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In this project, we have prepared conveniently Si-Mg 1,1-difunctional group reagents-α-silylvinyl Grignard reagents by hydromagnesiation of alkynylsilanes; Se-Br 1,1-difunctional group reagents-α-bromovinylselenides by hydrobromination of alkynylselenides; Sn-Br and Sn-I 1,1-difunctional group reagents by hydrozirconation of alkynylstannanes followed by halogenating reaction.

本项目通过炔基硅烷的镁化反应,方便地制得了Si-Mg 1,1-双官能团试剂-α-硅基烯基镁化物;通过炔基硒醚的溴化反应,方便地制得了Se-Br 1,1-双官能试剂-α-溴代烯基硒醚;通过炔基锡烷的锆化反应,继而卤代方便地制得了Sn-Br和Sn-I 1,1-双官能试剂。

The vibration energy or the electronic and vibration entropy of the gaseous molecules are approximately used as the energy or entropy of the solid. In this approximation, thermodynamic functions 、、 and hydrogen isotopes equilibrium pressure of the hydrogenating reaction have been calculated .Then we can fit the relations between temperature and equilibrium pressure.

在ZrH2的E和S的过程中,以气态分子总能量中的振动能EV代替该分子处于固态时的振动能量E,以电子和振动熵SEV代替分子处于固态熵的近似方法,计算了不同温度下金属Zr与同位素反应的,和以及化反应平衡压力,并导出了化反应平衡压力与温度的关系。

It is found that , H+ penetrates through ZnS and reaches the interface between ZnS and HgCdTe by SIMS testing. It is analyzed that H+ passivates the interface, reduces the density of interface states and improves the performance of detector.

SIMS测试发现化过程中离子可以穿过ZnS层到达ZnS与碲镉汞的界面处,分析认为离子对界面态起到了钝化作用,降低了界面态密度,提高了器件的性能。

Three schemes of dealing with AH wash liq uor of high soda concentration were analyzed and compared. The results show th at when the AH wash liquor of total soda concentration 95.06g/L is transferred d irectly to dilution tank, soda concentration in overflow of the 1st mud washer c ould be lowered by about 6g/L and soda loss in red mud attached liquor could be lo we red by 0.25 kg Na2O per ton of alumina and therefore saving cost of about 549 000 RMB per year; moreover, suspension in AH wash liquor could be re-dissolved in to diluted liquor and it is favor not only to rise pregnant liquor R p andimprove precipitation process, but also to avoid alumina loss cost of about 353?000 RMB per year by the suspension settling into red mud.

分析比较了处理高浓度氧化铝洗液的3种方案,结果表明:将全碱浓度为95.06g/L的氧化铝洗液直接送到稀释槽,可使赤泥一洗槽溢流浓度降低约6g/L ,每吨氧化铝赤泥附碱损失减小0.25kg氧化钠,每年可节省碱耗费约54.9万元;而且还能将氧化铝洗液中的浮游物反溶解进入稀释液,有利于精液 R p(氧化铝与苛性氧化钠的质量比)的提高,同时避免了其进入赤泥而被损失,每年可减少氧化铝损失费约35.3万元。

The research development of the reaction of light alkenes from CO 2 hydrogenation and the supply of cheap hydrogen is discussed.

对CO_2加合成低碳烯烃反应进行了热力学分析,就近年来关于CO_2加合成低碳烯烃反应及廉价的供给的研究进展进行了综述。

In addition, there are a large number of strong hydrogenbondings(N-H…O,O-H…O) and weak hydrogen bondings in involving the cations,perchlorate counter-ions,PNOS and water molecules, which result in formation 3-D networkstructure.

晶体中Ni与配体希夫碱中的N 、N(吡吡啶醛类过渡金属希夫碱配合物的合成、晶体结构及谱学表征啶)、O原子配位形成变形的八面体构型,由于分子间,存在大量的强键和弱键,这些键的交互作用使得该配合物形成二维网状结构。

In this paper,the principle of absorbing/desorbing hydrogen and researching progress of some kinds of light metal-aluminum hydride s as hydrogen storage material are introduced.

介绍了几种轻质金属-铝化物贮材料的吸放机理和研究进展。

In this paper,the principle of absorbing/desorbing hydrogen and researching progress of some kinds of light metal-aluminum hydrides as hydrogen storage material are introduced.

介绍了几种轻质金属-铝化物贮材料的吸放机理和研究进展。

The research development of the principle of absorbing/desorbing hydrogen, the effect of the catalyst type and preparing process, and the thermodynamics and kinetics of absorbing/desorbing hydrogen are reviewed.

本文着重阐述了两种络合铝化物的吸放原理,掺杂催化剂的类型和制备工艺的影响以及吸放热力学和动力学等方面的研究进展。

The desorbing plateau pressure and the desorption capacity of the alloy increased with improving the desorbing temperature.

随着放温度提高放的平台压力升高,放量则增大。

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