氢

The borohydride is hydrogen source for an advanced fuel cell, Imol borohydride with water produces 4mol hydrogen and Imol of side product sodium metaborate. Regeneration of metaborate for recycle of boron brings forth a bright future to the new fuel cells. In this paper, a method for the preparation of sodium borohydride from sodium metaborate was proposed.

硼氢化钠是一种燃料电池的氢源，1mol硼氢化钠催化水解产生4mol的氢气及副产物偏硼酸钠，若能实现偏硼酸钠的循环利用，该燃料电池将有广泛的应用前景。

The equation of states under high temperatures and high pressures, phase -transition and metalization for H_2 and its isotopes are one of the hot topics of scientific studies for a long time.

氢及其同位素的高温高压状态方程、相变与金属化等问题是长期以来科学研究的热点课题之一；氢、氦分别是结构最简单的双原子和单原子分子，在冲击加载条件下，氢，氦材料的热力学特性一直是从事凝聚态物理研究的理论和实验工作者非常关注的前沿研究课题之一。

The experiment results show that the yield of hexane catalyzed by the nano-fibrous catalyst was 4.7 times higher than that of PdCl_2/γ-Al_2O_3 catalyst. The hydrogenation ofα-tetradecylene, cyclohexene, nitrobenzol and styrene by the nano-fibrous catalyst was also studied, the selectivity to primary products of the hydrogenation of cyclohexene, nitrobenzol and styrene was 100%.

苯乙烯-丙烯腈共聚物负载纳米钯超细纤维形态催化剂在常温，氢气压力101.3Pa下催化α-己烯加氢时表现出很高的活性，催化剂PSAN-Pd10催化氢化α-己烯选择生成正己烷的产率在150 min就达到87%以上，与无机物负载的催化剂相比，加氢效果有显著提高，并且催化剂的重复使用性较好。

A modified γ-Al〓O〓 was prepared by a special precipitation method with aluminum nitrate solution containing a certain amounts of orthosilicic acid and ammonia aqueous solution. Compared with commercial γ-Al〓O〓, the modified γ-Al〓O〓 was an effecient catalyst for dehydration of tetrahydrofurfuryl alcohol to dihydropyran. The results revealed that the strong acid sites on the surface of the catalyst may play a crucial role in this reaction.

并以硝酸铝和氨水为原料，用沉淀法制备出一种高比表面和拥有较多强酸中心的γ-Al〓O〓，它在四氢糠醇开环脱水制备二氢吡喃的反应中有优良的催化活性，通过比较此γ-Al〓O〓和普通商业γ-Al〓O〓的Py-TPD图，发现强酸中心在制备二氢吡喃的反应中可能具有关键的作用。

The studies of hydrogen behaviour in HR-1 stainless steel and its composite sample with CVD coated chromium oxidic film have been presented.

本文介绍氢在HR－1不锈钢基体及镀有氧化铬膜的复合材料中的行为研究，包括基体的准备；膜的制备；用不同手段从不同角度对膜进行的分析测试；膜与基体之间的平均结合力测定；用不锈钢材料构成的高温低压渗透回路的建造、调试、密封性能校准；纯HR－1基体材料中的氢渗透规律研究；有膜复合材料中氢的稳态迁移过程的表现规律实验结果。

Twenty-seven compounds were isolated from the methanol extract of the stems of Pinus massoniana by means of chromatographic methods, and their structures were elucidated as 8(14),15-Pimaradien-19-oic acid (1), Pimaric (2), Podocarpic acid (3), 12-Hydroxydehydroabietic acid (4), Dehydroabietic acid (5), 15-Hydroxydehydroabietic (6), 3β-Methoxyserrat-14-en-21-one (7), 3β-Hydroxy- serrat- 14-en-21-one (8), 3β-Methoxyserrat-14-en-21-one-30-al (9),(24R)-Stigmst- 4-ene-3-one (10),β-sitosterol (11),-3-Hydroxy-5-methoxy-stilbene(12), 4-Hydroxy-3- methoxycinnamaldehyde (13),-Ferulic acidtetracosyl ester (14), Alkylferulates (15), Pinocembin (16), Coniferaldehyde (17), Matairesinol (18),-Nortrachelogenin (19), Balanophonin (20), Cedrusin (21),-Pinoresinol (22), Tanegoside (23), 1,2-Bis-(4-hydroxy-3- methoxyphenyl)-propane-1,3-diol (24),(1S*, 2S*)-1-(4- Hydroxyphenyl) glyceri...

同时对马尾松枝条的甲醇提取物利用各种色谱技术进行了分离纯化，并利用现波谱技术鉴定了27个化合物的结构，分别为：8(14)，15-Pimaradien-19-oic acid (1)、海松酸(2)、罗汉松酸(3)、12-羟基脱氢松香酸(4)、脱氢松香酸(5)、15-羟基-脱氢松香酯(6)、3β-甲氧基-锯齿石松-14-烯-21-酮(7)、3β-Hydroxyserrat-14-en-21-one (8)、3β-Methoxyserrat-14-en-21– one-30-al (9)、(24R)-豆甾-4-烯-3-酮(10)、-3-羟基-5-甲氧基-二苯乙烯(12)、4-Hydroxy-3-methoxycinnamaldehyde (13)、-Ferulic acidtetracosyl ester (14)、Alkylferulates (15)、Pinocembin (16)、Coniferaldehyde (17)、罗汉松树脂酚(18)、 Balanophonin (20)、tanegoside (23)、1，2-Bis-(4-hydroxy- 3-methoxyphenyl)-propane- 1，3-diol (24)、(1S*，2S*)- 1-(4-hydroxyphenyl)glycerins (25)、(1R*，2R*)-1-(4-hydroxy- phenyl)gly-cerins (26)和赤松素(27)。

With increasing number of hot-wall hydroprocessing reactors and extension of service time, the occurrence of polythionic acid corrosion, hydrogen induced spalling of weld overlay, temper embrittlement of base metal, hydrogen embrittlement and surface cracking etc.

随着国产热壁加氢反应器的数量不断增加和服役时间的延长，连多硫酸腐蚀、堆焊层氢致剥离、母材回火脆化、氢脆、表面开裂等时效损伤出现的情况越来越多。

There are two parts in this thesis. Part I focuses on the transient effect in InGaP/GaAs hetero-junction bipolar transistors. Part II focuses on the P memory effect and buffer-layer-quality determination using C-V measurement in AlGaAs/GaAs pseudomorphic high-electron-mobility transistors. The characterization of hydrogen passivation for InGaP HBTs grown on semi-insulating GaAs substrates is studied. The transient effect caused by hydrogen passivation results the current gain ?

本论文分两部分，第一部份讨论在磷化铟镓的异质接面双载子电晶体中，由於氢的包覆效应产生的特性之研究，由於氢在此种元件中所造成的载子包覆现象是引起电流增益增加的暂态现象的主要原因，本论文提出一个计算氢包覆比例的模型，并与SIMS量测的结果相比对，经过几次热回火处理，此种暂态效应可以被消除。

The mechanism of formation of light-end products during M-HyPy was discussed.The results indicated that higher concentration and yields of BTX,PCX and naphthalene were found in M-HyPy as compared to HyPy,which is resulted from promoting hydrogenation and inhibiting repolymerization of free radicals due to the retention of hydrogen in M-HyPy.

结果表明：煤的多段加氢热解过程所得油品与传统的单段加氢热解油品相比，含有更丰富的高经济价值组分，如苯、甲苯、二甲苯和酚、甲酚、二甲酚及萘，这主要是因为氢气在峰温处的停留促进了自由基的氢化饱和及抑制了其再聚合的反应。

Hydrogen storage materials, which are important carriers during hydrogen storage and transport, can absorb and desorb hydrogen reversibly.

储氢材料能可逆地大量吸放氢，在氢的储存与输送过程中是一种重要载体。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐