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A Pd /D005 resin catalyst was prepared by using ion exchange method.Selective hydrogenation for pentadiene in FCC C5 fractions and hydroetherification of tertiary pentanes with methanol were investigated.

摘 要：采用离子交换法制备了Pd/D005树脂催化剂，对催化裂化C5馏分中戊二烯的选择性加氢和叔戊烯与甲醇的临氢醚化反应进行了研究。

The mechanism of the dehydrogenation reaction of OsO〓 with methane For the reaction, OsO〓+CH〓→OOs〓+H〓, the minimum energy reaction path involves two PESs of quartet and doublet states.

因此整个反应的速率决定步骤是分子氢从二重态的亚甲基二氢化物中还原消去，能垒大约为30.4kcal/mol.c。

Hexahydropyridazine, an important pesticidal and pharmaceutical intermediate, was synthesized via catalytic cyclization and alcoholysis using diformylhydrazine and 1 ,2-dichlorobutane as starting reagents, with a total yield of 77% and purity of 97.7%.

六氢哒嗪是一种重要的农药和医药中间体，以二甲酰肼和1，2-二氯丁烷为主要原料，经催化环合和醇解2步反应合成六氢哒嗪，总收率77%，产品纯度97.7%。

The C_(60)-fused tetrahydrofuran derivatives are excellent synthons for further functionalization.While treated with different equiv,of BF_3·OEt_2 at various temperature,several novel functionized fullerene derivatives have been successfully synthesized.2.1,4-Fullerenols C_(60)ArOH were synthesized via the reaction of[60]fullerene with 4-substituted phenylhydrazine hydrochlorides and sodium nitrite under moisture and aerobic conditions.

这种四氢呋喃环合富勒烯衍生物作为一个合成中间体又可发生进一步的衍生化反应，其与不同当量BF_3·OEt_2在不同温度条件下可以得到二氢呋喃环合富勒烯衍生物、三元环合富勒烯衍生物等。2。

Synthesis experiments of butyl acetate were done with ammonium ferric hydrogen phos- phate as catalyzer.

以硫酸亚铁和磷酸二氢铵为原料，以聚乙二醇-400（PEG-400）为表面活性剂，经低热固相反应合成得到磷酸氢铁铵，经XRD分析表征证实了产物的分子式为（NH4）Fe（HPO4）2。

In the presence of Pt catalyst, polyhydrodimethylsiloxane reacted with allyl polyoxyethylenepolyoxypropylene ether (F-6) by hydrosilylation to form an intermediate polyether silicone, which further undergo phosphation reaction with phosphorous pentoxide, a kind of phosphate modified polyethersiloxane surfactant was prepared.

采用铂作催化剂，通过含氢硅油和端烯基聚醚（F-6）的硅氢化加成反应先制得聚醚硅油中间体，再将其和五氧化二磷进行酯化反应，制得了一种磷酸酯型有机硅表面活性剂。

The dark green bis-anion obtained from treatment of 10-hydroxy-5, 10-dihydrophenophosphazine 10-oxide with NaH reacted with MeI at about 120℃ in anhydrous DMF to give N-methyl phosphinic acid.

在无水DMF中，用NaH处理5，10-二氢磷杂吖嗪环系次膦酸，得到黯绿色双负离子钠盐，该钠盐与MeI在约120℃下反应，得到N-甲基-5，10-二氢磷杂吖嗪环系次膦酸。

Effects of the mass ratio of organic phosphonic acid to zinc biphosphate, compound system amount, corrosion time and temperature, and pH value on the anticorrosive efficiency were investigated.

以四乙烯五胺、甲醛和亚磷酸为原料合成了有机膦酸类缓蚀剂，与磷酸二氢锌复配，考察了有机膦酸类缓蚀剂与磷酸二氢锌质量比、复配体系加量、腐蚀时间、腐蚀温度及体系pH值对复配体系缓蚀效果的影响。

Tetrahydroisowuinolin derivatives and phthalide derivatives were designed and synthesized on the basis of a PDE4 inhibitor pharmacophore model set up through computer simulation. Some tetrahydroisowuinolin derivatives synthesized were evaluated on their activity against PDE4 for study on the structure-activity relationship.(7-cyclopentyloxy)-6-methoxy-3,4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155) and Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (170) showed good activity against PDE4, which were chosen as the lead compounds to design and synthesize another analogs in order to develop selective PDE4 inhibitors with better activity.

分别设计合成了以四氢异喹啉和氨基苯酞为骨架的两类小分子杂环化合物，并对部分四氢异喹啉衍生物测试了其相关的生物活性，初步确定了其构效关系，发现了两个对PDE4有较好抑制活性的先导化合物(7-cyclopentyloxy)-6-methoxy-3，4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155)和Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1，2，3，4-tetrahydroisoquinoline-3-carboxylate (170)。

Polymer substrates with dormant groups on the surface were prepared through the recombination of ITX pinacol radicals and surface radicals generated by the abstract hydrogen reaction.The influence of light intensity,irradiation time,concentration of ITX solution and polymer substrates to the dormant group density was investigated respectively.

论文取得的主要结果如下：1、利用夺氢型光引发剂异丙基硫杂蒽酮的夺氢-偶合光化学反应，将ITX嚬哪醇自由基固定到基材表面，制得了表面偶合有休眠基的聚合物基材。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。