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Besides,through Arbuzov reaction,Vilsmer-Haack Hydroformylation,Wittig-Horner reaction,nitryl hydrogenation deoxidize,and imidization five steps synthesized another compound which included hole-transporting,electron-transporting and luminescence materials.

此外,又通过Arbuzov反应、Vilsmer-Haack甲酰化反应、Wittig-Horner反应生成二苯乙烯、硝基加氢还原、酰亚胺化5步反应合成了一种集空穴传输-电子传输-发射三位一体的新型苝酰亚胺化合物。

The structures of 6 main products of ozonization of nopol were identified by GC-MS, and they are all four-ring compounds , the result suggests that the double bond, tertiary hydrogen can be oxidized, and there was other further oxidation.

通过GC-MS分析确定了6个诺卜醇臭氧化主要产物的结构,它们均为四元环类化合物,这表明诺卜醇臭氧化时碳碳双键、叔氢都会被氧化,还伴有其它更深层次的反应。

The conclusion was drawn by the synthesis of molecular sieve: after mixed soluble glass and aluminium sulfate with proper proportion under room temperature, it was stirred stormily to react. And then we mixed with potassium hydroxide solution after filtrating. At last, the molecular sieves of potassium type was synthesized after the mixture reacted in the oven or autoclave for 24 hours. The molecular sieve was remodeled more than twice with ammonium chloride solution that the concentration was 3mol/L and then remodeled twice with the saturated sodium chloride solution. Finally the molecular sieve was changed into the sodium type. It was named W zeolite.

通过对分子筛的合成得到:以泡花碱、硫酸铝为原料,以硅铝比按一定比例于室温下将二者混合,激烈搅拌,抽滤后与氢氧化钾溶液混合放于烘箱或高压釜中高温晶化24小时,晶化后的分子筛为钾型,先后用3mol/L氯化铵溶液和饱和食盐水各对其改型两次以上,最后改为钠型,可制得W型沸石分子筛。

Nitro-4-methylsulfonylbenzoic acid was prepared from 4-toluene sulfonyl chloride by the reaction of Alkylation (in the condition of sodium sulfite and baking soda), Nitrification (in the condition of nitric acid and vitriol) and Oxidation reaction (in the condition of nitric acid and catalyzer).

研究了以对甲苯磺酰氯为起始原料,首先通过亚硫酸钠和碳酸氢钠的水溶液进行烷基化、其次在浓硝酸和浓硫酸加热回流的条件下峭化、最后在浓硝酸和催化剂的条件下进行氧化,3步反应合成了玉米田高效除草剂甲基磺草酮的重要中间体2-硝基-4-甲磺酰基苯甲酸。

After the basis set superposition error correction and the zero point vibration energy correction, the interaction energies for three types of NMA-acetic acid complexes and one type of NMA-water complex were -44.3,-35.5,-32.4 and -16.0 kJ·mol-1 respectively, which showed that NMA had a great affinity for acetic acid than water.

NMA与水\醋酸之间都有氢键形成,经计算得到NMA-醋酸复合物的稳定化能在-32.4~-44.3kJ/mol之间,且平面构型的NMA-醋酸复合物稳定能较高,而NMA与单分子水的稳定化能仅为-16.0kJ/mol。

AVI may be protein matrix and it possesses neither a membrane boundary nor an internal structure,its formation is the result of the anthocyanins transported into the vacuole bind with a protein matrix. In vacuole, AVI is irregular and jelly-like in shape. In AVIs, the attachment of anthocyanins to the matrix protein is likely to be via H-bonds to a sterically restricted site. AVI is suggested to act as vacuolar anthocyanin "trap", preferentially for anthocyanidin 3, 5-diglycosides or acylted anthocyanins. The emergence of AVI can enhance color intensity and results in the "blueness" of color in the vacuole.

花色苷液泡包涵体可能具备蛋白质基质,既无膜包裹又无内部结构,其形成是转运进液泡的花色苷与蛋白质基质结合的结果;液泡里的花色苷液泡包涵体形状不规则,象果冻;在花色苷液泡包涵体中,花色苷可能通过氢键连接于蛋白质基质的一个有限空间位点;花色苷液泡包涵体被认为是液泡中花色苷的&陷阱&,优先摄取花色素3,5-二糖苷或酰化的花色苷;花色苷液泡包涵体的存在可增加液泡色彩的强度并导致&蓝化&。

The desulfurization networks of alkylthiophenes and benzothiophene on OTA catalyst were involving both and direct hydrodesulfurization, but also, containing disproportionation, isomerization.

烷基噻吩和苯并噻吩硫化物在OTA催化剂上脱硫反应网络一方面含有直接加氢脱硫反应,另一方面经历歧化、异构化和裂解等反应。

To find methylated genes, researchers usually turn to a technique called bisulphite sequencing, which chemically changes normal cytosine to thymidine (T; another DNA base), while leaving methylated cytosines unchanged.

研究者通常借助于亚硫酸氢盐测序技术检测甲基化的基因,它通过化学反应使正常胞嘧啶转变为胸腺嘧啶,而对甲基化的胞嘧啶无作用。

After this research work, we know that: HMCM-22 is a better catalyst of selecting naphthalene alkylation; Surface modification of zeolite Y is effective, but the effect of zeolite 3 is not evident and surface modification doesn"t suits mordenite; Surface modification doesn"t affect the frameworks and inner environments of zeolites, but only reduces diameter of orifice and overlays surface acidities; t-butanol is not suitable for alkylating agent of the reaction using modified zeolites as catalyst; Solvents with smaller molecular size are advantageous for naphthalene alkylation reaction using modified zeolites as catalyst, such as cyclohexane is better than decalin.

通过本论文的研究,我们知道:HMCM-22是萘择形烷基化反应较好的沸石之一;Y沸石的外表面改性效果较好,β沸石则效果不明显,而丝光沸石则不适于外表面改性;外表面改性不改变沸石的骨架结构和孔道内部环境,仅减小孔口直径和覆盖外表面酸性位;叔丁醇不适于作外表面改性沸石催化的反应的烷基化试剂,其反应活性很低,且选择性无明显提升;分子较小的溶剂更适于外表面改性沸石催化的反应,环己烷就明显好于十氢萘。

In the third part of this paper, a facile method is presented for synthesis of malonaldehyde dianil from propargyl alcohol by oxidizing using chromium trioxide and addition reaction with aniline.

对肼基苯磺酸是由对氨基苯磺酸经亚硝酸钠重氮化得到的重氮盐用亚硫酸氢钠还原、水解、硫酸酸化制得,本文经多次实验确定了反应原料、用量及反应条件,得到的产品纯度好,产率高。

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