氢化

A novel type of amphiphilic tri-block copolymers with both pH and temperature sensitiveness: poly-poly (dimethylamino ethyl methacrylate)-poly (ε-caprolactone)(PEG-PDMAEMA-PCL) was synthesized via sequential oxyanionic polymerization of macro-molecular: PEG, with a hydroxyl at one end, and dimethylamino ethyl methacrylate andε-caprolactone, with the potassium naphthalene as the initiator.

在本文中，报道了一类新型的兼具pH和温度敏感的双亲性嵌段共聚物：聚乙二醇-聚甲基丙烯酸N，N-二甲氨基乙酯-聚己内酯(PEG-PDMAEMA-PCL)及聚甲基丙烯酸N，N-二甲氨基乙酯-聚己内酯(PDMAEMA-PCL)的制备；并利用动态光散射和氢核磁共振光谱(~1H NMR)对该嵌段共聚物的水溶液性质进行研究；在此研究结果的基础上，初步探讨了其在仿生物矿化中的应用。

The disubstituted ureas and the catalyst could be separated by addition of water and the catalyst could be reused without deactivation.

新型高效的菲咯啉钯-离子液体含氮化合物羰化催化剂体系，以苯胺为反应物时该体系的转化频率可以达到6000mol/mol/h；氢氧化铯-离子液体催化剂体系，可以在不加入化学计量脱水剂的条件下活化二氧化碳与脂肪族胺反应得到二取代脲，反应结束后可以通过加入水实现产品和催化剂体系的分离，催化剂体系可以重复使用。

The hydroconversion of n dodecane on the Pt M/SAPO 11 catalyst was investigated in a microreactor.

以正十二烷为模型化合物，在高压微型反应装置上进行了长链烷烃在Pt M/SAPO 11催化剂上的加氢异构化反应规律研究。

For the stepwise mechanism, the ethylene molecule was firstly adsorbed at the Brnsted acid site via π-hydrogen bonding to form a stable complex, which then went through the protonation, leading to the formation of the ethoxide intermediate. Furthermore, the ethoxide reacted with the second ethylene molecule to form the butoxide product.

对于分步反应机理，乙烯分子首先通过π-氢键作用在酸性位形成稳定的吸附络合物，再进一步发生质子化并生成乙醇盐中间体，随后乙醇盐与第二个乙烯分子发生碳－碳键结合形成丁醇盐产物。

The effects of different ratio of aged refuse to alkali additive on fermentative hydrogen production from kitchen waste were investigated.

研究了不同配比的矿化垃圾与碱性添加剂对餐厨垃圾发酵产氢的影响。

The effects of different ratio of aged refuse to alkali additive on fermentative hydrogen production from kitchen waste were investigated.

摘 要：研究了不同配比矿化垃圾与碱性添加剂对餐厨垃圾发酵产氢的影响。

Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a&和4a&也可利用类似的质子化反应合成，唯有错合物3a'= CpRu(PPh32， Ar2 = fluorenyl 可以稳定於溶液中，不会进行上述反应，如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2，3-b：3'，2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子：1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换；2用LDA对二噻吩并[2，3-b：3'，2'-d]噻吩去质子化作用。

Three new fulvene polymeric compounds, namely 1[Ag (L3]CH2C12 , 2[Ag2(L25(H2O)(S03CF3)2]0.5C6H6 and 3 Mn(L42(C2H5OH)2 , were synthesized, respectively. Compounds 1 and 2 reported herein represent the organometallic polymers based on both Ag-N and Ag-C coordination interactions. In the solid state, compound 3 are bound together by strong intermolecular N H-O hydrogen bonding system into a supramolecular one-dimensional H-bonded chain.B.

一、富烯有机配体的合成及与金属离子的反应化学利用富烯负离子的芳酰化反应和Heck-偶联反应合成了富烯配体L1-L18，并合成了三个基于富烯配体的金属有机配位聚合物1[Ag(L3]·CH_2Cl_2、2[Ag_2(L25(H_2O)(SO_3CF_3)_2]·0.5C_6H_6和氢键驱动的超分子聚集体3Mn(L4_2(C_2H_5OH)_2。

Effects of the reaction temperature, pressure, gas flow rate of H2, liquid flow rate of furoic acid and methol were studied.

研究了反应的温度、压力、气、液体流速等工艺条件对糠酸杂环选择性催化加氢甲酯化过程的影响。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。