氢离子

Synthesis of the phenylhydrazone, oxime and semicarbazonederivatives of calix[4]arenesThe reaction of p-formylcalix[4]arenes with phenyl hydrazine,hydroxylamine hydrochloride or semicarbazide hydrochloride afforded thephenylhydrazone, oxime or semicarbazone derivatives of calix[4]arenes,respectively.

酯型杯[4]冠醚的全醚化及性能研究利用氢化钠作为碱，对酯型杯[4]冠醚剩余酚羟基进行烷基化，合成中性杯芳烃酯型冠醚，初步研究了其对金属离子、有机阳离子和中性分子的识别情况，发现其对这些底物缺乏有效作用能力。

From the literatures reported, the study of polarographic catalytic wave for inorganic metal ions has made a great progress.

从国内外报道的极谱催化波文献来看，无机金属离子的催化波研究已取得了很大进展，有平行催化波，络合物极谱催化波和铂族元素的氢催化波等多种类型。

For the above purposes, using a tailored cyanometalate precursor,(1) Tp=hydrotris (pyrazolyl borate; Bu〓N〓=tetrabutylammonium cation , two trinulear complexes,〓(2),〓(3; cyclam: 1, 4, 8, 11-tetraazacyclotetradecane), two one-dimensional polymers,〓(4; dien: diethylenetriamine),〓(5), and a cluster 〓(6) have been synthesized and characterized structurally and magnetically.

基于上述研究热点，我们以修饰的氰基金属化合物(1)为构筑基元（Tp：三吡唑基氢硼烷，Bu〓N〓：四丁基铵离子），合成了两个杂三核化合物，〓(2)，〓（3；cyclam：1，4，8，11-四氮环十四烷），两个一维聚合物，〓（4；dien：二乙烯三胺），〓(5)，和一个十四核簇合物〓(6)。

Organocatalyst ; N-methylimidazole ; aromatic aldehyde ; multi-component reaction ; Knoevenagel condensation reaction ; ionic liquid rhodanine ; decahydroacridine

广东省自然科学基金；国家自然科学基金有机小分子催化剂； 1-甲基咪唑；芳香醛；多组分反应； Knoevenagel缩合反应；离子液体；罗丹宁；多氢吖啶

The effect of ion exchange of Y-MCM-41 on the hydrogenation activity of Pd-Pt/Y-MCM-41 in tetralin hydrogenation reaction was examined wit...

结果表明，采用不同离子交换处理的载体所制备的催化剂，其金属的负载量、金属与载体间的相互作用存在差别，从而影响催化剂的加氢活性和选择性。

One of them was identified as aldehyde dehydrogenase 2, and the others were both identified as mouse RIKEN cDNA 2900053E13, suggesting that the protein might be post translationally modified.

通过对差异蛋白的胶内酶解和高效液相色谱／离子阱质谱鉴定，发现其中一个蛋白点为乙醛脱氢酶2（aldehyde dehydrogenase 2），另外两个差异点鉴定结果为同一个蛋白RIKEN cDNA 2900053E13，提示该蛋白在正常和心肌缺血心肌的线粒体内修饰状态发生了变化。

Hydroesterification of tert-butyl alcohol with ethanol catalyzed by transition metal triphenylphosphine complexes was first investigated in room temperature ionic liquids.

反应温度为100～140 ℃，CO初始压力为2～6 MPa条件下，研究了室温离子液体与过渡金属三苯基膦配合物构成的催化反应体系中，叔丁醇与乙醇的氢酯基化反应。

The mutagen mechanism is presumed single factor dominant.(4)There was 85 percent transvertion in mutagen spectra, and they were all G:C→T:A transvertion. The maximal possibility of mutagen mechanism is analyzed as followed:ion beam implant → breakage cell surface and enter the interior → stimulate plentiful radical born → radical oxidize and damnify DNA → G becomes 8—oxoG → 8—oxoG pairing A → result in G:C→T:A transvertion(5)Production of transition was presumed that ion beam implantion damnified DNA, stimulate activity of MMR interveniented by methyl reducing.

诱发突变谱中碱基颠换比例是0.85，且是全部G：C→T：A颠换，推测低能离子束诱变鼠伤寒沙门氏菌得分子机制可能为：离子注入→通过破坏细胞表面进入内部→刺激产生大量自由基→自由基氧化损伤DNA→G变成8氧—7，8—二氢鸟嘌呤(8—oxoG)→8—oxoG与A配对→导致G：C→T：A颠换。

By studying the alkali erosion mechanism and alkali resistance of glass fibers,the paper comes to conclusions that the corrosion of glass fibers by cement matrix includes the chemical action of hydroxide ions and silica tetrahedrons and the physical action in the static fitigue process,and that glass fibers behave quite differentl.

通过对玻璃纤维碱侵蚀机理和耐碱性的探讨，得出了水泥基对玻璃纤维的腐蚀作用包括氢氧离子和硅氧四面体的化学作用和静态疲劳过程的物理作用及玻璃纤维因成分和结构的不同有很大的差异等结论。

Dihydropyrimidin-2 (1H)-ones were synthesized by condensation of aromatic or aliphatic aldehydes, urea and ethyl acetoacetate or acetylacetone one-pot three-component Biginelli condensation in the presence of room temperature ionic liquids as catalysts under solvent-free conditions.

5利用室温离子液体作催化剂，芳香或脂肪醛、尿素和乙酰乙酸乙酯或乙酰丙酮三组分缩合制备3，4-二氢嘧啶-2-酮衍生物。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。