氧化磷

On dephosphorization was analyzed and the appropriate composition of the flux was determined. The results show that oxidizability and basicity have reverse effect on dephosphorization and the dephosphosphorization ratio of 50 % and phosphorus c...

实验结果表明：氧化性和碱度是影响脱磷效果的两个制约性因素；在钢水初始磷含量为0 01%左右的条件下，使用该渣获得了大于50%的脱磷率及低于0 005%(最低可达0 0027%)的磷含量；在300t转炉上进行的初步生产试验也获得了50%左右的脱磷率及0 006%左右的成品磷含量。

There is an oxidation process in two determination methods of total N and total P, so the samples＇liquation and oxidation processes can be done simultaneously, and the standard curve can be acquired simultaneously by confecting blended standard solution, which simplifies the determination process of total N and total P.

由于二者测定时都存在将含氮、含磷化合物转化为硝酸盐和下磷酸盐的氧化过程，因此本研究考虑将污泥样品消解和样品的氧化过程同时进行，标准曲线也可以通过配制混合标准溶液来同时测定，这使得总氮、总磷测定流程得以简化。

The contents of organic matter, total nitrogen, phosphorus, iron, manganese, copper, zinc can be increased, and the contents of hydrolizable nitrogen and their forms , Fe-P, Al-P, Ca〓-P, all organic P forms, exchangeable and organic iron, manganese, copper, zinc are increased obviously in long-term application organic manure soil. Not only the contents of soil readily oxidizable carbon, humic acid, fuluic acid, and HA/FA value are increased and Kos value decreased but also the available nitrogen, phosphorus, iron, manganese, copper, zinc are kept more high level in the organic manure soils. Long-term mulching straw has similar role with organic manure for soil nutrient except for decreasing total phosphorus, available P, N and Ca〓-P, but its fertilizer efficiency is not better than organic manure.

有机肥还具有提高土壤易氧化碳和松结态腐殖质含量，降低kos值，提高土壤HA、FA含量及其比值的作用，使土壤中有效态氮、磷、铁、锰、铜和锌含量处于中上等水平；长期秸秆还田除了不增加土壤全磷、有效氮和磷等外，对其他养分的作用效果与有机肥相似，但其肥效不如有机肥；长期氮磷化肥单施，土壤全氮和磷增加，有机质、铁、锰、铜和锌含量下降，易氧化碳、松结态腐殖质、HA和FA含量、kos和HA/FA值下降；长期不施肥土壤有机质、全氮等养分处于消耗状态。

The results show that a little amount of heteropolymolybdovanadophosphate can remarkably speed the degradation, the best conditions of the oxidative degradation of chitosan with hydrogen peroxide catalized by heteropolymolybdovanadophosphate in homogeneous condition are as follows: the ratio of catalyst and chitosan is 1 to 10, concentration of hydrogen peroxide is 0.15%, the temperature is 80℃, reaction time is 2h. 0.2g chitosan was degraded under the best condition and the molecular weight by viscometry was degraded from 1460000 to 7812. then water-soluble chitosan was obtained by this method; The heterogeneous method is a high efficient way, the best condition of this method are as follows: the ratio of catalyst and chitosan is 2 to 100, the volume of 30% hydrogen peroxide is about 3mL, the temperature is 90℃, reaction time is 5min～30min.

研究结果表明，适量磷钼钒的存在可显著加速壳聚糖的降解，磷钼钒催化过氧化氢均相氧化降解壳聚糖的适宜反应条件是：催化剂与壳聚糖的质量比为1∶10、过氧化氢百分浓度为0.15％、反应温度为80℃、反应时间为2h，在此条件下对0.2g溶解在100 mL 0.5％稀醋酸中的壳聚糖进行降解，可使壳聚糖的粘均分子量由原来的146万下降到七千多(7812)，成为水溶性低分子量壳聚糖，从而达到应用的要求；在异相条件下以磷钼钒为催化剂催化过氧化氢氧化降解壳聚糖是一种高效快速的方法，此法降解壳聚糖的最佳反应条件是：催化剂与壳聚糖的质量比为2∶100；30％过氧化氢的用量为3mL左右；反应温度为90℃、反应时间为5min～30min。

The results indicate that the Ca and P ions are incorporated into the anodized alumium oxide during the anodization process, and the incorporated Ca and P are reacted to be calcium phosphate after hydrothermal treatment. The calcium phosphate grows from the holes of AAO and covers the surface of AAO layer.

结果表明：在阳极氧化过程中，钙、磷元素嵌入阳极氧化铝膜，并经水热处理反应原位生成钙磷陶瓷；钙磷陶瓷晶体从Al2O3孔洞长出并覆盖于多孔氧化膜的表面；最终获得的钙磷生物陶瓷/多孔Al2O3复合涂层具有纳米网状、多孔的结构特征。

The traditional Passveer single ditch and Carrousel ditch are not good at removable N and P, but in the front of anaerobic pond is intercalated, and anoxic area is intercalated in, Carrousel Oxide Ditch becomes a mendable Carrousel 2000 Oxidation Ditch, so it possesses removal removal nitrogen and phosphorus by biology function.

传统的Passveer单沟型和Carrousel型氧化沟脱氮除磷功能差，但是在Carrousel氧化沟前增设厌氧池，在沟体内增设缺氧区，形成改良型Carrousel 2000氧化沟，便具备生物脱氮除磷功能。

In order to develop a liquid oxidation desulfurization technique, the characteristic of desulfurization of sodium Phosphomolybdate absorbent system was investigated by the method of dynamic tail-gas H,S concentration detection and the regeneration behavior of the same system was investigated by the method of redox poteatial detection.

以液相氧化脱硫工艺开发为目的，采用尾气H2S浓度动态监测法研究了磷钼杂多化合物脱硫体系的脱硫特性；采用氧化还原电位监测法研究了该体系的再生规律结果表明，磷钼酸钠体系的脱硫性能随温度升高而有所降低，随进气H2S浓度的提高而相应降低，随吸收剂浓度的提高而显著增强。

On the basis of ascertaining that phosphomolybdic acid modified platinum electrode has higher catalytic activity to methanol oxidation , three kinds of transition metal substituted phosphomolybdic acids were synthesized, and the IR spectrum indicated that the compounds still kept Keggin structure.

在证实了磷钼酸修饰铂电极对甲醇氧化具有较高活性的基础上，合成了3种过渡金属取代的磷钼酸，通过红外光谱测试仍为Keggin结构，并制备了过渡金属取代磷钼酸修饰铂电极，研究了修饰铂电极在硫酸溶液中的电化学行为及对甲醇的催化氧化作用。

Molybdophopsphoric Acid Catalysis in the Oxidative Cleavage of Olefins by the Hydrogen Peroxide Oxidative cleavage of the double bond could be catalyzed by H_3PMo_(12)O_(40) using H_2O_2 as oxidant, various trisubstituted olefins were oxidized to aldehydes or ketones in high yields. The system was not satisfied for electron-deficient olefins such as trans-(2-nitrovinyl) benzol or chalcone. The reaction of aliphatic olefins did not occur under the same conditions.

二、磷钼酸催化过氧化氢对烯烃的氧化断裂反应用过氧化氢(30％)作为氧化剂，磷钼酸可以催化氧化碳碳双键的断裂反应，三取代的烯烃被氧化生成醛或酮，产率较高；此体系对于缺电子烯烃如查尔酮，不饱和硝基化合物的断裂反应效果较差，脂肪族烯烃在此体系下的氧化并不发生。

A method for the determination of silicon and phosphorus in antimony oxide by inductively coupled plasma emission spectrometry ICP-AES was reported. he sample dissolution methods, election of spectral lines, interference of coexistent elements and the working parameters of the instrument were studied.

通过对氧化锑试样分解方法、硅磷分析线选择、共存元素光谱干扰和仪器最佳分析条件等方面的研究，建立了电感耦合等离子体原子发射光谱法测定氧化锑中硅和磷的方法。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。