氢

In this paper,firstly a series of acryloxyl derivatives were synthesized from the dehydrogenated abietic acid,a main composition of disproportionated rosin, through acyl chloridation and esterification.The derivatives included the (β-acryloxyl ethyl) esters of dehydrogenated abietie acid,(β-methacryloxyl ethyl) esters of dehydrogenated abietic acid and (β-methacryloxyl propyl)esters of dehydrogenated abietic acid.

论文首先以歧化松香中的主要成分脱氢枞酸为模型化合物，采用酰氯化、酯化手段合成了它的一系列丙烯酰氧基衍生物，包括脱氢枞酸酯、脱氢枞酸(β-甲基丙烯酰氧基乙基)酯和脱氢枞酸(β-甲基丙烯酰氧基丙基)酯。

Sulfur corrodible sites and their characteristics were introduced of the prefractionation system, air preheaters of heating furnace and product air coolers etc,and chlorine corrodible sites and their characteristics were also presented of the thermocouple casing tubes, product air coolers and fire arrestors of heating furnace etc in the catalytic reforming and diesel hydrogenated unit s.

介绍了中国石油哈尔滨石化公司催化重整及柴油加氢装置在预分馏系统、加热炉空气预热器、加氢装置反应产物空冷器等处易发生硫腐蚀和在预加氢热偶套管、加氢反应产物空冷器、加热炉阻火器等处易发生氯腐蚀的部位及其表现特征，指出装置在低温(不高于120℃)、含水、容易被堵塞的部位易形成HCl-H2S-H2O腐蚀体系，分析了腐蚀原因和介质来源，总结和提出了开好原油的电脱盐、采用脱氯技术、加强对加热炉的排烟温度控制和腐蚀介质的精制与净化、加大空冷器的注水量等针对性防腐经验和措施。

The p-Isopropylbenzoic acid was synthesized by catalytic transfer dehydrogenation with 5% Pd/C using dihydrocumic acid as material and hydrogen offer, industrial dipentene as hydrogen acceptor and solvent, reacted directly under reflux condition.

采用5% Pd/C作为转移氢催化剂，原料二氢枯茗酸为氢给予剂，以工业双戊烯作为氢接受剂和溶剂，合成了对异丙基苯甲酸。

Subcordiformis in Huanghai Sea near Dalian, it can be able to evolve H〓 photosynthetically. Comparing with Chlamydomonas reinhardtii in our lab, the H〓 productivity is same. By the elementary macro regulation of H〓 production with 2, 5-dibromo-3-methyl-6-isopropyl-p-benzoquinone , N, N'-dicyclohexylcarbodiimide , 3-(3, 4-dichlorophenyl)-1, 1-dimethylurea , sodium dithionate, sulfur-deprivation and cell immobilization, the results show that DCCD, immobilization and sulfur-deprivation has a positive effects on the H〓 production.

利用DCCD（质子泵抑制剂N，N'-dicyclohexylcarbodiimide）、DBMIB（光合电子传递抑制剂2，5-dibromo-3-methyl-6-isopropyl-p-benzoquinone）、DCMU[PSⅡ光合放氧抑制剂3-（3，4-dichlorophenyl）-1，1-dimethylurea]、连二亚硫酸钠、无硫调控及固定化扁藻等手段，对该扁藻产氢进行初步的宏观调控，发现DCCD的加入、扁藻的固定化和无硫调控对产氢均有正效应，其中无硫调控使扁藻产氢时间延长，总产氢量提高了近10倍。

Occurrence of RE hydride was identified in the Al-Si alloy containing RE andenrichment of hydrogen in polynary RE intermetallic compound was determined by means ofEPMA, secondary ion mass spectrography, Hg-free vacuum drivepipe hydrogen-meter to-gether with metallography and porosity measurement.

采用电子探针、二次离子质谱、无汞真空套管测氢仪等检测手段，并配合金相分析及试样孔隙度的测定，鉴定出含稀土的Al-Si合金中有稀土氢化物的存在，确认在多元稀土金属间化合物中氢的富集，提出稀土具有较强固氢作用的观点。

In this work , 1,8-octodiol, the starting material, reacted with 40% hydrobromic acid to produce 8-bromooctan-1-ol, with the catalytic action of PPTs, its hydroxyl group was protected by 2,3-dihydropyran. Then it coupled with 1-heptaalkyne, by means of P-2 nickel as catalyst, stereoselectivity catalysis hydrogenated, with the catalytic action of acid to take off extremital 2, 3-dihydropyran which protected hydroxy group, then used PCC to oxidize alcohol into corresponding aldehyde.

以1，8-辛二醇为原料，与40%氢溴酸进行单溴代反应，得到8-溴-1-辛醇，在对甲苯磺酸吡啶盐的催化下与2，3-二氢吡喃反应，保护分子中的羟基，再与1-庚炔进行偶联，以P-2镍为催化剂立体选择性催化加氢，酸性条件下脱末端的2，3-二氢吡喃对羟基的保护，使用氯铬酸吡啶盐将醇氧化成醛。

The hydrogenation and methyl esterification of furoic acid over Pd-Ni/γ-Al2O3 catalysts was investigated in fixed bed micro-reactor under different conditions such as reaction temperature,pressure,H2 space velocity,space velocity of furoic acid and methol,ratio of H2 and furoic acid and so on.

以糠酸、甲醇、氢气为原料，采用连续流动固定床微反应器，Pd-Ni/γ-Al2O3为催化剂，使糠酸一步加氢甲酯化生成α-四氢糠酸甲酯。研究了反应的温度，压力，气、液体流速，进料流量等因素对催化反应的影响。结果表明：在1.5MPa，250℃，氢气空速3300 h-1，液体空速3.0 h-1(氢油比为50)时，糠酸转化率为96.6%，四氢糠酸甲酯的选择性97.2.0%，产率94.0%。催化剂稳定性较好，连续运转280小时后未见活性下降。该反应体系活性高，选择性好，反应压力低，催化剂性能稳定，操作简单，产物易分离

Project Introduction: Trichlorosilane, also named Silicochloroform ,is mainly used in the synthesis of organic silicone, alkyl, aryl and organic functional group chlorosilane. It's the most basic monomer of the organic silane coupling agent,and the production material for semiconductor silicon and silicon; Manufacturing process of the tetrachlorosilane includes the reciprocal effect by the trichlorosilane steam and the hydric steam which has been heated up to 1700-2500SiCK by the plasma accelerator; the steam compound in the reactor goes into the condensing system that separates trichlorosilane. After that, polycrystalline silicon can be made.

三、项目概况：三氯氢硅：又名三氯硅烷、硅氯仿，主要用于有机硅烷和烷基、芳基以及有机官能团氯硅烷的合成，是有机硅烷偶联剂中最基本的单体，也是生产半导体硅、单晶硅的原料；四氯氢硅工艺包括在等离子加速器内加热到1700-2500SiCK的氢气流和四氯氢硅的蒸汽相互作用，在反应器内形成的蒸汽气体混合物进入分离三氯氢硅的冷凝系统，下步可制取多晶硅。

Experiment results show, in the HD process, the temperature of dehydrogenation process sets at about 580℃, can make the hydrid of Nd complete turning into NdH_2 which can resist being eroded and oxidation, so it increases the resistance to oxidation of the magnet powders.

研究结果表面，在氢爆HD工艺中，采用580℃左右的温度进行工艺中的脱氢过程，可以使富Nd相氢化物充分脱氢成稳定不易腐蚀氧化的NdH_2，增强了磁粉后续工艺中的抗氧化能力。

Research results of phase equilibrium for the KOH—K〓CrO〓—H〓O system, the KOH—KAlO〓—H〓O system and the KOH—K〓CrO〓—KAlO〓—H〓O system revealed that lower concentration of KOH was beneficial for the crystallization of KAlO〓, and within a certain range, higher concentration of KOH was favorable for the crystallization of K〓CrO〓.

KOH—K〓CrO〓—H〓O体系，KOH—KAlO〓—H〓O体系和KOH—K〓CrO〓—KAlO〓—H〓O体系相平衡研究结果表明，较低的氢氧化钾浓度有利于铝酸钾结晶析出，一定范围内，较高的氢氧化钾浓度有利于铬酸钾结晶析出，因此，通过控制氢氧化钾浓度可以使铬酸钾—铝酸钾—氢氧化钾得以分离。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。