, which are valuable for accelerating the oxidation Rate, consummating academic basic of lime stone-gypsum FGD and optimizing technical process A simulate equipment has been designed based on the theory of geometrical comparability which is reduced scale in geometric proportion to the 300MW capacity.

目前我国的湿式石灰石–石膏法设备和技术均从国外引进,因此深入研究脱硫过程中亚硫酸钙的氧化机制和影响亚硫酸钙氧化的主要因素,对提高氧化速度、完善湿式石灰石–石膏法脱硫技术的理论基础、优化烟气脱硫工艺过程具有重要的价值。

This article mainly explains the safety principium of infectant factors in waste water vented by the paper making industry in China. Through the study on the experiment in open country and indoors with soil pole, indicating that it is a complicated process of biochemical degradation to form a layer, which has a biochemical capability to process COD degradation in polluted water from paper making industry.

综述我国造纸业污水中的污染因子危及地下水水质安全的机理,通过对野外试验和室内土柱试验的过程及结果进行分析研究,表明在包气带中形成一个以生物化学作用为主的生化层在造纸污水中COD降解是一个复杂的生物化学降解过程;生化层在天然状态下形成,由生物氧化带和生物氧化还原带形成,其形成过程具有明显的阶段性;只有当生物氧化还原带形成后,生化层才发育成熟,具备对COD降解的生化能力;生化层空间分布,仅局限在污水池、渠底部包气带中有垂向渗流的部分。

The paper studied that HACCP projects was established,critical control point was controlled,hazard analyzed was evaluated in oxidation starch procedure in production,filtration,bath and dehydration,sirocco desicalion,metal detect were confirmed as critical control points, critical limits ,monitor procedures,corrective actions were established,as was that the safety and quality were improved.

对氧化淀粉生产过程进行危害分析评估、关键控制点控制及相对应的HACCP计划的制定进行探讨,确立了湿法生产氧化淀粉过程中的过滤、水洗脱水、热风干燥和金属探测4个关键控制点,制定了相关的关键限值、监控程序和纠编措施,从而为提高氧化淀粉生产过程中的质量和安全性提供保障。

The major results of this proposal are as follows:(1) ABA induces a rapid, substantial accumulation of apoplastic H2O2 in mesophyll and bundle sheath cells of maize leaves, and the accumulation of apoplastic H2O2 is involved in the induction of the chloroplastic and cytosolic antioxidant enzymes.(2) ABA-induced H2O2 production activates a 46 kDa MAPK, which in turn induces the expression of antioxidant genes and up-regulates the activities of antioxidant enzymes. The activation of MAPK also enhances H2O2 production, forming a positive amplification loop.(3) Water stress also induces the activation of a 46 kDa MAPK, which is dependent on the accumulation of ABA and H2O2 production induced by water stress and involved in the up-regulation of the expression and the activities of antioxidant enzymes.(4) ABA-induced H2O2 production mediates NO generation, which in turn activates a 46 kDa MAPK and results in the up-regulation in the expression and the activities of antioxidant enzymes in ABA signaling. NO-independent signaling is also involved in ABA- and H2O2-induced antioxidant defense.

本项目的主要研究结果如下:(1)ABA诱导的H2O2产生主要出现在叶肉细胞与维管束鞘细胞的质外体中,质外体H2O2的积累能够上调叶绿体与细胞溶质中抗氧化酶的活性;(2)ABA诱导的H2O2产生活化一个46kDa的MAPK,由此而导致编码抗氧化防护酶基因的表达与酶活性的上调;而MAPK的活化也能增强H2O2的产生,从而形成一个正的反馈调节环;(3)水分胁迫也能诱导一46kDa MAPK活化,这一MAPK活化依赖于水分胁迫诱导的ABA积累以及H2O2的产生,同时参与水分胁迫诱导的抗氧化防护基因的表达与抗氧化酶活性的上调;(4)ABA诱导一个依赖于H2O2的NO产生,NO活化一个46kDa的MAPK,从而导致抗氧化防护基因的表达以及抗氧化酶活性的上调;同时一个不依赖于NO的信号转导途径也存在于ABA诱导的抗氧化防护过程中。

Composition of suspension will chang from titanium monoxide to titanium dioxide during standstill procedure. Experimental results show that the proposed method can successfully prepare the anatase phase of titanium dioxide .In the photocatalysis experiment, the prepared titanium dioxide nanofluid absorbs the Ultraviolet when light wavelength was 360 to 380 nm. Adsorption experimental results show that the efficiency of absorbing methylene blue using TiO2 is higher than that for TiO2 (Degussa P-25) or ZnO. Depigmentation of methylene blue experimental using TiO2 can depigmentize methylene blue reach 100% in 60 min.

悬浮液所含之奈米颗粒在静置过程中,成份方面会由似一氧化钛转变为二氧化钛;在结晶组成方面,所制备之二氧化钛颗粒之结晶组成为锐钛矿结构;在光催化方面,所制备之奈米二氧化钛悬浮液在光波长360nm~380nm时产生吸收紫外光现象,在吸附实验中本制程所制备的二氧化钛颗粒的吸附效果优於商用的二氧化钛及氧化锌,在亚甲基蓝的脱色实验中本制程所制备的二氧化钛颗粒能在60分钟内达到脱色率100%。

These sug- gested that this model has an excellent reproducibility and representativeness and is an ideal model for study of gunshot wound at maxillofacial region; Intensification of early management after damage of tissue can help achieve good curative effect.

对一氧化氮特殊生成途径—L-精氨酸/一氧化氮途径改变引起的NO生成量的变化与机体内多种生理和病理过程的关系的研究,使人们对这些过程的发生、发展的机制有了更加深入的认识;许多细胞因子也是通过对L-精氨酸/一氧化氮途径的影响而发挥调节作用。

The results from electron micrographic analysis show that soot oxidation is influenced by aggregation and agglomeration of soot particulates, at the same time, the crystallograms show that the previous soot particle is non-crystal carbon, but in the latter conbustion period, a very small amount of crystal soot with unstable lattice at relatively higher flame temperature is formed. The crystallization happens greatly in period of combustion when temperature is relatively lower. The smoke particulates consist of crystal carbon similar to chaoite crystal latice and noncrystal carbon.

碳粒浓度和KL变化曲线表明预混合火焰中碳粒浓度远远小于扩散火焰,其原因在于不均匀的燃油—空气混合气结构在高温缺氧条件下产生大量碳粒,在温度峰值附近碳粒浓度亦达到峰值,其后迅速氧化,当温度低于2000°K时碳粒基本上不氧化,碳粒的电子显微分析表明碳粒的氧化受碳粒的集聚过程的影响,在燃烧初期碳粒是非晶体,碳粒的结晶在燃烧后期和排放过程中大量出现,排放碳烟微粒由晶体和非晶体碳组成。

Interlayer oxidized zone can be divided accurately by Fe_2O_3, Fe_2O_3/FeO and U parameters. We can correct the field macroscopic color zoning by combining the macroscopic zoning and microscopic zoning. Univalent major elements components(Al_2O_3, SiO_2, K_2O, Na_2O) show remarkable activity at the process of interlayer oxidizing, their contents are variable and mingled in different zones and it can't be used in zoning. But we can speculate the developmental degree of interlayer oxidized zone and uranium mineralization according to the concentration trends and variation characteristics of sensitivity group, activity group and their ratios .(3)The comparatively steady elements such as lithiphile elements, sulfophile elements and high field strength elements change regularly at the process of interlayer oxidation except some radioactive elements. Trace elements and rare earth elements commonly enrich in thin rock clast such as mudstone, in which the enriched elements species are more than those in the whole rock, which indicate that the regeneration action in caulking matter are more deep than that in whole rock at the process of interlayer oxidation, and the reallocate intention of trace elements in main minerlized rock in Tuha basin are more intensive than that in Yili basin at the process of deposition ,diagenesis and later changes .

根据化学蚀变参数PC值和分离迁移位等将常量元素组分分为敏感组分组、活动组分组、次活动组分组和惰性组分组,不同组分可分别用于讨论层间氧化带低温地球化学中不同问题;敏感组分(变价元素组分Fe_2O_3、FeO)和U在层间氧化带中迁移富集规律明显,Fe_2O_3/FeOFe~(3+/Fe~(2+)比值具分带判别能力,配合U含量对层间氧化带进行较准确的分带,可克服野外宏观颜色分带偏差:提出Fe~(3+)/Fe~(2+)分带判别值在不同盆地、不同地段不同,除受氧化作用控制外,流体酸碱度不同也是重要因素的观点,对找矿实践有实际指导意义;活动组分(Al_2O_3、SiO_2、K_2O、Na_2O)在层间氧化作用过程中具有较明显的活动性,其含量值变化跳跃,在不同分带相互交织,不具分带指示意义;但利用敏感组分、活动组分及其比值在层间氧化带中的变化特征可推测层间氧化带发育的完善程度及其含矿性;次活动组分组(CaO、MgO、MnO_2)含量低,变化规律性差;惰性组分组(TiO_2、P_2O_5)含量低,活动稳定,可用来反映沉积物源特征。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )>Fe〓TPPS (-0.14V)>Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应,电极电位从大到小排列为:Co〓-TPPS(-0.08V)>Fe〓-TPPS(-0.14V)>Mn〓-TPPS(-0.23V),电极反应可逆性也不相同,Mn〓-TPPS是可逆过程,Co〓-TPPS、Fe〓-TPPS是准可逆过程,实验测得Co〓-TPPS的标准电极反应速率常数ks=1.4×10〓cm/s,Fe〓-TPPS的ks=1.4×10〓cm/s,电极反应的速率从大到小为:Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS,即Mn〓-TPPS最容易被溶解氧所氧化,Fe〓-TPPS被氧化的速度最慢,Ni〓-TMPyP不能被氧化,因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

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