氧化合物

Results Nine compounds from supercritical CO2 extraction were identified and the main constituents were pentadecane, ethyl pmethoxycinnamate and ethyl cinnamate. Twentyeight compounds from water distillation were identified and the main constituents were δ3carene, ethyl pmethoxycinnamate and ethyl cinnamate.

结果 沙姜超临界CO2萃取物中分离鉴定出9种化合物，主要成分为十五烷、肉桂酸乙酯、对甲氧基肉桂酸乙酯等；水蒸气蒸馏法中分离鉴定出28种化合物，主要成分为δ3蒈烯、肉桂酸乙酯和对甲氧基肉桂酸乙酯等。

Results Nine compounds from supercritical CO2 extraction were identified and the main constituents were pentadecane, ethyl p-methoxycinnamate and ethyl cinnamate. Twenty-eight compounds from water distillation were identified and the main constituents were δ-3-carene, ethyl p-methoxycinnamate and ethyl cinnamate.

结果 沙姜超临界CO2萃取物中分离鉴定出9种化合物，主要成分为十五烷、肉桂酸乙酯、对甲氧基肉桂酸乙酯等；水蒸气蒸馏法中分离鉴定出28种化合物，主要成分为δ-3-蒈烯、肉桂酸乙酯和对甲氧基肉桂酸乙酯等。

Tetra-O-benzyl-D-glucose reacted with bromine to give glucosylbromide. It reacted with hydroxyl phenyl acetonitrile or hydroxyl benzaldehyde to give substituted ph- enylacetonitrile or substituted benzaldehyde.11 New stilbenes were synthesized possessing 2,3,4,6-tetra-O-benzyl-D-glucoside by condensation reaction with pheny lacetonitrile or benzaldehyde, which had potential biological activity and would be sieved in the future.

由2，3，4，6-四芐氧基葡萄糖作为中间体，首先制备出的溴代糖和含有羟基的苯甲醛和苯乙反应制备出含有糖的取代苯甲醛和取代苯乙，再和简单的苯乙或苯甲醛缩合反应生成11种具有潜在的生物活性且含有2，3，4，6-四芐氧基葡萄糖的类化合物，这些新化合物有待于进一步进行药理活性筛选。

Synthesizing new compounds are always the goal of chemist. Recent ly, the progress of the hydrothermal synthesis method is giving a new method to synthesize new compounds. The hydrothermal synthesis method is prefectly applied to synthesizing the tunnling materials, micro-and meso-porous mat erials as well as some new materials, so this method obtained the intrest of che mist.

中文题名含有杂原子的金属－氧簇(V，Mo，W，P，As)的合成与结构副题名外文题名论文作者李亚丰导师裘式纶教授学科专业无机化学研究领域\研究方向学位级别博士学位授予单位吉林大学学位授予日期2002 论文页码总数70，68页关键词金属－氧簇化学多酸化学无机合成化学馆藏号BSLW /2003 /O611 /3 合成新结构和新组成的化合物一直是化学家们的目标，近代水热合成技术的发展为合成亲新化合物提供了一种新的方法，水热由于在合成具有孔道结构、微介孔材料以及一其它一些新型材料具有其它方法无可比拟的优越性，因此，越来越受到人们的重视。

The largest chemical shifts were observed for the proton 1.48 ppm adjacent to the central pyridinium ring and para-protons 1.47 ppm with respect to the nitrogen of pyridinium.

在最终的亲核加成化合物2-F的芳香族区中的这些化学位移与9，10二氢-9-甲氧基-9-(4甲氧基苯基)-10-甲基吖啶的对应物是一致的，17b 这被证明是与过量的MeOH形成的9-苯基吖啶盐的加成化合物（支持信息中的图S7）。

A group of pyrylium salts with different substituents has been synthesized in this work. Their fluorescence life time, quantum yield and quenching constant by BVE have also been measured. It was found that a strong interaction was observed between BVE and pyrylium salt which contains an electron-withdrawing group, and contrary, the introduction of electron-repulsive groups to the pyrylium salt will decrease this effect. It indicated that these reactions possess the characteristic of electron transfer.

本工作合成了一组带不同取代基的氧鎓盐化合物，并对它们的荧光寿命、荧光量子产率以及用丁基乙烯基醚进行猝灭的荧光猝灭常数进行了测定，发现带拉电子基的氧鎓盐化合物和BVE间存在着较强的相互作用，相反，推电子基的引入则减弱了这种影响，表明反应具有电子转移性质。

Results Six compounds were isolated and identified as:5α,8α-epidioxy-(22E,24R)-ergosta-6,22-dien-3β-ol,scopoletin,isofraxidin,p-hydroxy benzaldehyde,3,4,5-trimethoxy benzoic acid,protocatechuic acid ethyl ester...

结果得到6个化合物，分别鉴定为：5α，8α表二氧(22E，24R)麦角甾6，22二烯3β醇、东莨菪素、异秦皮啶、对羟基苯甲醛、3，4，5三甲氧基苯甲酸、原儿茶酸乙酯。结论化合物Ⅰ～Ⅵ均为首次从该属植物中分离得到。

The stereochemical structures of two new compounds, 5-(3-chlorophenyl)-2-furfur-aldehyde-N-4-methylphenyloxyacetylhydrazone and 5-(3-chlorophenyl)-2-furfuraldehyde-N-4-nitrophenyloxyacetylhydrazone, were determined by DPFGSE-NOE experiments performed in DMSO-d\-6 at 25 ℃ and variable-temperature ~1H NMR The ~1H chemical shifts of the compounds were completely assigned at 25 ℃ and 90

利用变温实验和DPFGSE NOE实验，确定了 5 (3 氯苯基) 2 呋喃甲醛 N 4 甲基苯氧乙酰腙和5 (3 氯苯基) 2 呋喃甲醛 N 4 硝基苯氧乙酰腙两个新化合物25 ℃时在二甲基亚砜中的空间构型，并对这两个新化合物在 25 ℃和 90 ℃时的质子的化学位移进行了全归属。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体，合成了七{2，6-二-O-[3-(1，3-二羟基丙氨酸)]}-β-环糊精，再用醋酸酐将其乙酰化，得到了一种淡黄色粘稠液体，合成了一种新型的环糊精衍生物；以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物，再将其烷基化和酰基化，合成了β-环糊精聚合物的不同衍生物，用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上，通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究，结果表明所合成的β-环糊精衍生物对各类化合物，特别是对位置异构体和对映异构体具有较好的分离效果，显示了很强的立体选择性。

The ring-open nitration of propylene oxide compounds was investigated using dinitrogen pentoxide as nitrating agent.

并以N2O5为硝化剂考察了环氧丙烷类化合物开环硝化过程，探讨了取代基的电子效应和立体效应对环氧丙烷类化合物开环硝化过程的影响规律。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！