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氧化乙酰

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The second synthetic strategy commenced from butane-1,4-diol 50, which underwent monobenzylation, Swern oxidation, enolization followed by acetylation and debenzylation to yield an intermediate 46 in an overall yield of 54% in a 4-step procedure.

第二条路线从1,4-丁二醇50开始,这个化合物经过单苄基化、Swern氧化、烯醇化随后乙酰化和脱苄基化共4步反应得到中间体46,总产率54%。

If you have just eaten a meal rich in fatty acids but low in carbohydrate s, how does this regulatory property shut down the oxidation of glucose to CO2 and H2O but increase the oxidation of acetyl-CoA derived from fatly acids?

如果你刚进食了一顿富含脂肪酸而少有碳水化合物的食物,这个调节装置如何关闭葡萄糖氧化为CO2和H2O但是增加来源于脂肪酸的乙酰辅酶A的氧化?

In order to study the mechanism of the biotype of Galium aparine resistant to tribenuron-methyl, the differences on ALS, GSTs, SOD and POD of the resistant and susceptible biotypes to tribenuron-methyl were preliminarily determined.

为探讨猪殃殃Galium aparine抗药性生物型对苯磺隆的抗性机制,测定了苯磺隆对猪殃殃抗性、敏感生物型体内靶标酶[乙酰乳酸合成酶]、代谢酶[谷胱甘肽-S-转移酶]及抗氧化酶影响的差异。

Treatment under mild condition with solvent of lower polarity was in favor of keeping the molecular structure and properties such as water-solubility, gelatination, etc. Acetyl groups were partially eliminated when purified by Pb2 method, leading to increased crystallinity and glass temperature, which resulted in losts of water-solubility and gelatinability. Owing to the slight oxidative degradation with H2O2 method, the changes of chain size and some functional groups of KGM molecule led to decrease of viscosity and excessive swelling rate.

采用温和条件及低极性溶剂有利於保持KGM本身的分子结构以及水溶性、凝胶性等性能;而Pb2法由於部分脱去了KGM的乙酰基,导致结晶度变大,玻璃化温度升高,最终失去水溶性和凝胶性;H2O2法则由於对KGM造成了氧化降解,也改变了分子链的大小以及部分基团,从而导致粘度降低以及溶涨速度较快。

Catalytic oxidation ; p nitrotoluene ; p nitrobenzoic acid ; Co 2

催化氧化;对硝基甲苯;对硝基苯甲酸;乙酰丙酮钴

A series of neutral organophosphorus compounds including trialkylphosphates,dialkyl alkylphosphonate,alkyl dialkyI phosphinate,trialkyl phosphine oxide andalkyl esters of phosphorus acid have been separated by reversed phase chromatographyon acetylated paper.

一般中性磷化合物(磷酸三烷基酯、烷基瞵酸二烷基酯、二烷基瞵酸烷基酯、氧化三烷基瞵、亚磷酸二烷基酯及亚磷酸三烷基酯)皆能借乙酰化滤纸为固定相,进行纸上层析分离鉴定。

The experiment research indicates: contrasting with thecontrol groups, Bushen Huoxue Huatan Prescription has the following functions: 1. improving the praxiology function of model rats, 2. improving the activity in cholineacetyl-transferase in hippocampus tissue, 3. increasing the expression of NOS in hippocampus region of cortex, 4. promoting the expression of the synapse P3, in hippocampus region of cortex, 5. reducing obviously the apoptosis number of brain nerve cell .

实验研究表明:与对照组比较,补肾活血化痰方具有:1、改善动物行为学功能;2、提高海马组织胆碱乙酰转移酶活性;3、增加皮质及海马区一氧化氮合酶的表达;4、促进皮质海马区突触素蛋白P_(38的表达;5、显著降低脑神经细胞的凋亡数目。

Through salification, esterification, hydrogenation, condensation, oxidation and halogenation etc.,LA can produce useful chemicals and new polymer materials.

同时它具有良好的反应活性,通过成盐、酯化、加氢、缩合、氧化和卤化等化学反应,可制得各种各样有用的化合物和新型高分子材料,因此乙酰丙酸有望成为一个基于生物质资源的新平台化合物。

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合,采用双氧水为氧化剂,在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应,手性亚砜的对映选择性为72%-95%ee,产率为42%-83%。

Hideyuki Doi, Nakui Madaki, Hrroshi, Hiromichi Komatsu, Keisei Fujimori and Susumu Satomi Tohoku. A New Preadipocyte Cell Line,AP-18,Established from Adult Mouse Adipose Tissue. J.Exp.Med,2005,207:209-216[2] Tontonoz P, Hu E, Spiegelman BM. Stimulation of adipogenesis in fibroblasts by PPARγ 2, a lipid-activated transcription factor. Cell ,1994,79:1147-1156

PPARα调节脂肪代谢的机制总结如下:肝脏脂肪酸水平的增高激活PPARα,然后转录激活参与脂肪酸氧化的基因;配体与之结合后可激活编码乙酰辅酶A合成酶的基因,同时PPARα激活后可调节脂肪转运相关基因的表达如PPARα升高高密度脂蛋白和抑制ApoC-Ⅲ的表达。

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