氢离子

Selective hydrogenation for pentadiene in FCC C 5 fractions and hydroetherification of tertiary pentanes with methanol were investigated.

采用离子交换法制备了Pd/D0 0 5树脂催化剂，对催化裂化C5 馏分中戊二烯的选择性加氢和叔戊烯与甲醇的临氢醚化反应进行了研究。

A Pd /D005 resin catalyst was prepared by using ion exchangemethod.Selective hydrogenation for pentadiene in FCC C5 fractions and hydroetherification of tertiary pentanes with methanol were investigated.

采用离子交换法制备了Pd/D005树脂催化剂，对催化裂化C5馏分中戊二烯的选择性加氢和叔戊烯与甲醇的临氢醚化反应进行了研究。

A Pd /D005 resin catalyst was prepared by using ion exchange method.Selective hydrogenation for pentadiene in FCC C5 fractions and hydroetherification of tertiary pentanes with methanol were investigated.

摘 要：采用离子交换法制备了Pd/D005树脂催化剂，对催化裂化C5馏分中戊二烯的选择性加氢和叔戊烯与甲醇的临氢醚化反应进行了研究。

The best catalytic activity and selectivity could be found in the prepared catalyst system with the optimum combination of the ionic liquid, nano-Pd, and support. The stabilizer is also used to prevent the aggregation of nano-Pd particles. One of the advantages of this approach is that the prereduction of catalyst is not required.

其中离子液体、奈米钯金属及担体皆有其功能，三者之组合才能达到良好之效果，同时，在合成奈米钯过程中，必须使用稳定剂以避免奈米钯金属之聚集此触媒系统之另一优点为不需先加氢还原处理，耐水性强且可重覆使用，是一种颇具潜力之选择性氢化触媒。

Starting from the hydroxylamine (dimethyl amino ethanol, triethanolamine) and 1, 3-propane sultone, a series of hydroxyl and sulfonyl dual-functionalized zwitterionic salts were synthesized. Then dual-functionalized ionic liquids containing both hydroxyl and sulfonyl functional groups were produced successfully by zwitterionic salts and three kinds of strong acids (p-toluene sulfonic acid, trifluoromethanesulfonic acid, methanesulfonic acid) respectively. The structure of zwitterionic salts and dual-functional ionic liquids were confirmed by the 1H NMR and IR.

以羟基有机胺(N，N-二甲基乙醇胺，三乙醇胺)为原料与1，3-磺酸内酯反应合成了一系列含有羟基和磺酸基双官能团的内盐，并将所得到的内盐分别与三种强酸(对甲苯磺酸，三氟磺酸，甲磺酸)反应，成功地合成了双功能化室温离子液体，并通过红外光谱、核磁氢谱测定，证实了内盐和双功能化离子液体的结构。

The carboxyl of the tripodal ligand is a goodbridging group. The building blocks are linked together by the bridging group andother weak interactions (hydrogen bond and π-π stacking interaction, etc), thusgenerating a one, two or three-dimensional metal complexes.2. Studies on the fluorescence properties of the lanthanide complexes indicated that:(1) The excitations in the ligand-based π-π〓 transitions cause the structuredemission of lanthanide complexes while the ligand luminescence is completelyquenched showing that ligand-to-metal energy transfer occurs.

三脚架配体所带的羧基是一个很好的桥联基团，配合物的结构基元通过这种基团的桥联作用及其它一些弱的作用力(如氢键、π-π堆积作用等)联系起来，构成了一维、二维或三维的超分子空间结构。2、稀土配合物的发光研究发现：(1)用配体的π-π〓跃迁波长进行激发，配合物均显示出稀土离子的特征发射峰，同时，配体的荧光峰没有出现，这说明在三脚架配体与稀土离子间进行了有效的能量传递。

Compared of the efficiency of treating heavy metals in FGD wastewater with NaOH, Ca_2 and Mg_2. It indicated that NaOH was much efficient for precipitated waste water; Ca_2 was much efficient for unprecipitated waste water, the removal efficiency reached 98.4%. With the increasing of the main ion of Ca~2+, Cl~- in FGD wastewater, the efficiency decreased. It decreased 60% for the removing of Mn and 10% for Zn, Cd and Ni. The rectification coefficient token the Ksp of practical wastewater because it quite different with theoretic Ksp at different pH; the theoretic and practice addition were proportioned and it commonly reached 1:300.The precipitation efficiency of Na2S at different pH and the effect of Ca2+ was determined.

比较了NaOH、Ca_2和Mg_2处理脱硫废水时重金属的去除效果，分析了Ca~(2+)、SO_4~(2-)和Cl~-等主要离子的影响，结果表明：NaOH和Ca_2能有效处理脱硫废水中的重金属；对澄清废水而言，NaOH效果较好，对于未澄清废水而言，Ca_2效果更好，但去除废水中重金属的效率都能达到98.4%；随着Ca~(2+)、Cl~-等主要离子浓度的增大，中和作用去除重金属的效率降低，Mn最大降低60%，Zn，Cd，Ni降低10%左右；实际重金属浓度和用理论Ksp计算所得值差别很大，通过校正系数能有效计算实际重金属浓度；实现相同pH时氢氧化物的理论和实际投加量成一定比例，最大可达1：500。

From the analysis of FT-IR spectra, XRD patterns and SEM morphologies, the special functions of the chelating agents as follow: citric acid chelates metal ions, EDTA adjusts pH values and ethylene glycol polymerizes complex and replaces hydrogen bonds in SBT sol solution.

利用红外光谱、X衍射及扫描电镜等手段，证明柠檬酸主要起络合金属离子作用；EDTA除辅助交联金属离子外，主要用于调节pH值；而乙二醇用来聚合柠檬酸和EDTA，防止氢键产生，起稳定溶胶作用。

Therefor the key of gaining more sulfurs from sulfide is the strict controlling of the temperature and current.

实验结果表明：电流密度、温度、氢氧根离子浓度、硫氢根离子浓度和电解液的流速等对电解反应都将产生一定的影响；其中电流密度和温度对电解反应的影响最大，对于循环溶液的电解反应，严格控制温度和电流密度，是获得较高转化率的关键。

The oil shale ash is disintegrated into fine powder less than 150 eye to be calcined at a certain temperature, then sulfuric acid solution is added for performing acid dipping, after solid-liquid separation and solid residue removal, aluminum sulfate solution is obtained and is then filtered after sodium hydroxide solution is added in, further metallic ions as Ca2 , Mg2 , Fe3 , Fe2 and the like are filtered from the solution, thereby sodium aluminate solution is obtained, gas of carbon dioxide is communicated into the sodium aluminate solution to obtain aluminum hydroxide sediment, and after drying and calcining aluminum hydroxide powder is obtained.

将油页岩灰渣粉碎至＜150目的细粉，在一定温度下煅烧，加入硫酸溶液进行酸浸，固液分离，去除固体残渣，得硫酸铝滤液，加氢氧化钠溶液后过滤，滤除溶液中的Ca 2 、Mg 2 、Fe 3 、Fe 2 等金属离子，得偏铝酸钠溶液，向偏铝酸钠溶液通入二氧化碳气体，得到氢氧化铝沉淀，经烘干、煅烧得到氢氧化铝粉末。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。