氧化合物

Nine new compounds were characterized, and they were: opuntioside Ⅰ(11), 4-ethoxyl-6-hydroxymethyl-α-pyrone (14),--ester (22), 1-butoxyl--malate (24), ethyl α-L-rhamnopyranoside (26), opuntioside Ⅱ(34), kaempferol 7-O-β-D-glucopyranosyl (1→4)-β-D-glucopyranoside (46), methyl α-D-glucopyranoside-6-(methyl 4-malate)-ester (47), and opuntioside Ⅲ(48). Opuntioside Ⅰ,Ⅱ,Ⅲ and 4-ethoxyl-6-hydroxymethyl-α-pyrone belong to the skelecton of α-pyrone.

新化合物分别是：仙人掌苷Ⅰ（11），4-乙氧基-6-羟甲基-α-吡喃酮（14），琥珀酸乙酯--酯（22），L--苹果酸-1-丁酯（24），乙基α-L-吡喃鼠李糖苷（26），仙人掌苷Ⅱ（34），山奈酚7-O-β-D-吡喃葡萄糖基（1→4）-β-D-吡喃葡萄糖苷（46），α-D-吡喃葡萄糖甲苷-6-（苹果酸-4-甲酯）-酯（47），仙人掌苷Ⅲ（48），其中仙人掌苷Ⅰ、Ⅱ、Ⅲ及4-乙氧基-6-羟甲基-α-吡喃酮均为α-吡喃酮骨架类型的新化合物。

Objective: through various chemical synthesis target compounds 4 -- 6 - the - 7 -(2 - hydroxyl replace c oxygen radicals) quinazoline compounds were synthesized and the structure of the modified, so as to get high epidermal growth factor receptor tyrosine kinase inhibitor.

目的：通过各种化学合成方法完成目标化合物4--6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉的合成并对目标化合物进行结构修饰，以期获得高活性的表皮生长因子受体酪氨酸激酶抑制剂。

These chemical shifts in the aromatic region of the resulting nucleophilic adduct 2-F were consistent with the counterparts of 9,10-dihydro-9-methoxy-9-(4-methoxyphenyl)-10-methylacridine, 17b which was proven to be the adduct of the 9-phenyl acridinium salt formed with an excess of MeOH (Figure S7 in Supporting Information).

在最终的亲核加成化合物2-F的芳香族区中的这些化学位移与9，10二氢-9-甲氧基-9-(4甲氧基苯基)-10-甲基吖啶的对应物是一致的，17b 这被证明是与过量的MeOH形成的9-苯基吖啶盐的加成化合物（支持信息中的图S7）。

In order to study strcture-bioactivity relationship concerning α,β-unsaturated-γ-lactones, we further synthesized γ-benzyloxymethy-γ-butanolide XXIII and the corresponding unsaturated buteno- lido XXV Scheme 6, p.

为了研究该类化合物的构效关系，在本论文第三部分，我们进一步设计并合成了--γ-苄氧基甲基-γ-丁内酯XXIII和--γ-苄氧基甲基-γ-丁烯内酯XXV这两个内酯化合物，目的是想考察内酯的α，β-不饱和双键是否是产生细胞毒性的关键结构。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

On the basis of molecular design and assembly, the polyoxometalate compounds supported by Keggin, Dawson, lacunary Keggin, and Silverton-type etc. polyanions on the basis of well-known and novel polyanions as building blocks were successfully synthesized by the hydrothermal technique, which are"decorated"or"bridged"by organic N-donor and/or O-donor ligands. The study on synthetic conditions and rules for these hybrid compounds and characterization by X-ray crystallography, spectroscopic, thermal, electrochemical and magnetic properties are carried out.

本文主要利用水热合成方法，从分子设计及组装的思想出发，借助不同N和含O的有机配体对多金属氧酸盐阴离子结构进行&修饰&或&桥连&，合成了一些以饱和Keggin结构、饱和Dawson结构、缺位Keggin结构和Silverton结构等阴离子为构筑模块的多金属氧酸盐化合物，研究了这些化合物的合成条件及规律并对它们的晶体结构、谱学性质、热性质以及磁性质进行了研究。

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1，3-偶极体，可以与一系列芳基或烷基取代的腈反应，高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物；也可以与富电子的链状和环状的烯基醚反应，以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物；而与2，5-二甲基呋喃的反应，由于甲基的位阻作用，只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

A process for preparing clean gasoline features that under existance of epoxidizing catalyst and alkoxylating catalyst, the olefine in gasoline and the oxygen and alcohol take part in epoxidizing and alkoxylating reactions to generate diolmonoether or dioldiether compounds which has higher octane number, so being excellent gasoline component.

本发明公开了一种清洁汽油的生产方法，在一个具有环氧化的催化剂以及同时具有烷氧化催化组分或者催化剂的存在下，汽油中的烯烃与氧、醇、发生环氧化、烷氧基化反应而生成二醇单醚或二醇双醚类化合物，这类化合物具有较高的辛烷值，是优良的汽油组分。

Recent developments of clean oxidation systems catalyzed by polyoxometalates are summarized in detail. The emphasis is on the epoxidation reaction of olefinic compounds, oxidation of alkanes and aromatic compounds with the comparatively ideal oxidants, hydrogen peroxide and molecular oxygen respectively.

文本总结了多金属氧酸盐在液相清洁催化氧化方面的进展，主要针对以过氧化氢和分子氧为氧化剂的烯烃类化合物的环氧化反应、烷烃和芳香族化合物的氧化反应，并详细探讨了此类氧化反应的反应机理。

Recent developments of clean oxidation systems catalyzed by polyoxometalates are summarized in detail. The emphasis is on the epoxidation reaction of olefinic compounds, oxidation of alkanes and aromatic compounds with the comparatively ideal oxidants, hydrogen peroxide and molecular oxygen respectively. The oxidation mechanisms are elucidated in detail.

文本总结了多金属氧酸盐在液相清洁催化氧化方面的进展，主要针对以过氧化氢和分子氧为氧化剂的烯烃类化合物的环氧化反应、烷烃和芳香族化合物的氧化反应，并详细探讨了此类氧化反应的反应机理。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！