氢化

To avoid the influence of ammonolysis, alcoholysis and hydrolysis on molecular structure identification, in this paper, derivational estimation is utilized to confirm molecular structures ofβ-naphthol-containing sulfonyl chloride intermediates. Then the structures of corresponding sulfonamide dyes are also confirmed by FTIR,~1H NMR and mass spectrometry.

为了避免磺酰氯化合物发生水解、醇解和胺解等衍生化反应影响磺酰氯化合物分子结构表征，本文采用衍生化反推法证明了β-萘酚结构磺酰氯化合物的分子结构，并利用红外光谱、核磁共振氢谱、质谱表征了含β-萘酚结构磺酰胺染料的分子结构。

The results indicated that hydrogen bond and covalence bond were formed between PVA and TEOS through the sol-gel reaction.

结果表明PVA与无机相发生溶胶-凝胶反应生成氢键和共价键Si-O-Si，形成交联有机聚合物／无机杂化体系，使杂化膜的结晶度减少，控制了膜的溶胀，提高膜的溶解选择性能，但膜的溶胀减少会使通量有所下降。

All compounds are synthesized starting from the acylation reaction of gallic acid with L-glutamine to form the basic scaffold, followed by the cyclic reaction in acetic anhydride and the key intermediate cyclic anhydride (compound 4) was obtained. The intermediate compound is condensed with different amino acids or primary amines, and produces the target compounds.

本研究以L－谷氨酸为基本骨架，与甲醚化保护的没食子酸缩合后，经过酰化、环合反应得到关键中间体环状酸酐（化合物4），再经胺解反应合成目标化合物，其化学结构经过红外光谱、电喷雾质谱和核磁共振谱（氢谱、碳谱、碳氢异核多键相关谱）确证。

A series of diazonium salts of 4-(N-methyl-N-phenylamino)-3-amino-1,8-naphthalic anhydride 5a, its naphthalimide derivative 5b, and 5e were designed and synthesized,and it was the first time to discover that aromatic radical-induced intramolecular aromatic 1, 5-hydrogen transfer was also involved in the nitrogen-contianed system during Pschorr cyclization.

实验设计合成了4--3-氨基-1，8-萘酐的重氮盐5a、其衍生物N-丁基-4--3-氨基-1，8-萘酰亚胺的重氮盐5b和N--4--3-氨基-1，8-萘酰亚胺的重氮盐5c，并首次发现了通过普朔尔环化反应以氮甲基化的氮为桥原子的体系存在着芳香自由基诱导的芳香1，5-氢转移。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题，系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性，通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析，全文主要内容如下： 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明：红磷在空气中发生缓慢氧化、歧化反应，微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度，其中铜离子的作用最为明显，而铝、锌等离子减慢了红磷的氧化速度，银离子对减少红磷的吸湿性效果最好。

It was revealed that content of water among nitriding agent, space velocity, final nitriding temperature, temperature rate, the ratio of N2 and H2 all have impacts on the formulation of high surface area γ-Mo2N and the significance reduces in turn.

研究发现氮化剂中水含量、空速、氮化终温、升温速率、氢氮体积比对高比表面积γ-Mo2N/SiO2的形成均有影响，且影响显著性依次降低。

Hydrogen halide, which is a co-product of these downstream processes, can be recycled to the oxidative halogenation process.

这些下游工艺的共产物卤化氢，可循环回到所述氧化卤化反应方法之中。

It was found that the effect of hydrogen bonds played an important role in increasing the stabilities of 2,6-dithiopurine hydrated tautomers and lowering the activation energies of proton transfer.

计算结果还表明，氢键作用在增大2，6-二巯基嘌呤氢键一水合物稳定性、降低质子转移异构化反应活化能等方面起着重要的作用。

The mainly conclusions in our research are as flowing: tungsten trioxide powders with 100 nm primary particle are obtained by spray drying,calcination and wet milling process, and an average size of quadric particle composed of agglomerated particles is 0.64 μm; tungtsen powders with 39 nm grain size and 60 -100 nm primary particle are produced directly from previous tungsten trioxide using one step reduction in hydrogen at 700℃, and an average size of quadric particle of tungsten powder is 2.91 μm; tungsten trioxide and copper tungstate compound powders with 100 nm - 200 nm primary particle are produced using ammonia metatungsten and copper nitrate as raw materials by spray drying,calcination and wet milling process;the compound powders are transformed completely into tungsten and copper compound powders by reduction in hydrogen at 700℃,in which tungsten grain size is 59 nm and copper grain size is 51 nm; primary particle size of compound powders is 80 - 120 nm,and an average size of agglomerated quadric particle is 1.86 μm; tungsten nitride powders with 35 nm grain size are prepared from tungsten trioxide powders by nitrogen treatment thoroughly in pure ammonia at 650℃, and an average size of agglomerated quadric particle is 0.64 μm in normal temperature.

研究结果表明：采用喷雾干燥—焙烧—球磨工艺可以制备出粒度约为100nm的WO_3粉体，它们在团聚后形成的二次颗粒平均粒度为0.64μm；采用一步直接氢还原方法可在700℃下从上述WO_3粉体制备出晶粒尺寸为39nm的、一次颗粒粒度为60-100nm的W粉体，其二次颗粒的平均粒度为2.91μm；以偏钨酸铵、硝酸铜为原料，采用喷雾干燥—焙烧—球磨工艺可制备出一次粒度为100-200nm的WO_3和CuWO_4混合粉体；采用氢还原工艺可在700℃下将这种粉体完全转变为W、Cu复合粉体，其中W的平均晶粒粒尺寸为59nm，Cu的平均晶粒尺寸为51nm；复合粉体的一次颗粒尺寸为80-120nm，在常温下团聚后形成的二次平均粒度为1.86μm；采用纯氨氮化工艺可以在650℃下由WO_3粉体制得WN，其晶粒尺度为35nm，在常温下团聚后的二次平均粒度为6.4μm。

Beta molecule sieves has good catalytic activity in hdrocracking and hydrogenated isomerization, and good adsorption capacity to straight chain paraffin, and also capacity to avoid sulfur, nitrogen poisoning.

beta；分子筛具有很高的加氢裂化、加氢异构化催化活性和对直链烷烃的吸附能力，并有良好的抗硫、氮中毒能力。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。