氢

Along with the wide application of hydrogenation technology in the oil refining industry, the processes of heating, boiling and condensation of the petroleum products are in the conditions of having a lot of noncondensable gas in the hydrogenation heat exchanger and furnaces.

随着加氢工艺在炼油工业中的广泛应用，加氢换热器和加热炉中石油的加热、沸腾和冷凝过程都是在有大量不凝气体存在的情况下进行，但目前关于含不凝气体的石油产品的换热研究进行得很少。

The results calculated by the Elovich rate equation showed that K release rates from 1 mol.L-1 HNO3 extraction ＞those from 2 mol.L-1 HNO3 extraction ＞those from H-resin extraction. Elovich equations combining with the data of H-resin and 2 mol.L-1 HNO3 successive extraction could well described the release characteristics of soil K. The correlation coefficients of the equations reached most significant levels (r＝0.956**—0.999**), and standard errors of specific K release capacities between the vaules calculated by the equations and those measured by both successive extractions were smaller(s=1.61 and 3.52). The specific release rates of soil K calculated by the Elovich rate equations were significantly correlated with the indices of soil K availability (the amounts of easily available K, nonexchangeable K, total available K in soils and K absorbed by ryegrass).

研究结果表明：1 mol.L-1 HNO3提取法的释K速率＞2 mol.L-1 HNO3提取法的释K速率＞氢饱和交换树脂提取法的释K速率；氢质交换树脂和2 mol.L-1 HNO3提取法结合Elovich模型较理想地描述了土壤K素的释放特性，拟合方程的相关系数均达极显著水平(r＝0.956**-0.999**)，土壤特征累积释K量的计算值与实测值的标准差较小(s=1.61和3.52)，且通过速率方程计算的土壤特征释K速率与K素有效性指标(速效K、缓效 K、有效K及黑麦草总吸K量)的相关性也较为密切。

Some further approximations lead to a simple formula that expresses the barrier for nonidentity and identity hydrogen abstraction reactions as a function of the bond strengths of reactants and products.

第八章利用从头算价键计算方法结合价态相关图模型研究了卤族非等同氢提取反应，并对此类非等同氢提取反应做了归纳，推导出描述此类化学反应的能垒的普适半经验公式。

Zn-La alloys increase the overpotential ofhydrogen evolution, Tafel slope 〓 and polarization, decrease the corrosion current density, inhibitthe corrosion of zinc electrode in alkaline solution, decrease anode Tafel slope 〓, promotedischarge reaction of zinc electrode, have higher passivation current density, inhibit thepassivation of zinc electrode, avoid the oversaturation of zincate in electrolyte, greatly increase〓 diffusion coefficient, decrease Tafel slope 〓, polarization and the overpotential of deposition,inhibit the dendrites formation and improve the electrodepostion of Zn.

实验结果表明，Zn-La合金电极显著改善了锌电极的各项电化学性能：提高析氢过电位、析氢过程Tafel斜率〓和极化，减小腐蚀电流密度，抑制锌电极在碱液中的腐蚀；降低阳极Tafel斜率〓，促进了锌电极的放电反应；具有较高的维钝电流密度，抑制锌电极的钝化；有效避免了溶液中锌酸盐的过饱和现象：使〓的扩散系数明显增大：降低Zn沉积过程的Tafel斜率〓、极化和沉积过电位，明显抑制锌枝晶的生长，改善了锌的电沉积性能。

The transition states of the reaction between THF、 butylene oxide and secondary oxonium ion were acquired. By using frequency analysis and inner reactioncoordinate analysis the rationality of these transition states were affirmed.

分别对四氢呋喃和环氧丁烷，绘出了链增长反应的势能面曲线，得到四氢呋喃链增长反应的活化能为116.749kJ/mol；环氧丁烷链增长反应的活化能为92.672kJ/mol。

By using density functional theory B3LYP/6-311G++method, the geometric configuration was optimized for tetrahydrofuran、butylene oxide、 secondary oxonium ion and tertiary oxonium ion. And parameters about the electronic structure, bondlength, energy of frontier orbital of these species were determined.

采用DFT中的B3LYP/6-311G++方法对四氢呋喃和环氧丁烷单体、仲氧鎓离子以及叔氧鎓离子进行了几何构型的全优化，确定了各个构型的电子结构、键长和前线轨道能量等参数，并运用前线轨道理论从微观层次上分析了四氢呋喃和环氧丁烷的阳离子均聚反应机理。

Poly, palmitic acid and trimethylchloro-silicane were selected as surface treatment agents for HA particles.

FTIR分析表明，HA晶胞中不存在OH-之间的强烈氢键作用，但支持OH-与PO3-4存在弱的氢键的结论。

These results strongly demonstrate the importance of diffusion of hydrogen in the passivation process in semiconductors.

研究实验充分证明了氢的扩散是GaN中实现氢钝化作用的一个重要前提。

Selective hydrogenation for pentadiene in FCC C 5 fractions and hydroetherification of tertiary pentanes with methanol were investigated.

采用离子交换法制备了Pd/D0 0 5树脂催化剂，对催化裂化C5 馏分中戊二烯的选择性加氢和叔戊烯与甲醇的临氢醚化反应进行了研究。

A Pd /D005 resin catalyst was prepared by using ion exchangemethod.Selective hydrogenation for pentadiene in FCC C5 fractions and hydroetherification of tertiary pentanes with methanol were investigated.

采用离子交换法制备了Pd/D005树脂催化剂，对催化裂化C5馏分中戊二烯的选择性加氢和叔戊烯与甲醇的临氢醚化反应进行了研究。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐