氧丙环

In this paper , two fluorocarbon amphoteric phosphate surfactants were synthesized and their performances were determined.

首先，磷酸二氢钠与环氧氯丙烷开环加成合成2-羟基-3-氯丙基磷酸酯钠，分离提纯后，分析其红外。

Three ways leads to the synthesis of fenclorin, one way discussed here has 3 steps. Stepl :benzonitrile using as raw material goes though dry hydrogen chloride and becomes a-imino phenylmethyl ether after meet carbinol.

解草啶的合成主要有三条路线，本文选取合成路线是以苯甲腈为原料，经三步反应而成：1、苯甲腈在干燥的氯化氢通入，与甲醇形成亚氨基苯甲醚，通入氨气后置换甲氧基得到苯基脒盐酸盐(收率76.18%)。2、苯基脒盐酸盐在碱性条件下与丙二酸二乙酯环合而得嘧啶醇(收率84.39%)。3、嘧啶醇在三氯氧磷中羟基被氯化得到产品解草啶(收率87.29%)。

Products has led caprate cobalt, cobalt naphthenate, TY series of high-performance polyimide resin, FLQ type latent epoxy curing promoting agent, diallyl bisphenol A Product dozens of top-five.

主导产品有癸酸钴、环烷酸钴、TY系列高性能聚酰亚胺树脂、FLQ型潜伏性环氧固化促进剂、二烯丙基双酚A五大类数十种产品。

The intermediate of flazasulfuron weedicide ,2-amino-4,6-dimethoxypyrimidineis conveniently obtained by treating 2-amino-4,6-dihydroxypyrimidinewith diazomethane at 20 °C for 24h.

本文利用硝酸胍和丙二酸二乙酯为起始原料，经环合及甲氧基化两步反应得到除草剂啶嘧磺隆的中间体：2-氨基-4，6-二甲氧基嘧啶。

Cyclization: cyclization occurs at 100℃in polyphosphoric acid for 4h in the mass ratio of 3-(4-methoxyanilino) propionic acid to PPA with 1:8, and 6-methoxy-2,3-dihydro-4-quinolone is formed in 50.5% yield with a method of rapid chromatographic column, c.

成环反应：质量比[3-(4-甲氧苯氨基)丙酸∶多聚磷酸]=1∶8，反应温度为100℃，反应时间4h，柱层析纯化后6-甲氧基-2，3-二氢-4-喹啉酮的收率为50.5％；c。

By using tetramethylammonium hydroxide as catalyst, a new silicone, amino and long-chain alkyl co-modified polysiloxanes was synthesized by bulk polymerization of octamethylcyclotetrasiloxane (D4), N-β-aminoethyl-γ-aminoproylmethyldimethoxysilane (YDH-602), dodecylmethyldimethoxysilane (HD-109) and hexamethyldisiloxane. The optimum experimental conditions were studied.

以八甲基环四硅氧烷(D4)、长链烷基甲基二甲氧基硅烷(HD-109)、N-β-氨乙基－γ-氨丙基甲基二甲氧基硅烷(YDH-602)和六甲基二硅氧烷为原料，在四甲基氢氧化铵催化下，采用本体聚合反应合成了一种新型硅油－氨基与长链烷基共改性硅油。

Bezaldehyde was used as protective agent in first method.S-Epichloeohydrin was aminated and acidulated to give(2S)-1-Amino-3-chloro-propanol Salts.The acetylation of (2S)-1-Amino-3-chloro-propanol by acetic anhydride produced the intermediate-N-[2--3-chloropropyl]acetamide.And then at 20℃,in the presence of lithium tert-butoxide,benzyl 3-fluoro-4-morpholinophenyl carbamate react with-N-[2--3-chloropropyl]acetamide to give linezolid in total yield of 43.6%.

路线一采用苯甲醛作保护剂，使S-环氧氯丙烷氨解、酸化生成S-1-氨基-3-氯-2-丙醇盐酸盐，然后经乙酰化反应后，生成中间体-N-[2-乙酰氧基-3-氯丙基]乙酰胺，再用N-(3-氟-4-吗啉苯基)氨基甲酸苄酯和中间体在催化剂叔丁醇锂存在下25℃反应生成利奈唑酮，总产率达到43.6%。

Intend to use the most advanced technologies in building the 20,000 t/y propylene oxide plant, hydrogen peroxide and propylene as raw materials. Process control using phase transfer catalyst reaction of propylene oxide technology, non-polluting, non-joint products.

拟采用国内先进技术建设2万吨/年环氧丙烷生产装置，以双氧水和丙烯为主要原料，生产工艺采用反应控制相转移催化丙烯氧化技术，无污染、无联产品。

E. . The epoxidation of cis-allylic alcohols is difficult, and with 20％mol Ti 〓 and 30％mol tartrates, up to 80％e.

的对映选择性被得到；对难于环氧化的顺式烯丙基醇，使用20％mol四异丙氧基钛和30％mol酒石酸酯得到最高80％e.e。

ABSTRACT: In the presence of sodium t-butoxide and DMSO,ethyl 2-oxocyclopentanecarboxylate was subjected to C-alkylation with 2-(4-bromomethylphenyl)propanoic acid with high regioselectivity to give 2-［4-(1-ethoxycarbonyl-2-oxo-1-cyclopentanylmethyl)phenyl］propanoic acid (4) which was followed by hydrolysis,decarboxylation and salt formation to afford loxoprofen sodium in about 72% overall yield.

在叔丁醇钠和二甲基亚砜的存在下，2-丙酸对2-乙氧羰基环戊酮进行C-烷基化，再经水解脱羧，成盐即得洛索洛芬钠，以2-丙酸计算，总收率为72%。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。