氧化合物

The structures of these two molecules are almost the same with slight differences in bond lengths and bond angles. And compounds 1-3 are the first examples of this type containing amido and ethoxide groups.

而且到目前为止，Sn4O4的梯子状结构中同时含有氨基和乙氧基的化合物还未见报道，化合物1，2和3为首次合成此类化合物。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分，我们研究了α，α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应，发现全氟苄基碘或溴及α，α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐；全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴；在烯烃存在下，全氟苄基碘则与烯烃发生加成反应，生成相应的1：1加成产物；在三价醋酸锰的作用下，部分芳香化合物如茴香醚，二甲氧基苯，吡啶，喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应，反应表现出一定的区域选择性，产率良好。

In summary, 15 new N--2-(4, 6-dimethoxypyrimidin-2-yl-oxy)benzylamine derivatives with high herbicidal activity are obtained.

4氧桥双取代嘧啶苄胺类化合物也是一类具有高除草活性的化合物，在75 g ai／hm~2低剂量下，化合物主要表现出芽后除草活性。

The good herbicidal activity can not be observed at low dosage of 75 g ai/hm~2 for N-(mono-ester substituted phenyl)-2-(4, 6-dimethoxy-pyrimidin-2-yloxy)benzylamine derivatives in post-emergent and pre-emergent application.

主要研究结果如下：(1)氧桥单取代卤素嘧啶苄胺类化合物是一类具有高除草活性的化合物，在75 g ai／hm~2低剂量下，一些化合物表现出良好的芽后和芽前除草活性。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

From Cacalia deltophylla (collected from Luqu County, Gansu Province), 22 compounds were isolated, of which 15 compounds have been identified. Among them, two compounds are new. They are named as 3-methyl-4-hydro-8-acetyl-furanonaphth-9-one and 1hydroxy-2-methoxy-3-acetyl-4, 8-dimethyl-5, 8-dihydro-naphthalene.

从采自甘肃省碌曲县的三角叶蟹甲草全草的甲醇提取物的石油醚部分和乙酸乙酯部分中，采用同样方法分离得到22个化合物，鉴定了其中的15个化合物，其中有2个为新化合物，分别命名为3-甲基-4-氢-8-乙酰基-呋喃萘-9-酮（2）和1-羟基-2-甲氧基-3-乙酰基-4，8-二甲基-5，8-二氢-萘（3）。

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物，采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物，包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

The reaction between 3, 4 cinnamic acid and 〓 has also been investigated as an evidence for the electron transfer mechanism.

以〓为过氧自由基模型，研究了羟基肉桂酸衍生物对该自由基的清除作用，发现这类化合物，特别是芥子酸，能够通过电子转移反应有效地还原过氧自由基。3，4-亚甲二氧基肉桂酸与〓的反应的动力学研究为电子转移机制提供了证据。

Sixteen target compounds were designed and synthesized, basing on 2--(4-hydroxy-3-methoxybenzylidene)cyclopentanone as the lead compound, all of which are innovative and have not been reported yet.

本文以2--(3-甲氧基-4-羟基苯亚甲基)环戊酮为先导化合物，设计并合成了16个目标化合物，均为未见文献报道的新化合物。

A new flavanone from Dryopteris sublaeta;2. Isolation and Structure Identification of a New Flavanone from Dryopteris sublaeta;3. RESULTS Five compounds are isolated from the ether fraction of 70% acetone-extracts,and their structures were identified as(2S)5,7-dihydroxy-6,8-dimethyl flavanone desmethoxymatt.

结果浅裂鳞毛蕨地上部分用体积分数为70%丙酮提取液乙醚萃取部位分离得到了5个化合物，分别鉴定为：(2S)5，7-二羟基-6，8-二甲基二氢黄酮，(2S)5，7-二羟基-6，8-二甲基-4′-甲氧基二氢黄酮，(2S)5，7，2′-三羟基-6，8-二甲基-二氢黄酮，(2S)5，7，4′-三羟基-3′-甲氧基-6，8-二甲基二氢黄酮，(2S)5-羟基-4′-甲氧基-6，8-二甲基二氢黄酮-7-O--βD-葡萄糖苷。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！