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The results of in situ DRIFTS on propylene oxidation show that the allyl species originated from α-H abstraction of propylene were located at the wavenumbers of 1454 cm~(-1) and 1427 cm~(-1). The rate-determining step is the abstraction of an α-H abstraction from a lattice oxygen linked to a bismuth ion to form a π-allyl intermediate coordinated to a molybdenum ion. The metal-oxo group then attacks the allyl intermediate forming a σ-bonded oxygen-allyl species, which is in a rapid equilibrium with the π- bonded species. The σ-bonded species then transforms to acrolein by further abstraction of α-H. Such species as formate, carboxylate, carbonate transform to deep oxidation products. The acetone was derived from propylene by an enolic species at lower temperatures.

丙烯氧化反应体系的原位漫反射红外光谱研究结果表明,由丙烯脱生成的烯丙基中间物种吸收峰在1454cm~(-1)和1427cm~(-1)处;基于此提出了较完整的丙烯氧化反应网络:丙烯选择氧化生成丙烯醛主要经历丙烯脱除甲基上的一个H,生成烯丙基物种,该物种嵌氧生成σ-O络合物,脱得到丙烯醛前驱体,脱附生成丙烯醛;完全氧化产物是由催化剂表面上生成甲酸盐、羧酸盐、碳酸盐等形式的中间物种转化而成;较低反应温度下丙烯氧化生成丙酮,通过烯醇式中间物种氧化生成丙酮前驱体得到。

Similar to the histological changes, the shape of the enzym lesion focus was also global, it contained a center showed no enzym activities and a low enzym activity peripheral zone of 5~7 cell layers well-demarcated from the normal activity tissues.

结果:1。射频消融能明显破坏心肌组织多种代谢酶的活性,使乳酸脱酶、琥珀酸脱酶、细胞色素氧化酶和钙ATP酶活性丧失或减低,而且各酶的损伤范围相同。

It's found that th e activation of alloy was improved with increasing the concentration,temperature and immersing time of alkaline solution,the reason is that the Zr-rich surface of alloy was conversed to Nirich surface because of the strong erodent action of alkaline solution,this catalyzes ...

实验发现:储合金电极的活化性能随碱液浓度增大、温度升高以及浸泡时间的延长得到改善,主要由于KOH的强腐蚀性使合金表面由富Zr层转化为富Ni层,为的吸附离解起到催化作用,总结出最佳KOH处理液的实验参数:6mol/L、80℃、浸泡 2 4h ,在此条件下合金电极循环两周即达最大放电容量。

In this paper,the Lactate dehydrogenase, malate dehydrogenase,superoxide dis-mutase of five tissues of Carassius auratus gibelio; Cyprinus carpio Linnaeus; Esox americanus Gmelin; Leuciscus waleckii in Dalai Lake were studied by vertical polypropylene gel electrophoresis and the isozyme composion of four kinds of fishes were obtained. Then the analysis of the expressing specify of 3 kinds of isozyme in different tissues and loci were carried on and the genetic base of isozyme system was discussed.

本实验采用垂直板聚丙烯酰胺凝胶的电泳方法对达赉湖的野生鲤鱼、银鲫、狗鱼、东北雅罗鱼的五种组织脏器(肌肉、心脏、肝脏、脑、眼睛)的三种同工酶(苹果酸脱酶、乳酸脱酶、超氧化物岐化酶)进行了初步研究,获得了达赉湖四种鱼类物种的同工酶谱,在此基础上对同工酶在不同组织的表达差异和基因位点进行分析,探讨其同工酶系统的遗传基础。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下,利用2,4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应,合成了中间体4-丙氧基-2-羟基二苯甲酮,将其进一步与聚甲基硅氧烷进行硅化加成反应。

The paper is a survey of fermentative bio-hydrogen production process, followed by its new approaches in the future development.

本文主要介绍了厌氧发酵生物制技术的方法和机理,分析了生物制的可行性,结合国内外研究现状提出了未来的发展方向。

Second, investigations were made in the effects of polymerization of HRP on its catalytic activity in the excess of H〓O〓 by the use of fluorogenic hydrogen donors of HRP. The results showed that some HD, e. g. homovanillic acid could indicate the activity differences between HRP and polymerized HRP.

其次,为建立辣根过氧化物酶标记的调制型荧光免疫分析研究了用荧光供体代替显色供体指示聚合前后辣根过氧化物酶在高浓度H〓O〓中活性的差异。

Under the optimal reaction conditions of 0.5MPa pressure, at 150℃, H2 gas flow rate of 5000 mLh^(-1) and liquid flow rate of 5.0mLh^(-1), the conversion of furoic acid, selectivity to methyl tetra-hydro-furan formiate and yield of methyl tetra-hydro-furan formiate can reach 99.0%, 98.2% and 97.2%, respectively.

结果表明:在0.5MPa,150℃,气流速5000mLh^(-1),液体流速5.0mLh^(-1)(油比为50)时,呋喃甲酸转化率为99.0%,四糠酸甲酯的选择性98.2%,产率97.2%。

The effects of five factors on residue rate during the liquefaction of branches of Fraxinus chinensis Roxb. in tetralin-phenol hydrogen-donor solvents were investigated by orthogonal test.

通过正交试验考察了白蜡枝桠材在四萘与苯酚混合供溶剂中液化过程的5个因素对残渣率的影响。

Two skeleton nickel catalysts A and B were prepared at 50 ℃ and 90 ℃ respectively and hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol was studied with the catalysts under different reaction conditions.

研究了以骨架镍为加催化剂,以糠醇为原料制备四糠醇。在中温和高温下制备了两种骨架镍催化剂A和B,研究了不同的反应条件对两种骨架镍催化剂的影响,确定了最佳反应条件。

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Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

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