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In this paper, eleven benzothiazole derivatives such as N, N, N′, N′-tetra (2-benzothiazolyl) methyl-1, 2-ethanediamine,(2-benzothiazolyl) methyloxy benzene, 2,4-dichloro( 2-benzothiazolyl) methyloxy benzene, O-di(2-benzothiazolyl) methyloxybenzene, P-di(2-benzothiazolyl) methyloxy benzene, 3-(2-benzothiazolyl) pyridine were synthesized by means of conventional method or MWI technology and a single crystal of di (2-benzothiazolyl ) methyl ether was obtained.

本文分别用常规合成法和微波辐射法合成了N,N,N′, N′-四(2-苯并噻唑基)甲基-1,2-乙二胺、(2-苯并噻唑基)甲基苯、2,4-二氯-(2-苯并噻唑基)甲基苯、邻-二(2-苯并噻唑基)甲基苯、对-二(2-苯并噻唑基)甲基苯、3-(2-苯并噻唑基)吡啶等11 个苯并噻唑类化合物并得到二(2-苯并噻唑基)甲基醚单晶。

Amino-6-methoxy Benzothiazole 99%、2-Amino Benzothiazole 99%、Veratraldehyde 99%、Veratric Acid 99%、1,2- Dimethoxy Benzene 99%、6-Nitroveratric Acid 97%、2,5-Dichlorobenzoic Acid 99%、4-Chloro-3-Nitrobenzoic Acid 99%、 3-Nitrobenzole Acid 98%、p-Methoxybenzoie Acid 99%、Anisole 99.5%、p-Methoxyacetophenonc 99%、(2'-Chloroethyl) Benzene 99%、(2'-Bromoethyl) Benzene 99%、N,N-Diethyi-m-Toiuamide 99%、Aminoacetonitrile Hydrochloride 98%、 Alkyl Diphenyl Phosphate Estrel 98%、5-Chloro-2-benzothiazolone 99%、6-bromo-2-naphthol 98%、6-Nitro-Veretric Acid Estrel 97%、4-chloro phenoxyaeetic 99

2-氨基-6-甲基苯骈噻唑、2-氨基苯骈噻唑、藜芦醛、藜芦酸、藜芦醚、6-硝基藜芦酸、2,5-二氯苯甲酸、3-硝基-4-氯苯甲酸、3-硝基苯甲酸、对甲基苯甲酸、苯甲醚、对甲基苯乙酮、β-氯代苯乙烷、β-溴代苯乙烷、N,N-二乙基间甲苯甲酰胺、氨基乙腈盐酸盐、磷酸二苯月桂酯、5-氯-2-苯骈噻唑酮、6-溴-2-萘酚、6-硝基藜芦酸甲酯、4-氯苯乙酸

New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物:含五元膦-螯合环的1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-螯合环的[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-螯合环的[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明,配合物46、47都为变形的四方锥构型,膦-与钌形成螯合配位,其中苯亚甲基与钌的配位得以加强。

Bubbleless aeration using membrane is a new-developed technology of oxygen supply for aerobic bacteria in wastewater treatment, and the gas pressure has been proved a key factor for applying bubbleless aeration .

膜法无泡供是一新兴高效好生物处理水体污染的供技术,气相操作压力是实现无泡供的关键因素。

Dimethyoxyphenyl Lithium and 2,4,6-trimethoxyphenyl Lithium could also react whth γ-butyrolactone to produce -hydroxypropyl 2,4-dimethoxyph

2,4-二甲基苯基锂和2,4,6-三甲基苯基锂也能与γ-丁酸内酯反应分别生成γ-羟丙基-(2,4-二甲基苯基)酮和γ-羟丙基-(2,4,6-三甲基苯基)酮。

As the fourth generation of bacteriophage medicinesuch as carbostyril, Levofloxacin Hydrochlo-Ride is ofloxacin is the updating and upgrading product, its clinic dosage only is onehalf of ofloxacin, but its curative effect is obviously better than ofloxacin.

盐酸左氟沙星作为第四代喹诺酮类抗菌药,是氟沙星的升级换代产品,其临床用量仅为氟沙星的一半,而疗效却明显优于氟沙星。

A series of 2-oxocyclododecyl sulfonylurea s have been synthesized from 2-oxocyclododecylsulfonamide via acylation of phenyl chloroformate and amination.

以环十二酮为起始原料,经磺化反应制备得到2-代环十二烷基磺酸盐B,B经过氯化和胺解反应制备得到2-代环十二烷基磺酰胺C,C经过苯酰化与胺解反应后合成了10个新的2-代环十二烷基磺酰脲类化合物D,它们的结构通过了1HNMR和IR的确证。

The paper has experimentally studied the explosive limit ed oxygen concentration and critical oxygen concentration of effect of coal mine combustive gases.

目前对可燃性气体的临界浓度的研究大多数都是对单元气体进行的,通过对煤矿可燃性气体的爆炸极限浓度和临界浓度进行的实验研究,对煤矿可燃性气体临界浓度的影响因素进行了分析,得出的数据及结论为煤矿瓦斯的安全防爆工作提供了理论基础。

Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型,其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根螯合配位, 2个酒石酸根中剩下的4个羧酸根中的2个分别与2个Zn2原子连接形成无限一维链, Zn2原子的另外2个反式赤道配位点被2个水分子占据,同时这两种Zn原子的轴向配位点均被4,4'-联吡啶的氮原子占据,形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构,游离的2个水分子通过氢键作用形成二聚体,并与酒石酸根中未与Zn配位的羧酸连接,把二维层状结构连接成三维网状的超分子结构。

In biodegradation study, debromination of 4-monobrominated diphenyl ether (4-BDE) is investigated with aerobic and anaerobic sludges. This also is the first report demonstrating microbaially mediated biodegradation of 4-BDE under aerobic conditions. 4-BDE biodegraded within 11 days by 68 % and 83 % with toluene and diphenyl ether, respectively, as second carbon sources to stimulate biodegradation.

本研究之生物降解部分,以酒厂之好及厌活性污泥及经PCE驯化之厌活性污泥能有效降解一溴联苯醚(4-mono-BDE, 4-BDE),结果证实了在好情况下微生物降解PBDEs的可行性,而补助碳源的添加有助於提高降解速率,在甲苯或联苯醚存在的情况下,11天内4-BDE分别降解了68 %及83 %。

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