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The crystallitic carbon was prepared from anthracite by demineralization and carbonization,then the magnesium/carbon nanocomposites for hydrogen storage were manufactured through reaction milling of the mixture of magnesium,crystallitic carbon and aluminium under hydrogen atmosphere.

将无烟煤进行脱灰和碳化,制备微晶碳,再将微晶碳和铝添加到镁中,用气反应球磨法制取镁/碳纳米复合储材料。用透射电子显微镜、选区电子衍射、X射线衍射和差示扫描量热分析对储材料的粒度、晶体结构和放温度进行了测定。

The research results indicate that the main reaction from the hydrodeoxygenation of decanoyl/octanoyl-glycerides on the catalysts include hydrogenation saturation,decarboxylization,isomerization and hydrocracking.The main product is alkane.On the Pt/SAPO-11 catalyst,the products composition of HDO f...

结果表明:辛癸酸甘油酯在加催化剂上的反应包括加饱和、脱羧、异构化和裂化反应,主要产物为烷烃;采用Pt/SAPO-11催化剂的催化加产物中异构化烷烃比例明显提高,脱羧反应和裂解反应得到明显抑制。

The insufficiencies of current models for the hydrogenation/dehydrogenation are analyzed and summarized,and the development trends for future research are proposed.

最后对现有模型存在的不足作出了总结,并对未来的金属化物化/脱反应动力学模型研究进行了展望。

From comparative research of synchronous and asynchronous reaction of dehydrogenation and cracking of dipentene,it is shown that farraginous extent of by-products from synchronous reaction is relatively high.

双戊烯脱裂解的同步反应和异步反应对比研究显示,双戊烯脱裂解的同步反应产物比较混杂,反应产物中甲苯的相对含量仅为24.03%,双戊烯相对于甲苯的料耗比为5.34,甲苯的得率为30.79%,中间产物对伞花烃的得率为2.49%;双戊烯脱裂解的异步反应产物混杂程度相对较低,反应产物中甲苯的相对含量为40.74%,对伞花烃的相对含量为18.31%,双戊烯相对于甲苯的料耗比为3.33,甲苯的得率为49.26%,中间产物对伞花烃的得率为16.92%。

P-Isopropylphenol was synthesized by catalytic transfer dehydrogenation with 5% Pd/C using 4-isopropylcyclohexenone as the material and the hydrogen offer, industrial dipentene as the hydrogen acceptor and the solvent.

采用5%Pd/C作为转移催化剂,4-异丙基环己烯酮为给予剂,工业双戊烯为接受剂和溶剂进行反应,合成了对异丙基苯酚。

Much oxygen was evolved in the course of H〓 production. Sodium dithionate and DCMU make the system anaerobic, but H〓 production didn't increase, even decreased. By addition of sodium acetate, glucose, heteroauxing in the course of illumination and Fe, Ni in the course of algal growth, the H〓 production increases by P.

采用强还原剂、PSⅡ抑制剂虽然可使体系处于厌氧状态,但产效率并无提高,甚至下降;光照产过程分别外加碳源NaAc、促生长剂IAA,藻体培养过程中补充Fe和Ni的无机物均能使扁藻产的效率有所提高。

Use D4 or DMC, Divinyl tetramethyl disiloxane, Tetravinyl tetramethyl cyelo tetrasiloxane were used as raw materials and Tetramethyl ammonium hydroxide as catalyst to synthesize a high molecular weight of vinyl silicone oil. Concentrate hydrosilicone oil, tetramethyl dihydro disiloxane, hexamethyldisiloxane and D4 were used to synthesize the cross linker of low-hydro silicone oil required in experiments.

以D4或DMC,乙烯基双封头,乙烯基环体等为原料,四甲基氧化铵为催化剂合成了不同摩尔质量的乙烯基硅油;以高含硅油,含双封头,六甲基二硅氧烷,D4合成实验所需的交联剂低含硅油。

The reaction performance of Pt-Sn-Li/Al_2O3/FeCrAl catalyst was measured,and the properties of the catalyst were characterized.It was found that reaction temperature,LHSV and the molar ratio of hydrogen to alkane have greatly affected on the catalytic performance of the Pt-Sn-Li/Al_2O_3/FeCrAl catalyst.Under a set of optimal reaction conditions,at 0.1 MPa,470℃,the molar ratio of hydrogen to alkane of 4 and LHSV of 0.14 mL·m~(-2)·h~(-1),the dodecane conversion is 6%,and the dodecene selectivity is about 72%.

结果表明:工业催化剂的催化性能比至今实验室制备的γ-Al_2O_3和SBA-15颗粒负载型颗粒状催化剂的性能好;反应温度、液时空速和烃摩尔比对Pt-Sn-Li/Al_2O_3/FeCrAl金属基整体式催化剂脱性能都有重要影响,最适宜的反应条件是压力为0.1 MPa,反应温度为470℃,进料烃摩尔比为4和LHSV为0.14 mL·m~(-2)·h~(-1),此时十二烷的转化率约为6%,十二烯的选择性约为72%;活性组分涂层与金属基体结合良好。

The key intermediate 3-methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods,formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction,and then hydr...

以3-氨基吡啶为原料,分别通过甲酰化反应、化铝锂还原和原甲酸三乙酯缩合、硼化钠还原两种方法得到3-甲胺基吡啶,最后经催化化得到中间体3-甲胺基哌啶。

The key intermediate 3- methylaminopiperidine was synthesized from 3-methylaminopyridine by two methods, formylation and lithium aluminium hydride reduction or condensation with triethyl orthoformate and sodium borohydride reduction, and then hydrolysis.

以3-氨基吡啶为原料,分别通过甲酰化反应、化铝锂还原和原甲酸三乙酯缩合、硼化钠还原两种方法得到3-甲胺基吡啶,最后经催化化得到中间体3-甲胺基哌啶。

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