氢离子

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构，化合物8是白花丹素的Na盐，以离子化合物形式存在；化合物9～16为白花丹素的La，Y，Dy，Sm，Gd，Nd，Er，Eu的稀土金属配合物；化合物17是白花丹素的双核钇结构；化合物18为白花丹素的单核钇结构，该配合物除了含白花丹素外，还有来自白花丹植物中的另一个单体化合物也参与配位；化合物19～21是以2，2\'-联吡啶和邻菲咯啉等含N配体为辅助配体，具有白花丹素—含N配体—金属离子的三元配合物，化合物19是白花丹素和2，2\'-联吡啶与Cu的配合物，具有五配位的四方锥构型，通过Cu…O弱的成键作用形成二聚体，再通过分子间的氢键作用进一步形成一维链状结构，化合物20和化合物21是白花丹素分别与2，2\'-联吡啶和邻菲咯啉的Zn配合物，都具有六配位八面体构型的双核锌配合物，呈一维链状结构，化合物20中链与链之间的大量氢键将一维链扩展成二维层，分子间的π-π堆积作用进一步形成三维结构。

For H_2~+ molecule, the basic theory model is the same as that for a single proton, but adding in the interactions of fragment ions, concluding Coulomb forces and wake-like interaction. Then the trajectories of each of the fragment ions can be simulated in order to further study the vicinage effect.

对于氢分子离子在碳纳米管中的库仑爆炸过程，基本理论模型与求解单个离子时所采用的相同，但是考虑了离子之间的相互作用力，包括库仑相互作用与尾流效应，计算出分子离子中每个离子的运动轨迹，从而对邻近效应进行分析。

The initial interaction modes of pyreno[2,1-b]pyrrole and its dimeric derivative with F in MeCN can be understood as hydrogen-bonded complexes. Excess F ions promotes deprotonation of N-protons and results in the bathochromic changes in both absorption and fluorescence spectra.

实验过程中发现，在初始模式中，芘骈吡咯及双芘骈吡咯与氟离子形成氢键附合物；之后加入的氟离子，因其带有极强的碱性，将促使吡咯官能基中氮上氢进行去质子化，而造成吸收及萤光光谱的红位移现象。

The effect of zeolites ion-exchanged by transition metals on thermal catalytic cracking reaction is studied. The product distributions of the cracking reactions catalyzed by theβor ZSM-5 zeolites exchanged with transition metals are different from that catalyzed by corresponding Hzeolites, which means the mechanism of cracking reactions has varied. Group Ⅷ metals Fe, Co, Ni and Cu, Zn are shown to be of strong catalytic activity of oxidative dehydrogenation, while Ti and Cr are not of oxidative activity. Catalyzed by zeolites or catalyst containing Ag, conversion of thermal catalytic cracking reactions and the yield of ethylene increase while the yield of propylene does not decrease. Silver can not only promote the formation of carbonium ion, but also convert carbonium ion into free-radical via redox reaction. The weak adsorption of olefins on silver reduces the occurrence of hydrogen transfer and dehydrogenation. As a result, the yield of light olefins is favored by silver in the catalyst.

采用过渡金属交换的分子筛作为催化剂，进行催化热裂解制取乙烯的反应，研究发现，在β沸石分子筛和ZSM-5分子筛中引入过渡金属后，催化热裂解反应的产物分布与相应的氢型分子筛相比有了较大的变化，说明过渡金属的加入对于催化热裂解反应的机理具有影响，Ⅷ族金属如Fe、Co、Ni和第Ⅰ、Ⅱ副族Cu、Zn表现出较强的氧化脱氢活性，产物中氢气、焦炭的产率很高，Ti、Cr则未表现出氧化作用：分子筛及催化剂中引入银后，催化热裂解反应的转化率和乙烯的产率有了提高，丙烯产率没有很大的变化，说明银在催化热裂解反应中能够促进正碳离子的生成，又有可能通过氧化-还原作用部分改变反应机理，促进了自由基的生成，并且由于银对烯烃的吸附很弱，其氢转移反应和脱氢、加氢活性比较低，有利于烯烃产率的提高。

Results:Biochemical indicators: the concentrations of K+, Na+ and Cl－ in the serum after the infusion are different with those before the infusion; other indicators don't have the significant difference. The mean infusion time of group A is longer than that of group B (p=0.006), while the dosis letalis of KCl doesn't have significant difference between groups (p=0.062); the concentrations of K+ in blood, Na+, Mg2+ and Cl－ in serum have the significant difference between groups; the urine volume and the concentrations of all the urine electrolyte indicators don't have the statistical significant difference between groups.

结果：生化指标：输入钾前后，家兔血清钾离子浓度升高，钠、钙及氯离子浓度降低，具有统计学显著性差异，p=0.000；全血钾及血清其他离子浓度变化，以p=0.05为标准，不具有统计学显著性差异。A、B两组间比较结果：A组输液致死时间长于B组(p=0.006)，致死输钾量无统计学显著性差异(p=0.062)；全血钾、血清钠、镁及氯离子浓度变化值具有显著差异，血清钾、钙、碳酸氢根离子浓度变化值无明显的差异；尿量和尿液各电解质浓度指标无统计学显著性差异。

Occurrence of RE hydride was identified in the Al-Si alloy containing RE andenrichment of hydrogen in polynary RE intermetallic compound was determined by means ofEPMA, secondary ion mass spectrography, Hg-free vacuum drivepipe hydrogen-meter to-gether with metallography and porosity measurement.

采用电子探针、二次离子质谱、无汞真空套管测氢仪等检测手段，并配合金相分析及试样孔隙度的测定，鉴定出含稀土的Al-Si合金中有稀土氢化物的存在，确认在多元稀土金属间化合物中氢的富集，提出稀土具有较强固氢作用的观点。

This invention relates to method of using boron magnesium fertilizer to produce fiber shape magnesium hydroxide fire retardant. First dissolve boron magnesium fertilizer, then add magnesia and oxydol to solution to carry out sulfuric acid neutralization and ferrous ion oxidation, remove iron ion, then add ammonium bicarbonate to carry out metathetical reaction.

利用硼镁肥生产纤维状氢氧化镁阻燃剂的方法，涉及一种制取纤维状氢氧化镁的方法，首先将硼镁肥溶解，然后向溶液中加入氧化镁和双氧水进行硫酸中和与亚铁离子氧化并除去铁离子，然后对余液加入碳酸氢铵进行复分解反应。

By using density functional theory B3LYP/6-311G++method, the geometric configuration was optimized for tetrahydrofuran、butylene oxide、 secondary oxonium ion and tertiary oxonium ion. And parameters about the electronic structure, bondlength, energy of frontier orbital of these species were determined.

采用DFT中的B3LYP/6-311G++方法对四氢呋喃和环氧丁烷单体、仲氧鎓离子以及叔氧鎓离子进行了几何构型的全优化，确定了各个构型的电子结构、键长和前线轨道能量等参数，并运用前线轨道理论从微观层次上分析了四氢呋喃和环氧丁烷的阳离子均聚反应机理。

Active hydrogen atom and oxygen ion form Hydroperoxy radicals which surround the positively charged biological contaminants, and then react with three hydrogen elements of its protein structure, destroying and detoxicating the biological contaminants nature.

活性氢和氧离子(O2-)形成的氢过氧自由基，会包围着带正电荷的生物污染物，每一枚黏附在污染物表层的氢过氧自由基，会与其蛋白质结构中三个氢元素产生反应，完全破坏其结构，变成无毒状态。

The results indicated that BaCe0.8Ho0.2O(subscript 3-α) sinters are of single-phase structures of orthorhombic perovskite. In the temperature range of 600~1000℃, the nonstoichiometric materials (x=1.03 and 0.97) have higher conductivities in wet hydrogen and wet air and better performances of hydrogen-air fuel cells than the stoichiometric one (x=1). In this series, BaCe0.8Ho0.2O(subscript 3-α) has the highest conductivities 2.10×10^(-2Scm^(-1) in wet hydrogen, 3.46×10^(-2) Scm^(-1) in wet air, at 1000℃ and the maximum power output density 122 mWcm^(-2 at 1000℃.

结果表明，在600~1000℃温度范围内、湿润氢气和湿润空气气氛中，该系列材料的电导率随温度和钡离子含量的变化均与以该系列材料为固体电解质的氢－空气燃料电池性能随温度和钡离子含量变化的次序一致，即：非化学计量组成材料BaCe0.8Ho0.2O(下标 3-α)(x=1.03， 0.97)具有较化学计量组成材料BaCe0.8Ho0.2O(下标 3-α)(x=1)高的电导率和氢－空气燃料电池输出功率密度，其中BaCe0.8Ho0.2O(下标 3-α)有最高的电导率（1000℃时、在湿润的氢气气氛中：2.10×10^(-2)Scm^(-1)；在湿润的空气气氛中：3.46×l0^(-2)Scm^(-1)）和最大的氢－空气燃料电池输出功率密度（1000℃时：122mWcm^(-2)）。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。