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In the charge-discharge tests, for the electrode irradiated by light and charged with current simultaneously, the discharge time is about 11.4 h, much longer than that (about 8.7 h) charged only with current, indicating obvious photo-assisted chargeability of the electrode. The additional discharge capacity is contributed to the photocharge of photogenerated electrons and holes.

HSA/Cr-BIO电极在200μA电流与光照同时充电时比仅200μA电流充电后放电时间长(11.4小时vs8.7小时),所增加的放电容量来自光生电子与空穴对储氢合金电极的充电,表明该HSA/Cr-BIO电极具有明显的光辅助充电性能。

This paper reviews recent developments in the design and assembly of hydrogenase-modified electrodes, wherein the enzyme was immobilized by physical adsorption, self-assembly, sol-gel and Langmuir-Blodgett methods. Electrochemical properties of hydrogenase in the molecular assemblies and biohydrogen production are discussed.

本文综述了氢酶及其分子聚集体薄膜在电极表面的组装技术,如吸附法、自组装法、Langmuir-Blodgett法和溶胶-凝胶法等,并讨论了分子聚集体薄膜中氢酶的结构、生物活性、电化学性质及其在催化产氢方面的应用。

The anodic oxidation reactions of borohydride ion involves a novel and complex reaction system of three hydrogen valence states: protide H(superscript --protium H(superscript 0*-proton H(superscript +. Based on cyclic voltammetry and polarization studies, a multi-step mechanism for the oxidation of BH4-on Cu anode in NaOH solution was presented, and a kinetic expression containing the coverages of BH(superscript - subscript 4) and OH-adsorbed on the surface of Cu anode was deduced by the steady state approximation theory.

鉴于BH(上标-下标 4)阳极氧化反应涉及一个复杂的氢负离子H(上标-下标 4)-氢单原子H(上标 0*)-质子H之间价态转化的新颖反应体系,在循环伏安和极化实验研究基础上,提出了NaOH溶液中BH(上标-下标 4)在Cu电极上氧化反应的多步骤机理,导出了包含表面吸附态BH(上标-下标 4, ad)和OH覆盖率θ和θ的电极反应动力学方程。

Carbon fiber microelectrode has been used as a detector for capillary electrophoresis with end-column electrochemical detection of melatonin, sulfonamide, the traditional Chinese medicine of ash brak, thiolzoles and barbituric compounds.

碳纤维电极的应用,(2)金属 Pd 超微粒碳纤维修饰电极的应用,(3)氢醌类衍生物自组装修饰 Pt 电极的应用,(4)在柱毛细管电极的制作。

In this paper, the effect of modifying procedure of the GC electrode on the electrode reaction kinetics of benzoquinone and the modified mechanism of enzyme electrode havebeen studied.

玻碳电极经电化学氧化处理,可提高苯醒电子中继物电极反应的可逆性,其原因在于电极表面氧化生成的羧基与醌基之间形成氢键,提高了电极表面电子冲继物的浓度,降低了异相电荷传递的活化

It's found that th e activation of alloy was improved with increasing the concentration,temperature and immersing time of alkaline solution,the reason is that the Zr-rich surface of alloy was conversed to Nirich surface because of the strong erodent action of alkaline solution,this catalyzes ...

实验发现:储氢合金电极的活化性能随碱液浓度增大、温度升高以及浸泡时间的延长得到改善,主要由于KOH的强腐蚀性使合金表面由富Zr层转化为富Ni层,为氢的吸附离解起到催化作用,总结出最佳KOH处理液的实验参数:6mol/L、80℃、浸泡 2 4h ,在此条件下合金电极循环两周即达最大放电容量。

The hydrogen precipitation of different metals, platinum, lead, nickel, iron and titanium, were discussed in different pH value and current density. By using Cyclic Voltammetry to study the reduction reaction, copper, titanium, lead, Ti/PbO2 and Ti/MnO2 as cathode respectively, it is proved that sodium metaborate can be electrochemically reduced to sodium borohydride. The kinetic parameters and fractal dimension of these electrode, graphite, lead iron Ti/PbO2 and Ti/MnOa etc, will be researched.

采用循环伏安法,分别以铜、钛、铅、钛、Ti/PbO_2和Ti/MnO_2作为阴极,对该反应进行实验研究,证实了偏硼酸钠电化学还原制各硼氢化钠的可能性;分别对石墨、铅、铁、Ti/PbO_2和Ti/MnO_2等电极在本实验体系中的电极动力学参数(a,b,i_0)及分形维数进行了讨论,认为Ti/PbO_2为该体系中的最佳电极材太原理工大学硕士研究生学位论文料。

Electrochemical hydrogenation of anthracene was carried out in a divided three-electrode cell with spumous Pb as cathode and Pt as anode.

在隔离式电解槽中,以制备的泡沫Pb为阴极,Pt丝为对电极,饱和甘汞电极为参比电极,研究了不同电解体系的伏安曲线和蒽的阴极电化学加氢行为。

One is the interstitial water or zeolitic water, it corresponds to the broad absorptive band at around 3498 cm〓 that results from the association of water owing to the H-bonding. 2 The other is the water coordinated to lanthanum, corresponding to the very strong sharp peak at 3607cm〓, The peaks at around 1600cm〓 were assigned to the bending vibrations of water in LaHCF, two sharp peaks were found at 1601cm〓 and 1624cm〓 respectively, which correspond to two bending vibrations of the interstitial water and the coordinated water respectively in the structure of LaHCF.

通过电化学扫描法,得到了一种有电活性的稀土元素化学修饰电极—铁氰化镧修饰电极;并用循环伏安法进行了表征,比较了碱金属离子Li〓,Na〓,K〓,Rb〓,Cs〓和H〓在膜中的通透性,结果表明氢离子能透过铁氰化镧膜而碱金属离子则不能透过铁氰化镧膜;稳定性研究表明,该修饰电极在纯1.0mol/L HCl溶液中扫描,峰电流迅速下降,到第10圈时峰电流几乎为零,而在混合溶液1.0mol/L KCl+0.10mol/L HCl。

Performance of SBS electrode such as discharge capacity, average discharge potential, rate dischargeability and cycling ability is also satisfactory.

研究了不同粘合剂的MH电极性能,结果表明粘合剂对MH电极性能的影响较大,新型粘合剂SBS是一种很有应用前景的金属氢化物电极粘合剂。

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Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书,王祥生,李德昌。安徽省首次发现嗜群血蜱。

Chapter Three: Type classification of DE structure in Sino-Tibetan languages.

第三章汉藏语&的&字结构的类型划分。