氢化

Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a"和4a"也可利用类似的质子化反应合成，唯有错合物3a'= CpRu(PPh32， Ar2 = fluorenyl 可以稳定於溶液中，不会进行上述反应，如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

Hydrogen bonding in hard segment domains of segmented polyester polyurethaneurea based on 4,4'-diphenylmethane diisocyanate, ethylene diamine and polybutylene adipate(M. W. 1975 and M. W. 1228) was studied by means of IR spectroscopy.

用红外光谱法对基於4，4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯（分子量分别为1975和1228）的两系列嵌段聚酯型聚脲氨酯硬段微区中的氢键化进行了研究。

This article mainly reviewed the discovery and the research course of natural phosphine ,namely,how phosphine coming into being,and whether phosphine being universal existed gas in natural environment such as in aerosphere,biosphere,hydrosphere.

磷化氢是剧毒的、十分活泼的无色气体，具有强的还原性，在光照、空气等作用下，极易转化为磷的其它形态。

An organic compound in which the hydrogen of the hydroxyl group of methyl alcohol is replaced by a metal.

甲基化产物一种有机合成物，是甲醇的羟基中的氢被一种金属取代

In the one hand, for catalytic double carbonylation of phenyl iodide or catalytic hydroesterification of styrene, the effect of pressure on products ratio reflected the difference in the volume of activation of different reaction routes.

对于碘苯双羰基化反应或苯乙烯氢酯基化反应，由于不同产物反应的活化体积不同，压力对于不同反应速率常数的影响亦不相同，因此压力增大会有利于其中某个反应。

The aniline HDN was strongly stressed by the presence of quinoline and DHQ and the HDN of quinoline proceeds exclusively via a pathway which involves fully saturated intermediates on the MCM-41-supported nickel phosphides. The HDN activity of nickel phosphide catalyst was dramatically reduced by the presence of H2S and DBT, probably due to the strong adsorption of H_2S and DBT on active sites which inhibited the adsorption of quinoline.

喹啉和DHQ对苯胺的HDN反应有强烈的抑制作用，喹啉在磷化镍催化剂上几乎全部通过完全加氢饱和路径进行反应。H_2S和二苯并噻吩强烈地吸附在磷化镍催化剂活性中心上，阻碍了反应物分子的吸附，从而对喹啉的HDN反应有强烈的抑制作用。

The thickness and composition of the nitrided layer can be controlled by changing ion-nitriding parameters.

此外，改变温度及氮氢比等氮化参数可有效控制氮化层之成分与厚度。

UV-curable hyperbranched poly was synthesized via organosilicon polymer bearing silicon hydride end groups and vinyltriallylsilane at the presence of Pt/C catalyst.

通过含硅氢键的超支化聚合物和乙烯基三烯丙基硅烷在铂催化剂作用下反应制备了可紫外光固化的超支化聚硅氧基硅烷。

And therefore it has the potential applications in green chemistry and chemical process,organic reactions areas.The literature review section of the thesis gave a brief introduction of the important applications in the green chemical process as well as the status of organic reactions research in NCW,and also summarized the applications in different kind of reactions such as hydrolysis,dehydration/hydration,alkylation,acylation, Diels-Alder reactions,rearrangements,condensations,hydrogen isotope exchange reaction,oxidation-reduction reaction,organometallic reactions.

论文的综述部分简要介绍了近临界水在绿色化工过程中的重要应用价值和国内外在近临界水中进行有机化学反应的研究现状，以及以近临界水作为反应溶剂或催化剂在水解反应、脱水/水合反应、烷基化、酰基化、Diels-Alder反应、重排反应、缩合、氢同位素交换反应、氧化还原反应、有机金属反应等反应类型中的应用。

When combined by heavy chromate-sodium hydrogen sulfite and by silane couplant, rapidly quenched NdFeB permanent magnetic particles, can form passive pycho-film (containing Cr〓O〓) and silane composite coating, which can improve greatly its oxidation resistance of NdFeB particles and increase the magnetic properties of bonded NdFeB Permanent Magnetic Composite .

采用重铬酸盐钝化-亚硫酸氢钠还原与硅烷偶联剂处理相结合来包覆处理快淬NdFeB永磁粉，能在快淬NdFeB表面形成致密的含Cr〓O〓钝化膜/硅烷复合涂层，它们显著地改善了快淬NdFeB的抗氧化性并提高了粘结NdFeB永磁复合材料的磁性能，并与其它的NdFeB包覆处理工艺所获得的涂层进行了比较。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。