氢

The invention relates to a method for the extraction of keratin from dead animal skins, characterised in the treatment of dead animal skins with a substance of general formula, or at least one corresponding alkali metal, earth alkali metal, ammonium, or phosphonium salt, the variables having the following definitions: R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, whereby at least one of R or R is not H, or R and R are not H and two vicinal groups of R to R together may be C3-C10 alkylene, R = H, C1-C12 alkyl, H-C=O or C1-C4-Alkyl-C=O, X, X, X and X = OH, SH or NHR, whereby where Rto R contains at least one sulphur atom, at least one of X to X = SH and where R to R contains no sulphur atom, at least two of X to X= SH.

本发明涉及一种从死亡动物原皮中除去角质的方法，其特征在于用通式I的物质或至少一种对应的碱金属盐、碱土金属盐、铵盐或∴盐处理死亡动物原皮，式I中各变量定义如下：R 1 和R 4 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基，其未被取代或被一个或多个SH或OH基团取代；R 2 和R 3 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基，其未被取代或被一个或多个SH或OH基团取代，其中至少一个基团R 2 或R 3 不为氢，或R 1 和R 4 不为氢，且两个相邻基团R 1 -R 4 可以一起为C 3 -C 10 亚烷基；R 5 选自氢、C 1 -C 12 烷基、H-C＝O或C 1 -C 4 烷基-C＝O；X 1 、X 2 、X 3 和X 4 选自OH、SH和NHR 5 ，其中若R 1 -R 4 含有至少一个硫原子，则至少一个基团X 1 -X 4 为SH，以及若R 1 -R 4 不含硫原子，则至少两个基团X 1 -X 4 为SH。

The results show that: Microwave pretreatment at 2 min considering energy balance, of which the lag-phase time the maximal specific hydrogen rate and the specific hydrogen potential were 2.51h, 13.33 mL/ and 215.11 mL/g, can consumingly enhance hydrogen production.

结果表明：不同长度的微波预处理时间对泔脚发酵产氢具有不同程度的促进作用，4 min是转折点；结合能量衡算，2 min的微波预处理表现出更大的产氢优越性，其产氢延迟时间λ、最大比产氢率、产氢率分别为2.51h，13.33mL/，215.11mL/g。

Ascorbate is concomitantly oxidized to monodehydroascorbate. Some monodehydroascorbate radicals are re-reduced in a reaction catalyzed by monodehy- droascorbate reductase, but the remainder undergoes spontaneous dismutation to ascorbate and dehydroascorbate.

在抵抗氧化胁迫的反应中，抗坏血酸自身被氧化为单脱氢抗坏血酸，一部分单脱氢抗坏血酸在单脱氢抗坏血酸还原酶的催化作用下还原为抗坏血酸，另一部分单脱氢抗坏血酸的在歧化作用下被不成比例地还原为抗坏血酸或氧化为脱氢抗坏血酸。

Hydrogenases are key enzyme for bio-hydrogen production, most of them were rapidly inactivated by oxygen. It is important to bio-hydrogen production and hydrogen application that improve the O2-tolerance of hydrogenase.

氢酶是生物制氢的关键酶，大多数氢酶因对氧极敏感而易失活，因此提高氢酶的氧耐受性对生物制氢有重要意义。

By researching the catalysis action of metals in hydrogen storage materials, it is found that metal activators accelerate hydriding-dehydrding velocity of hydrogen storage materials in the process of grinding, and they also reduce the dehydriding temperature, enhance the hydrogen storage capacity of materials, and hasten the formation of similar-graphite microcrystal in the process of pretreatment.

通过对储氢材料中金属催化作用的研究发现，金属催化剂促进材料球磨过程中的快速吸氢，加快材料的放氢速度，降低材料的放氢温度，提高材料的储氢密度，促进无烟煤在预处理过程中类石墨微晶结构的形成。

As the preferentially recommended odorant of the new generation, THT took the place of ethanethiol as the odorant for nature gas by Beijing Natural Gas company in 1996. Due to the relatively short history and low production level of THT in China, little research has been done on it.

四氢噻吩作为在国际上被推荐首选使用的新一代燃气加臭剂，北京市天然气公司于1996年将天然气中的加臭剂由乙硫醇改为四氢噻吩，但中国由于采用四氢噻吩的时间比较晚，且因为四氢噻吩的生产在国内比较少，所以针对四氢噻吩的研究比较缺乏。

The paper reviewed the current research progress and the main achievements of biohydrogen production technology research both at home and abroad,and described the hydrogen production mechanism s of main hydrogen producing organisms,such as phot.

本文综述了目前国内外生物制氢技术各个方面的研究进展和成果，并详细描述了光合产氢细菌及发酵产氢细菌等主要产氢生物的产氢机制。

The supported WP catalysts showed considerable activity in HDS reaction of dibenzothiophene and HDN reaction of quinoline. The ibenzothiophene HDS activity and quinoline HDN activity of the spported WP catalysts synthesized by co-impregnation method was better than that synthesized by mixing method. The HDS and HDN activities of 25～30% WP catalysts synthesized by co-impregnation method and reduced at 650～750℃ were better than those of the corresponding sulfurized catalyst.

负载型WP催化剂具有较好的二苯并噻吩加氢脱硫和喹啉加氢脱氮活性，共浸渍法制备的磷化钨催化剂二苯并噻吩加氢脱硫和喹啉加氢脱氮活性要高于混合法制备的磷化钨催化剂。650～750℃还原制备的负载量25～30%的浸渍法磷化钨催化剂具有较高的二苯并噻吩加氢脱硫和喹啉加氢脱氮活性，高于相应的硫化态催化剂。

The results show that T225NG Ti-alloy has good property of resisting hydrogen brittleness in atmosphere and in loop water. Hydrogen brittleness of T225NG Ti-alloy is hydride brittleness. This is due to the forming of hydride caused by a large amount of hydrogen dissolved in and oxide film on the surface of T225NG ...

研究结果表明：T225NG钛合金在空气和高温高压高纯水的环境下具有良好的抗氢脆性能； T225NG 钛合金的氢脆属于氢化物脆性，这是由于T225NG钛合金中渗入的氢导致氢化物的析出引起的；T225NG钛合金表面氧化膜对它优良的抗氢脆性能起了决定性的作用。

The degree of hydrogenation of methyl benzoate might be controled by adding the promoters and changing the nano-size of ZnO. For hydrogenation of methyl benzoate to benzaldehyde, the active-structure of a catalyst should be modified to decrease the absorption of benzaldehyde on the surface of it, because benzaldehyde absorbed is hydrogenated easily. Using 30-40％ZnO/γ-Al〓O〓 or Li-30％ZnO/γ-Al〓O〓, a higher selectivity to benzaldehyde is obtained. Hydrogenolysis of methyl benzoate to toluene or benzene is carried out effectively using a catalyst modified. For instance, 45.3％ selectivity to benzene and 100％ conversion of methyl benzoate at 420℃ was obtained over 10％ZnO/MCM-41 with the nano-size particles of ZnO (2.4nm).

也可以通过助催化剂的添加和活性组分的纳米化，并根据苯甲酸甲酯多步加氢反应的特点实行加氢深度的调控：苯甲酸甲酯选择性加氢制苯甲醛中，由于苯甲醛容易进一步加氢，需要对活性结构进行调变，以减弱苯甲醛的吸附，使用30-40％ZnO/γ-Al〓O〓催化剂或Li调变的Li-30％ZnO/γ-Al〓O〓催化剂，可获得较高的苯甲酸甲酯加氢制苯甲醛的活性；采用同样的方式，苯甲酸甲酯选择性氢解为甲苯或苯也获得了较好的结果，如使用ZnO纳米化的10％ZnO/MCM-41催化剂，在420℃，可获得45.3％的苯选择性，苯甲酸甲酯完全转化。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。