氧化合物

The phosphorus oxychloride or phosphorus tribromide N, N-dimethylformamide mix and react to form the Vilsmeier reagent used in the reaction. The newly prepared Vilsmeier reagent is added into the reaction bottle provided with the return condenser and the blender; a reaction raw material N, N-dimethylformamide solution expressed in the reaction formula is added into the system; the temperature is risen; the corresponding multi substituting pyridine-2 (1 H)-ketone compound can be made after the column chromatography of the silica gel; the production rate is between 60 and 95 percent according to different reactions.

由三氯氧磷或三溴化磷N，N-二甲基甲酰胺混合获得反应中所用Vilsmeier试剂；将新配制的Vilsmeier试剂加入装有回流冷凝管、搅拌器的反应瓶中，向体系中加入反应通式中表示的一种反应原料的N，N-二甲基甲酰胺溶液，升温，经硅胶柱层析分离得相应的多取代吡啶-2(1H)-酮类化合物，产率视不同反应在60~95％之间。

The structures were identified by NMR, IRand MS.Results Three compounds were identified from its 80% alcohol extract as: 5,7,3'-trihydroxy- 4'-methoxyflavanone, 4',5, 7- trihydroxyflavanone, stigmaasterol.

结果 从紫茉莉种子的80%乙醇提取物中分离到3 化合物，它们的结构分别被鉴定： 5，7，3'-三羟基-4'-甲氧基黄酮(1)， 4'，5， 7-三羟基黄酮(2)，豆甾醇(3)。

The structures were identified by nmr, irand ms.results three compounds were identified from its 80% alcohol extract as: 5,7,3'-trihydroxy- 4'-methoxyflavanone, 4',5, 7- trihydroxyflavanone, stigmaasterol.

结果 从紫茉莉种子的80%乙醇提取物中分离到3个化合物，它们的结构分别被鉴定为： 5，7，3'-三羟基-4'-甲氧基黄酮(1)， 4'，5， 7-三羟基黄酮(2)，豆甾醇(3)。

Because the BPE molecule is long enough to eliminate the interlayered antiferromagnetic interaction, B2 become ferrimagnatic based on the faced-shared trimeric cobalt units below 20K.

因为BPE分子够长足以消除无机层间的反铁磁作用，使得化合物B2显现无机层的氧铁磁性。

First, the geometry optimization for 1-phenyldibenzophosphole and triphenylphosphine were carried out using quantum chemical AM1 method.

用量子化学AM1方法优化了1-苯基二苯并膦和三苯基膦的几何构型，比较了两种化合物的电子结构和空间结构，发现PDBP作为羰基合成铑膦催化剂的配体要优于三苯基膦；系统研究了PDBP的合成方法，其最佳合成条件为：在无水无氧的条件下，采用二乙胺锂与溴化四苯基膦摩尔比为3，反应温度为22 ℃，反应5 h，反应后酸化， pH值为1～2，产物收率可达到85％～88％。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

Three compounds of tungstosilicic acid and tungstosilicic salt: K3H[SiW12(superscript Ⅵ)O40]?

合成了三种具有Keggin结构的硅钨氧簇化合物：K3H[SiW12O40]？

The results were shown as following:(1)Compared with unsubstituted Pc, the introduction of carboxyphenoxy improves the solubility of four Pc derivates, and can be attributed to amphiphilic phthalocyanine. This property is most important for photosensitizer to transmit in vivo and enrich on the surface of tumors.

研究结果表明：(1)合成的四种酞菁与其它酞菁类衍生物相比，由于用羧基苯氧基对酞菁周边环进行了修饰，其溶解性能得到明显地改善，属于两亲性酞菁化合物，这种溶解特性适合其作为光敏剂在体内的传输和在肿瘤组织中的富集。

Their structures were characterized as usnic acid,evinic acid,perlatolic acid,olivetoric acid,2-hydroxyl-4-methoxyl-6-pentyl benzoic acid and 2,4-dihydroxyl benzoic acid,respectively.

结果从太白花的石油醚部分得到6个化合物，分别鉴定为：松萝酸、去甲环萝酸、珠光酸、漂红梅衣酸、2-羟基-4-甲氧基-6-正戊基苯甲酸和2，4-二羟基-6-正戊基苯甲酸。

Simultaneously we prepared benzimidazolines with two methods by the of reduction benzimidazolium salts with NaBH_4 and Grignard addition with benzimidazolium salts. Thus we provided a new biomimic synthetic method for 13 kind of tetrahydroisoquinoline starting from carboxylic aicd and halid, gave a new idea of the synthesis for new drugs.It can make many kind ofβ-carboline alkaloids which have bioactivity to antibacterium, antivirus and antitumor to start from 1,2,3,4-tetrahydro -β-carboline.

本文以1，3-二甲基苯并咪唑碘盐和2-取代的1，3-二甲基苯并咪唑碘盐为原料，采用了NaBH_4还原和Grignard试剂加成两种方法，制备了13种1，3-二甲基苯并咪唑烷和2-取代的1，3-二甲基苯并咪唑烷作为四氢叶酸辅酶一碳单元转移新模型，在酸性条件下，以2-(3，4-二甲氧基苯基)乙胺作为接收一碳转移的亲核试剂，完成了13种重要的四氢异喹啉类化合物的新合成方法研究。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！