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氢化

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They are, 4 21-amidohydrocortisone Ba1~Ba4, 10 21-amidoprednisolone Bb1~Bb10, 4 21-amidomethylprednisolone Bc1~Bc4, 4 21-amidodexamethasone Bd1~Bd4, 1 21-amidobetamethasone Be1, 1 21-amidoRS Bf1, 1 21-amidocortisone Bg1, 1 21-amidoprednisone Bh1. The amido groups were acetamido, nicotinamido, hemesuccinamido, benzoylamido, methanesufonamido, or arylsufonylamido.

包括:4个21-酰胺基氢化可的松(Ba1~Ba4),10个21-酰胺基氢化泼尼松(Bb1~Bb10),4个21-酰胺基甲泼尼龙(Bc1~Bc4),4个21-酰胺基地塞米松(Bd1~Bd4),1个21-酰胺基倍它美松(Be1),1个21-酰胺基RS(Bf1),1个21-酰胺基可的松(Bg1),1个21-酰胺基强的松(Bh1)。21-酰胺基分别为乙酰胺基、烟酰胺基、单琥珀酰胺基、苯甲酰胺基、甲烷磺酰胺基或取代苯磺酰胺基等。

And in Jiangsu can early absorbed domestic and international technology before two years, have development, research to technology of chloric hydrogen sulfide, through countless experiment, mastered skill of chloric hydrogen sulfide eventually, passed the sanction of bureau of national technology property right.

而江苏中能则早在两年前就吸收了国内外的技术,对氯氢化技术进行开发、探究,通过无数次的试验,终于把握了氯氢化技术,并通过了国家技术产权局的批准。

An alicyclolic epoxy resin with endocyclic structure,namely hydrogenated terpinene-maleic ester type epoxy resin, was synthesized from the raw material hydrogenated terpinene-maleic anhydride.

氢化萜烯马来酸酐为原料与环氧氯丙烷反应合成一种含桥环结构的饱和脂环基环氧树脂——氢化萜烯酯型环氧树脂。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下,利用2,4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应,合成了中间体4-丙氧基-2-羟基二苯甲酮,将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1,2-氧硼杂环戊烷与〓反应,再经PCC氧化,分子内缩合得到二氢茉莉酮。1,2-氧硼杂环戊烷的C-B键除氧化断裂之外,也能够在〓或KF作用下卤化断裂成碳卤键。

The synthesis of chiral pharmaceuticals is a hot issue of the development in pharmaceutical in the world,asymmetric hydrogenization of which is the successful technology in the chiral synthesis .

手性药物的合成是目前全球药物开发研究的热点,而不对称氢化是手性合成中最成熟的技术。讨论了不对称氢化技术在镇痛类、抗生素类、抗菌类、抗忧郁类以及维生素类等9类手性药物合成中的实际应用

In the second section, with ketone and hydroxylamine hydrochloride as the starting materials, 3-aminopropanol is prepared via three steps including reaction of ketone and hydroxylamine hydrochloride , condensation of ketoxime and acrylonitrile, and hydrogenation cracking of condensation product.

第二是3-氨基丙醇的制备,由酮肟丙烯睛缩合物催化氢化裂解制得:即先以酮、盐酸羟胺为起始原料在碱性条件下合成酮肟,再与丙烯腈反应生成酮肟丙烯腈缩合物后经催化氢化裂解制得3-氨基丙醇。

In the presence of Pt catalyst, polyhydrodimethylsiloxane reacted with allyl polyoxyethylenepolyoxypropylene ether (F-6) by hydrosilylation to form an intermediate polyether silicone, which further undergo phosphation reaction with phosphorous pentoxide, a kind of phosphate modified polyethersiloxane surfactant was prepared.

采用铂作催化剂,通过含氢硅油和端烯基聚醚(F-6)的硅氢化加成反应先制得聚醚硅油中间体,再将其和五氧化二磷进行酯化反应,制得了一种磷酸酯型有机硅表面活性剂。

The main objective of this research project is to modify the Methyl-Acetylene/propadiene selective hydrogenation reaction system of the No.3 Naphtha Cracker in CPC. The original gas phase reaction system was redesigned to a liquid phase reaction so that higher propylene selectivity was achieved and lower rates of propane and green oil were produced. To recover effectively the higher production of valuable propylene from the reaction system, the following fractionator was also redesigned.

本研究之目的在於修改中油公司三轻工场老旧的甲基乙炔/丙二烯选择性氢化气相反应系统,使成为液相反应系统,藉由液相反应的优异性,提高由MAPD氢化得到丙烯之选择率,同时降低丙烷及绿油产率,以增加丙烯产率,另亦修改丙烯精馏系统,以提升蒸馏塔提纯之效率。

Some useful fluorine-containing intermedi-ates were synthesized by the reaction of activated methylenecompounds or silyl enol ether with 2,2-dihydropolyfluoro-alkanoates or 2-hydropolyfluoroalk-2-enoates in the presenceof different bases.

进一步研究表明,在氢化钠的作用下,苯乙腈,苄基苯基甲酮也可以与2-氢多氟-2-烯酸乙酯发生亲核加成反应,苄基苯基甲酮的加成中间体经多聚磷酸环化,得到了间位氟烷基取代的α-萘酚衍生物。

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