氧化物

This dissertation consists of five chapters. The arrangement of the chapters and the main contents in each chapter are presented as follows:In chapter 1, we make a brief introduction to all kinds of magnetoresistance effects; the basic properties of the perovskite-type manganese oxides, including research history, crystal structure, electronic structure, magnetic structure, and the electronic and magnetic phase diagrams; the strain relaxation of manganite thin films; and the research progress in application.

各章的主要内容分别概括如下：第一章简单介绍了各种磁电阻效应；钙钛矿锰氧化物的基本性质，包括研究历史、晶体结构、电子结构、磁结构和电磁相图；锰氧化物薄膜中应力弛豫；锰氧化物在应用方面的研究进展。

This dissertation is relation to SrO(La2/3Sr1/3MnO3)n the manganese oxides with RP structure. We mostly studied the structure and electrical transport properties, The major studies are listed below: The classes of magnetoresistance were introduced, the electron and crystal structure and the mechanism of double exchange of manganite pervosike related to colossal magnetoresistance have been summarized. More attention had also been paid to the advance in the study of RP structure manganite and grain system. The principle and process of sol-gel method were introduced. With sol-gel method a series of different grain size La2/3Sr1/3MnO3 sample were prepared.

本文以Mn3+：Mn4+=2：1的Ruddlesden-Popper结构锰氧化物SrO(La2/3Sr1/3MnO3)n为研究对象，系统的研究了利用溶胶-凝胶法制备的n=∞的La2/3Sr1/3MnO3和n=2的La4/3Sr5/3Mn2O7两个系列样品的结构和电磁性质，主要内容包括以下几点：简单介绍了磁电阻效应的分类，概述了具有超大磁电阻效应的锰基钙钛矿氧化物的电子晶体结构和双交换等相关的物理机理，给出RP结构系列锰氧化物的晶体结构和电磁相图以及研究状况，分析了颗粒系统的研究进展。

In order to find a kind of low-cost and high-capability catalyst for methane combustion, a series of CeO_2-ZrO_2-Al_2O_3 solid solution, in which the content of Ce_0.67Zr_0.33O_2 and Al_2O_3 were different, were prepared by co-precipitation method.

近年来，非贵金属氧化物甲烷燃烧催化剂的研究虽然十分活跃，但对铁基氧化物催化剂研究不多，其主要原因是铁基氧化物催化剂对甲烷燃烧的催化活性较差。

A preparation method of nickel oxide-base cathode of fused carbonate fuel cell is to select alkali earth metal oxide, transition metal oxide and rare-earth metal oxide, mix with carbonyl nickel powder in the proportion of 0.01-15.00 mol%, add assistant and mix even into a slurry; after the slurry is formed into a biscuit by doctor-blade casting, sinter it into a multi-porous nickel plate; dissolve lithium nitrate and cobaltous nitrate with mole ratio of Li:Co-1:1 and citric acid or PVA in the distilled water to make a solution with Li of 0.00-0.5 mol/L; immerse the multi-porous nickel plate or nickel oxide plate in the solution, keep for 10-60 minutes under vacuum below 200 millibar, then dry in an oven at 75 degrees centigrade further transfer to a crucible electric furnace preheated 650 degrees centigrade for keeping the temp.

要約 熔融碳酸盐燃料电池氧化镍基阴极的制备方法属于燃料电池领域。选取碱土金属氧化物、过渡金属氧化物和稀土金属氧化物，按0.01－15.00mol％的比例与羰基镍粉混合，加入助剂，混合均匀成浆料；混合浆料流延成型为素坯后烧结为多孔金属镍板；将摩尔比为Li∶Co＝1∶1的硝酸锂和硝酸钴以及柠檬酸或聚乙烯醇溶于蒸馏水中，制成为0.005－0.5mol/L的溶液；将多孔金属镍板或氧化镍板浸入溶液中，在真空度低于200毫巴下保持10－60分钟；置于75℃的烘箱中烘干，转移至预热到650℃坩埚电炉中保温1－10小时；将此过程重复一次或多次即可。

Metallurgy School, UST Beijing, Beijing 100083, China）ABSTRACT The negative thermal expansion in some complex oxides has beenattributed to transverse thermal motion of A-O-M linkage composed of two-coordinate oxygenbridge bond, and the librationsand tilts of essentially rigid polyhedral blocks in openframework structure. The isotopic NTE materials have been finding moresubstantialapplications in composites and other relative technique fields.

氧化物材料负热膨胀机理邢献然摘要氧化物的负热膨胀性是由于在其开放式的骨架结构中，有二配位的桥氧键产生横向热运动，以及引起的多面体热摆动和耦合作用使非键合M-M1键距变短，导致单胞体积缩小；各向同性NTE氧化物在复合材料及其相关技术领域具有更广泛的应用价值。

The present Cu-20Ni-25Co alloy forms a continuous of Co2O3 layers over the surface of alloy because Cu-20Ni-25Co alloy formed by adding Ni to Cu-Co alloy decrease the critical concentration of forming reactive component oxides.

这主要归因于向Cu-Co合金加入了第三组元Ni，降低了合金表面活泼组元形成氧化物所需的临界浓度，促使合金表面由混合氧化物膜向单一活泼组元氧化物膜的转化。

In the first part, two novel methods were proposed for the determination of three kinds of organogermanium compounds βcarboxyethylgermanium sesquioxide,β- carboxyethylgermanium sesquioxide and di-(β-carboxyethyl) germanium hydroxide by using high performance ion-exchange and ion-exclusion chromatography.

第一部分采用高效离子交换和离子排斥色谱法，建立了两种测定三种有机锗化合物β-羧乙基锗倍半氧化物、β-羧乙基锗倍半氧化物、二-锗氢氧化物的新方法。

As the RE ions concentration in groundwater increases or the surface sites on Mn-Fe oxide become saturated, RE ions may sorb via surface precipitation, then surface precipitation become the dominant sorption mechanism.

当离子浓度低时，形成表面络合物是占统治地位的吸附机制；当氧化物/水体系中离子浓度大时，金属离子除在表面形成表面络合物外，也可能形成表面氢氧化物沉淀，直到氧化物表面吸附点位被全部占满，这时表面沉淀则变成主要的吸附机制。

The surface of uranium metal is made of oxide and the distribution of surface layer is: metal/non-stoichiometry oxide/oxide.

铀金属的表面主要为氧化物，其表面组成为：金属-亚化学计量氧化物区-高价稳定氧化物。

The results show that REEs oxide have little effect on the decomposition of carbonate and they improve the sinterability of the raw meal;they also promote the formation of alite and growth of clinker minerals,and have beneficial effect on the uniformity of crystal size and well-distributed minerals. But some REEs result in the corrosion of alite when they are excessive,which may influence the hydration reactivity of alite.When clinker is well sintered, REEs oxide and its tailing improve the strength of cement clinker, and have little effect on setting time of cement.

研究结果表明，稀土氧化物对碳酸盐的分解影响不大，对生料的易烧性有改善作用；稀土氧化物能促进熟料中A矿的形成和矿物的发育，有利于熟料中矿物结晶尺寸和分布均匀，但部分稀土在掺量过量时可能造成矿物的熔蚀，影响矿物的水化活性；在煅烧良好的条件下，稀土氧化物和尾矿对熟料强度有增进作用，对水泥凝结时间影响较小。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。