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The XPS result ravels an inner layer of Cr oxide and an outer layer of Fe oxide, which is in agreement with the previous works.

XPS测试结果表明钝化膜主要由内层的铬氧化物和外层的铁氧化物组成,这与以前的研究结果相一致。

The iron oxides, if presence, accumulated themself mostly on the surfacelayer of slagged zone, formed an assemblage of reaction products and convertedinto two systems of ferro-spinels asA andF.

存在铁氧化物时,基本上吸附在渣蚀带表面,形成有两个尖晶石固溶体〔A和F〕系列的矿物共生组合,当不存在铁氧化物时,在渣蚀带生成纯MA。

In range of 300℃~900℃, all the transition metal oxide catalysts could get high ammonia conversion, during the initial stages of the reaction, the SO〓 conversion is relatively low since the catalysts have not been sulfureted, but it increases gradually and attain constant with rising temperature and time continuance,〓 is better than other catalysts in reactivity and elemental sulfur selectivity; XRD indicates that, in the SO〓-SCR process, stable transition metal sulfide is generated which is very important to SO〓 reduction and transition metal sulfide probably is the active phase of catalyst, further the reduction of SO〓 by H〓 to H〓S is the limiting step of all process, then the activity is somewhat related to its lattice oxygen yet not so notable; XPS indicates that little sulfur on surface exists as S〓 in sulfate, showing that TiO〓 could restrain the generation of sulfate.

对于过渡金属氧化物催化剂的研究发现,在300℃~900℃范围内,不同的催化剂均可获得很高的NH〓转化率,反应初期由于催化剂还未硫化,所以SO〓的转化率较低,随着温度升高和反应时间的延续,SO〓的转化率逐渐升高并达到了稳定值;七种过渡金属氧化物中,以〓对于NH〓还原SO〓反应的活性和选择性最好;XRD结果表明在NH〓-SO〓反应后生成了稳定的硫化物相,硫化物对SO〓的还原过程具有重要作用,催化剂的活性相可能是过渡金属硫化物,而且在硫化物催化剂上进行的H〓还原SO〓生成H〓S的反应是整个过程的速率控制步骤,所以催化剂的活性与其自身的晶格氧的氧化还原能力有一定的联系,但关系不明显;XPS结果表明催化剂表面的硫大部分以过渡金属硫化物的形式存在,只生成少量的S〓,说明TiO〓催化剂能够较好的抑制硫酸盐的生成。

The development of metal-air battery and air electrode is briefly introduced in this paper. Then, the catalysts for oxygen reduction, especially perovskite-type oxide, are reviewed in detail. Meanwhile, the principle of sol-gel technology is summered, and then their preparation with Sol-Gel method has been briefly introduced.

本论文简述了锌-空气电池及空气电极,介绍了金属-空气电池用催化剂特别是钙钛矿型复合氧化物催化剂的研究现状及进展,并对溶胶-凝胶制备法制备钙钛矿型复合氧化物作了简要的介绍。

On this bases, according to the electronic configuratiosn of antimony oxide and the principle of p-type doping in wide band-gap semiconductors oxides, we tried to develop a new transparent conducting tin-antimony oxide films with p-type conduction.

在此基础上,根据氧化锑的电子结构特征和宽禁带氧化物p型掺杂机理,尝试在氧化锑中掺入适量Sn元素以获取一种新型p型透明导电氧化物薄膜。

The good results are achieved by deeply-process of by-product hydrochloric acid through these technology improvement methods of resin exchange,Barium chloride settlement and oxide reduction.

曼海姆工艺副产盐酸存在着硫酸盐和氧化物超标的问题,通过工艺技术的改进,利用树脂交换、BaCl_2沉降、氧化物还原对副产盐酸进行深加工,效果良好。

Borax calcium carbonate, hydroxide, copper sulphide, ferric oxide, barium carbonate, antimony trioxide, all kinds of metallic hydroxide, kinds of heavy metallic salt, synthetic cryolite and so on.

无机物:硼酸、碳酸钙、氢氧化物、硫酸铜、氧化铁、碳酸钡、三氧化锑、各种金属氢氧化物、各种重金属盐、合成冰晶石等

If r and oxide layer are thin, they will improve the adhesion between the substrate and the bond coat. They will reduce hightemperature-oxidation-resistance if they become thick. The solid-liquid reaction of forming melting layer can enhance the bonding between the substrate and the bond coat.

由于界面反应形成的致密的Y'或氧化物膜对提高涂层的寿命是有利的,但厚的Y'或氧化物层是涂层失效的原因之一;形成熔化层的固液反应可提高基体与底层的结合强度。

After heat treatment at 1100C in air, the elements of the substrate and the bond coat diffuse and the diffusion of Ni is an uphill diffusion. The layer of r " phase and the layer of A12O3 or NiAl2O4 were formed at the interface of the substrate and the bond coat and at the interface of the bond/top coat, respectively. The thickness of the r " phase and the oxide layer increases with the increase of the time of the heat treatment.

经1100℃热处理,基体和底层中元素发生了相互扩散,并在界面析出γ'相,γ'的存在使界面的结合为冶金结合;在底层/面层界面由于底层被氧化和Al与ZrO_2氧化还原反应形成Al_2O_3等氧化物,Y'和氧化物的厚度随热处理时间延长而增加。

The syntheses methods of carbon nanotubes supported metal oxide nanoparticle were summarized in this paper, and the present research hotspots and problems were also introduced.

综述了碳纳米管负载纳米金属氧化物的制备方法以及当前研究的热点和存在的问题,重点论述了纳米金属氧化物沉积在碳纳米管表面上的方法及其相互作用机理,并展望了这类复合材料的应用前景。

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