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氧化合物

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Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a&和4a&也可利用类似的质子化反应合成,唯有错合物3a'= CpRu(PPh32, Ar2 = fluorenyl 可以稳定於溶液中,不会进行上述反应,如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

To test this hypothesis, we measured the effect of IV infusion of the NMDA blockers dizocilpine (MK-801) and-4-(3-phosphonopropyl) piperazine-2-carboxylic acid to decrease the MAC (the minimum alveolar concentration of anesthetic that prevents movement in 50% of subjects given a noxious stimulation) of 8 conventional anesthetics (cyclopropane, desflurane, enflurane, halothane, isoflurane, nitrous oxide, sevoflurane, and xenon) and 8 aromatic compounds (benzene, fluorobenzene, o-difluorobenzene, p-difluorobenzene, 1,2,4-trifluorobenzene, 1,3,5-trifluorobenzene, pentafluorobenzene, and hexafluorobenzene) and, for comparison, etomidate.

为了验证这个假说,我们检测静脉注射 NMDA 阻滞剂 MK-801和 CPP 来降低8种常规吸入麻醉药(环丙烷,地氟醚,安氟醚,氟烷,异氟醚,一氧化二氮,七氟醚和氙)和8种芳香族化合物(苯,氟苯,邻二氟苯,对二氟苯, 1,2,4-三氟苯, 1,3,5-三氟苯,五氟苯和六氟苯的 MAC 值,依托咪酯作为对照组。

A new synthesis method of Taxane s was reported involving radicals generated from hypophosphorous acidn initiated by 2,2′-azobisisobutyronitrile.

由偶氮二异丁腈引发次磷酸产生次磷酸根自由基,以链式自由基反应机制脱除紫杉烷类化合物结构中的含氧基团,简单、高效地合成了紫杉烷。

A new synthesis method of Taxanes was reported involving radicals generated from hypophosphorous acid n initiated by 2,2′-azobisisobutyronitrile.

由偶氮二异丁腈引发次磷酸产生次磷酸根自由基,以链式自由基反应机制脱除紫杉烷类化合物结构中的含氧基团,简单、高效地合成了紫杉烷。

The 5-benzyloxy-2-nitrotoluene is an organic intermediate to prepare indoles by Reissert indole synthesis.

2-硝基-5-苄氧基甲苯是有机中间体,可以进一步采用Reissert法合成吲哚类化合物。

According to the structure-activity relationships, we have designed five novel indoline derivatives and have synthesized three of them. Some animal evaluations are under way.

从药物的构效关系出发,我们设计了五种二氢吲哚氧苯甲酸类新化合物并完成了其中三个的合成,目前已在做动物试验。

In contrast to S- and O-heterocyclic compounds, increasing ionic strength reduced the sorption of ionizable N-heterocyclic compounds (pyridine, 2-methylpyridine, quinoline, 2-methylquinoline, and isoquinoline), due to increased electrostatic competition by cations.

对比硫和氧类杂环物质,提高离子强度会减少杂环化合物的吸收(吡啶、2甲基吡啶、喹啉、2甲基喹啉和异喹啉)这主要是由于阳离子的静电竞争。

By reacting isobutyraldehyde with diethyl oxalate using sodium methoxide as catalyst,3-methyl-2-oxobutanoic acid,sodium salt was prepared by one pot.

3-甲基-2-氧代丁酸钠是一种重要的酮酸类化合物,它在制药工业、高分子工业、食品工业、日化业等领域都有着广泛的用途。

An active isoflavone compound 3′methoxy puerarin was isolated from puerarin lobate.

3′ 甲氧基葛根素是从常用中药野生葛根中分离提取出来的一种具有很强生物活性的异黄酮类化合物。

These compounds were identified as follows:chrysophanol (FP-1),physcion(FP-2),eriosematin(FP-3),scoparone(FP-4),lupeol(FP-5),betulinic acid(FP-6),3\',4\'-Dihydroxy-trans-cinamic acid octacosyl ester(FP-7),β-sitosterol (FP-8),flemiphilippinone A(FP-9),monopalmitin(FP-10),emodin(FP-11),islandicin (FP-12),salicylic acid(FP-13),p-methoxyphenylpropionic acid(FP-14),trideca-1, 3-diene(FP-15),lupinifolin(FP-16),flemichin D(FP-17),flemiphilippinin A(FP-18), auriculasin(FP-19),erythrinin B(FP-20),6-C-prenylluteolin(FP-21), 8-(1,1-dimethylallyl) genistein(FP-22),flemiphilippinin E(FP-23),flemiphilippinin F (FP-24),5,7,3\',4\'-tetrahydroxy-6,8-diprenylisoflavone(FP-25),flemiphilippinin D (FP-26),dorsmaninsⅠ(FP-27),osajin(FP-28),6,8-diprenyleriodictyol(FP-29), lupinalbin A(FP-30),genistein(FP-31),3\'-O-methylorobol(FP-32),orobol(FP-33), 5,7,2\',3\',4\'-pentahrdroxyflavone(FP-34),the mixture of biochanin A and prunetin (FP-35 and 36),genistin(FP-37),sophororicoside(FP-38),3\'-O-methylorobol-7-glucoside(FP-39),the mixture of sissotrin and prunetin 4\'-O-β-D-glucoside(FP-40 and 41),adenosine(FP-42) and luteoloside(FP-43,mixture).

这些化合物分别为大黄酚(FP-1)、大黄素甲醚(FP-2)、eriosematin(FP-3)、滨蒿内酯(FP-4)、羽扇豆醇(FP-5)、白桦酸(FP-6)、咖啡酸二十八烷酯(FP-7)、β-谷甾醇(FP-8)、蔓性千斤拔酮A(FP-9)、单棕榈酸甘油酯(FP-10)、大黄素(FP-11)、islandicin(FP-12)、水杨酸(FP-13)、对甲氧基苯丙酸(FP-14)、十三烷-1,4-二烯烃(FP-15)、lupinifolin(FP-16)、千斤拔素D(FP-17)、蔓性千斤拔素A(FP-18)、auriculasin(FP-19)、erythrinin B(FP-20)、6-C-异戊烯基木犀草素(FP-21)、8-(1,1-二甲烯丙基)-染料木黄酮(FP-22)、蔓性千斤拔素E(FP-23)、蔓性千斤拔素F(FP-24)、5,7,3′,4′-四羟基-6,8-双异戊烯基异黄酮(FP-25)、蔓性千斤拔素D(FP-26)、dorsmaninsⅠ(FP-27)、osajin(FP-28)、6,8-双异戊烯基圣草素(FP-29)、lupinalbin A(FP-30)、染料木黄酮(FP-31)、3\'-O-甲基香豌豆苷元(FP-32)、奥洛醇(FP-33)、5,7,2′,3′,4′-五羟基黄酮(FP-34)、鹰嘴豆素甲和樱黄素的混合物(FP-35和FP-36)、染料木苷(FP-37)、槐属苷(FP-38)、7-葡萄糖基-3\'-O-甲基香豌豆苷(FP-39)、印度黄檀苷和樱黄素4′-O-β-D-葡萄糖苷的混合物(FP-40和FP-41)、腺嘌呤核苷(FP-42)和木犀草苷(FP-43,混合物)。

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