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Molecular configurations in LB films undergo change from keto form to zwitterion assurface pressures increase,companied by intermolecular hydrogen bonds decreaseand intramolecular hydrogen bonds increase.

在LB膜中,随表面压增加,分子间氢键减少,分子内氢键增加,SBC18头基构型在转折区发生醌式→双性离子构型转变。

When surface pressures are lower than the turnover(5~30mN/m),intermolecularhydrogen bonds were formed with keto form and phase transition was higher ca.60℃;most of SBC18 formed intramolecular hydrogen bonds companied withzwitterion form and phase transition was lower ca.48℃ while at surface pressurehigher than the turnover(≥45mN/m),which is caused by the different interchaininteraction arising from various hydrogen bonds for SBC18 LB film deposited atdifferent surface pressures.

低于相应π-A等温线转折(5~30mN/m)时,以分子间氢键为主,头基主要以醌式构型存在,相变温度较高(≈60℃);高于转折(≥40mN/m)时,以分子内氢键为主,头基主要以双性离子构型存在,相变温度较低(≈48℃)。

The isotopic composition of hydrogen and oxygen in heavy water are analyzed by using a high-resolution mass spectrometer.

用高分辨率质谱计分析了重水中氢与氧的同位素组成;分析了重水的分子组成、质谱中的单电荷离子;利用高分辨率质谱峰相对强度,计算了重水中的氢氧同位素组成。

The results indicated that the proton transport number and fuel cell performance of BaCe_(0.8)Y_(0.2)O_(3-α) synthesized by sol-gel method could be obviously affected by sintering temperature.

以烧结体样品为固体电解质、多孔性铂为电极,组成氢及氧浓差电池、氢-空气燃料电池,测定了BaCe_(0.8)Y_(0.2)O_(3-α)烧结体的质子和氧离子迁移数以及燃料电池的性能,并与高温固相反应法合成的样品进行了比较。

In the first part, two novel methods were proposed for the determination of three kinds of organogermanium compounds βcarboxyethylgermanium sesquioxide,β- carboxyethylgermanium sesquioxide and di-(β-carboxyethyl) germanium hydroxide by using high performance ion-exchange and ion-exclusion chromatography.

第一部分采用高效离子交换和离子排斥色谱法,建立了两种测定三种有机锗化合物β-羧乙基锗倍半氧化物、β-羧乙基锗倍半氧化物、二-锗氢氧化物的新方法。

Lithium ion battery, Ni-MH (Nickel-Metal hydride) battery, F uel cell , Metal hydride (AB5 type metal hydride, Mg-based metal hydride, NaBH4 etc.) and its application, Syntheses and measurement of structural material and catalyst, Inorganic chemistry, Applied e le ctrochemistry

锂离子电池;镍氢电池;燃料电池;金属氢化物( AB5型稀土系合金,镁基合金,硼氢化物等)及其应用;催化剂和结构材料;无机化学;应用电化学

Heated in water bath,uranyl ion and nitrate radical adsorbed on resin are replaced into solution by sodium bisulfate,then are determined by titanous method and spectrophotometry,respectively.

在水浴加热条件下,用硫酸氢根将吸附在树脂上的铀酰离子和硝酸根离子置换到液相中,之后分别采用亚钛法、分光光度法进行测定。

Their catalytic performances in selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde were investigated.

以肉桂醛选择性加氢合成苯丙醛为模型反应,考察了离子液体的结构对Ni/SiO2催化剂性能的影响,并对肉桂醛加氢反应条件进行了优化。

CuRF coupounds are based on the combination of deprotonation and ICT mechanisms. The secondary amines conjugated to 1,8-naphthalimide could be deprotonated by Cu2+, and as a result, large red shifts in both absorption and fluorescence spectra were obtained, from which one could sense Cu2+ colorimetrically and ratiometrically.

CuRF 系列则是基于脱氢和ICT原理的结合,铜离子与受体的作用能够诱使共轭氮原子上的氢脱去,共轭氮原子显负电增强了对荧光团的供电能力,从而引起荧光波长的红移,同时也造成了吸收光谱的红移。

Aluminum phosphate (AlPO 4) can be prepared by solid state synthesis with different templates, aluminum chloride and ammonium diacid phosphate at low temperature (180℃) within a short time (2 h).

以氯化铝和磷酸二氢铵为原料,在模板剂存在下用固相合成方法合成了磷酸铝类化合物,合成的化合物通过化学分析、ICP测定、XRD和 IR图谱对其进行了表征,研究了化合物对铬离子吸附性能,实验表明这类化合物对铬离子有较好的吸附能

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